Wettability of MXene films
Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucida...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Machata, Peter [verfasserIn] Hofbauerová, Monika [verfasserIn] Soyka, Yaryna [verfasserIn] Stepura, Anastasiia [verfasserIn] Truchan, Daniel [verfasserIn] Halahovets, Yuriy [verfasserIn] Mičušík, Matej [verfasserIn] Šiffalovič, Peter [verfasserIn] Majková, Eva [verfasserIn] Omastová, Mária [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2022 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of colloid and interface science - Amsterdam [u.a.] : Elsevier, 1966, 622, Seite 759-768 |
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| Übergeordnetes Werk: |
volume:622 ; pages:759-768 |
| DOI / URN: |
10.1016/j.jcis.2022.04.135 |
|---|
| Katalog-ID: |
ELV008088829 |
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| 245 | 1 | 0 | |a Wettability of MXene films |
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| 520 | |a Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucidate the experimental values of the static contact angles and get reproducible contact angle data, it is wiser to perform the advancing and receding contact angle measurements on smooth and compact Ti3C2T x layers and focus on deep understanding of the physical basis behind the wettability, which is provided by contact angle hysteresis.Experiments: Measurements of the advancing and receding contact angle on mono-, bi, and trilayer Ti3C2T x on two different substrates were performed. As substrates, UV-ozone treated silicon wafer and silicon wafer functionalized by (3-aminopropyl)triethoxysilane, were used.Findings: The values of the advancing contact angle on Ti3C2T x on both substrates were proved to be independent of the number of Ti3C2T x layers, demonstrating a negligible effect of the background substrate wettability. In addition, a giant contact angle hysteresis (44–52 °) was observed on very smooth surface, most likely as a result of chemical heterogeneity arising from the diversity of surface terminal groups (F, O, and OH). The findings reported in this study provide a comprehensive understanding of the wettability of MXene. | ||
| 650 | 4 | |a MXene | |
| 650 | 4 | |a Contact angle | |
| 650 | 4 | |a Wettability | |
| 650 | 4 | |a Surface modification | |
| 650 | 4 | |a Surface energy | |
| 700 | 1 | |a Hofbauerová, Monika |e verfasserin |4 aut | |
| 700 | 1 | |a Soyka, Yaryna |e verfasserin |4 aut | |
| 700 | 1 | |a Stepura, Anastasiia |e verfasserin |4 aut | |
| 700 | 1 | |a Truchan, Daniel |e verfasserin |4 aut | |
| 700 | 1 | |a Halahovets, Yuriy |e verfasserin |4 aut | |
| 700 | 1 | |a Mičušík, Matej |e verfasserin |4 aut | |
| 700 | 1 | |a Šiffalovič, Peter |e verfasserin |4 aut | |
| 700 | 1 | |a Majková, Eva |e verfasserin |4 aut | |
| 700 | 1 | |a Omastová, Mária |e verfasserin |4 aut | |
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10.1016/j.jcis.2022.04.135 doi (DE-627)ELV008088829 (ELSEVIER)S0021-9797(22)00703-2 DE-627 ger DE-627 rda eng 540 DE-600 35.18 bkl Machata, Peter verfasserin aut Wettability of MXene films 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucidate the experimental values of the static contact angles and get reproducible contact angle data, it is wiser to perform the advancing and receding contact angle measurements on smooth and compact Ti3C2T x layers and focus on deep understanding of the physical basis behind the wettability, which is provided by contact angle hysteresis.Experiments: Measurements of the advancing and receding contact angle on mono-, bi, and trilayer Ti3C2T x on two different substrates were performed. As substrates, UV-ozone treated silicon wafer and silicon wafer functionalized by (3-aminopropyl)triethoxysilane, were used.Findings: The values of the advancing contact angle on Ti3C2T x on both substrates were proved to be independent of the number of Ti3C2T x layers, demonstrating a negligible effect of the background substrate wettability. In addition, a giant contact angle hysteresis (44–52 °) was observed on very smooth surface, most likely as a result of chemical heterogeneity arising from the diversity of surface terminal groups (F, O, and OH). The findings reported in this study provide a comprehensive understanding of the wettability of MXene. MXene Contact angle Wettability Surface modification Surface energy Hofbauerová, Monika verfasserin aut Soyka, Yaryna verfasserin aut Stepura, Anastasiia verfasserin aut Truchan, Daniel verfasserin aut Halahovets, Yuriy verfasserin aut Mičušík, Matej verfasserin aut Šiffalovič, Peter verfasserin aut Majková, Eva verfasserin aut Omastová, Mária verfasserin aut Enthalten in Journal of colloid and interface science Amsterdam [u.a.] : Elsevier, 1966 622, Seite 759-768 Online-Ressource (DE-627)266891136 (DE-600)1469021-4 (DE-576)103373160 1095-7103 nnns volume:622 pages:759-768 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.18 Kolloidchemie Grenzflächenchemie AR 622 759-768 |
| spelling |
10.1016/j.jcis.2022.04.135 doi (DE-627)ELV008088829 (ELSEVIER)S0021-9797(22)00703-2 DE-627 ger DE-627 rda eng 540 DE-600 35.18 bkl Machata, Peter verfasserin aut Wettability of MXene films 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucidate the experimental values of the static contact angles and get reproducible contact angle data, it is wiser to perform the advancing and receding contact angle measurements on smooth and compact Ti3C2T x layers and focus on deep understanding of the physical basis behind the wettability, which is provided by contact angle hysteresis.Experiments: Measurements of the advancing and receding contact angle on mono-, bi, and trilayer Ti3C2T x on two different substrates were performed. As substrates, UV-ozone treated silicon wafer and silicon wafer functionalized by (3-aminopropyl)triethoxysilane, were used.Findings: The values of the advancing contact angle on Ti3C2T x on both substrates were proved to be independent of the number of Ti3C2T x layers, demonstrating a negligible effect of the background substrate wettability. In addition, a giant contact angle hysteresis (44–52 °) was observed on very smooth surface, most likely as a result of chemical heterogeneity arising from the diversity of surface terminal groups (F, O, and OH). The findings reported in this study provide a comprehensive understanding of the wettability of MXene. MXene Contact angle Wettability Surface modification Surface energy Hofbauerová, Monika verfasserin aut Soyka, Yaryna verfasserin aut Stepura, Anastasiia verfasserin aut Truchan, Daniel verfasserin aut Halahovets, Yuriy verfasserin aut Mičušík, Matej verfasserin aut Šiffalovič, Peter verfasserin aut Majková, Eva verfasserin aut Omastová, Mária verfasserin aut Enthalten in Journal of colloid and interface science Amsterdam [u.a.] : Elsevier, 1966 622, Seite 759-768 Online-Ressource (DE-627)266891136 (DE-600)1469021-4 (DE-576)103373160 1095-7103 nnns volume:622 pages:759-768 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.18 Kolloidchemie Grenzflächenchemie AR 622 759-768 |
| allfields_unstemmed |
10.1016/j.jcis.2022.04.135 doi (DE-627)ELV008088829 (ELSEVIER)S0021-9797(22)00703-2 DE-627 ger DE-627 rda eng 540 DE-600 35.18 bkl Machata, Peter verfasserin aut Wettability of MXene films 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucidate the experimental values of the static contact angles and get reproducible contact angle data, it is wiser to perform the advancing and receding contact angle measurements on smooth and compact Ti3C2T x layers and focus on deep understanding of the physical basis behind the wettability, which is provided by contact angle hysteresis.Experiments: Measurements of the advancing and receding contact angle on mono-, bi, and trilayer Ti3C2T x on two different substrates were performed. As substrates, UV-ozone treated silicon wafer and silicon wafer functionalized by (3-aminopropyl)triethoxysilane, were used.Findings: The values of the advancing contact angle on Ti3C2T x on both substrates were proved to be independent of the number of Ti3C2T x layers, demonstrating a negligible effect of the background substrate wettability. In addition, a giant contact angle hysteresis (44–52 °) was observed on very smooth surface, most likely as a result of chemical heterogeneity arising from the diversity of surface terminal groups (F, O, and OH). The findings reported in this study provide a comprehensive understanding of the wettability of MXene. MXene Contact angle Wettability Surface modification Surface energy Hofbauerová, Monika verfasserin aut Soyka, Yaryna verfasserin aut Stepura, Anastasiia verfasserin aut Truchan, Daniel verfasserin aut Halahovets, Yuriy verfasserin aut Mičušík, Matej verfasserin aut Šiffalovič, Peter verfasserin aut Majková, Eva verfasserin aut Omastová, Mária verfasserin aut Enthalten in Journal of colloid and interface science Amsterdam [u.a.] : Elsevier, 1966 622, Seite 759-768 Online-Ressource (DE-627)266891136 (DE-600)1469021-4 (DE-576)103373160 1095-7103 nnns volume:622 pages:759-768 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.18 Kolloidchemie Grenzflächenchemie AR 622 759-768 |
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10.1016/j.jcis.2022.04.135 doi (DE-627)ELV008088829 (ELSEVIER)S0021-9797(22)00703-2 DE-627 ger DE-627 rda eng 540 DE-600 35.18 bkl Machata, Peter verfasserin aut Wettability of MXene films 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucidate the experimental values of the static contact angles and get reproducible contact angle data, it is wiser to perform the advancing and receding contact angle measurements on smooth and compact Ti3C2T x layers and focus on deep understanding of the physical basis behind the wettability, which is provided by contact angle hysteresis.Experiments: Measurements of the advancing and receding contact angle on mono-, bi, and trilayer Ti3C2T x on two different substrates were performed. As substrates, UV-ozone treated silicon wafer and silicon wafer functionalized by (3-aminopropyl)triethoxysilane, were used.Findings: The values of the advancing contact angle on Ti3C2T x on both substrates were proved to be independent of the number of Ti3C2T x layers, demonstrating a negligible effect of the background substrate wettability. In addition, a giant contact angle hysteresis (44–52 °) was observed on very smooth surface, most likely as a result of chemical heterogeneity arising from the diversity of surface terminal groups (F, O, and OH). The findings reported in this study provide a comprehensive understanding of the wettability of MXene. MXene Contact angle Wettability Surface modification Surface energy Hofbauerová, Monika verfasserin aut Soyka, Yaryna verfasserin aut Stepura, Anastasiia verfasserin aut Truchan, Daniel verfasserin aut Halahovets, Yuriy verfasserin aut Mičušík, Matej verfasserin aut Šiffalovič, Peter verfasserin aut Majková, Eva verfasserin aut Omastová, Mária verfasserin aut Enthalten in Journal of colloid and interface science Amsterdam [u.a.] : Elsevier, 1966 622, Seite 759-768 Online-Ressource (DE-627)266891136 (DE-600)1469021-4 (DE-576)103373160 1095-7103 nnns volume:622 pages:759-768 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.18 Kolloidchemie Grenzflächenchemie AR 622 759-768 |
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10.1016/j.jcis.2022.04.135 doi (DE-627)ELV008088829 (ELSEVIER)S0021-9797(22)00703-2 DE-627 ger DE-627 rda eng 540 DE-600 35.18 bkl Machata, Peter verfasserin aut Wettability of MXene films 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucidate the experimental values of the static contact angles and get reproducible contact angle data, it is wiser to perform the advancing and receding contact angle measurements on smooth and compact Ti3C2T x layers and focus on deep understanding of the physical basis behind the wettability, which is provided by contact angle hysteresis.Experiments: Measurements of the advancing and receding contact angle on mono-, bi, and trilayer Ti3C2T x on two different substrates were performed. As substrates, UV-ozone treated silicon wafer and silicon wafer functionalized by (3-aminopropyl)triethoxysilane, were used.Findings: The values of the advancing contact angle on Ti3C2T x on both substrates were proved to be independent of the number of Ti3C2T x layers, demonstrating a negligible effect of the background substrate wettability. In addition, a giant contact angle hysteresis (44–52 °) was observed on very smooth surface, most likely as a result of chemical heterogeneity arising from the diversity of surface terminal groups (F, O, and OH). The findings reported in this study provide a comprehensive understanding of the wettability of MXene. MXene Contact angle Wettability Surface modification Surface energy Hofbauerová, Monika verfasserin aut Soyka, Yaryna verfasserin aut Stepura, Anastasiia verfasserin aut Truchan, Daniel verfasserin aut Halahovets, Yuriy verfasserin aut Mičušík, Matej verfasserin aut Šiffalovič, Peter verfasserin aut Majková, Eva verfasserin aut Omastová, Mária verfasserin aut Enthalten in Journal of colloid and interface science Amsterdam [u.a.] : Elsevier, 1966 622, Seite 759-768 Online-Ressource (DE-627)266891136 (DE-600)1469021-4 (DE-576)103373160 1095-7103 nnns volume:622 pages:759-768 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.18 Kolloidchemie Grenzflächenchemie AR 622 759-768 |
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Enthalten in Journal of colloid and interface science 622, Seite 759-768 volume:622 pages:759-768 |
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MXene Contact angle Wettability Surface modification Surface energy |
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Machata, Peter @@aut@@ Hofbauerová, Monika @@aut@@ Soyka, Yaryna @@aut@@ Stepura, Anastasiia @@aut@@ Truchan, Daniel @@aut@@ Halahovets, Yuriy @@aut@@ Mičušík, Matej @@aut@@ Šiffalovič, Peter @@aut@@ Majková, Eva @@aut@@ Omastová, Mária @@aut@@ |
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2022-01-01T00:00:00Z |
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Machata, Peter |
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Machata, Peter ddc 540 bkl 35.18 misc MXene misc Contact angle misc Wettability misc Surface modification misc Surface energy Wettability of MXene films |
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Wettability of MXene films |
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Wettability of MXene films |
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Machata, Peter Hofbauerová, Monika Soyka, Yaryna Stepura, Anastasiia Truchan, Daniel Halahovets, Yuriy Mičušík, Matej Šiffalovič, Peter Majková, Eva Omastová, Mária |
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wettability of mxene films |
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Wettability of MXene films |
| abstract |
Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucidate the experimental values of the static contact angles and get reproducible contact angle data, it is wiser to perform the advancing and receding contact angle measurements on smooth and compact Ti3C2T x layers and focus on deep understanding of the physical basis behind the wettability, which is provided by contact angle hysteresis.Experiments: Measurements of the advancing and receding contact angle on mono-, bi, and trilayer Ti3C2T x on two different substrates were performed. As substrates, UV-ozone treated silicon wafer and silicon wafer functionalized by (3-aminopropyl)triethoxysilane, were used.Findings: The values of the advancing contact angle on Ti3C2T x on both substrates were proved to be independent of the number of Ti3C2T x layers, demonstrating a negligible effect of the background substrate wettability. In addition, a giant contact angle hysteresis (44–52 °) was observed on very smooth surface, most likely as a result of chemical heterogeneity arising from the diversity of surface terminal groups (F, O, and OH). The findings reported in this study provide a comprehensive understanding of the wettability of MXene. |
| abstractGer |
Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucidate the experimental values of the static contact angles and get reproducible contact angle data, it is wiser to perform the advancing and receding contact angle measurements on smooth and compact Ti3C2T x layers and focus on deep understanding of the physical basis behind the wettability, which is provided by contact angle hysteresis.Experiments: Measurements of the advancing and receding contact angle on mono-, bi, and trilayer Ti3C2T x on two different substrates were performed. As substrates, UV-ozone treated silicon wafer and silicon wafer functionalized by (3-aminopropyl)triethoxysilane, were used.Findings: The values of the advancing contact angle on Ti3C2T x on both substrates were proved to be independent of the number of Ti3C2T x layers, demonstrating a negligible effect of the background substrate wettability. In addition, a giant contact angle hysteresis (44–52 °) was observed on very smooth surface, most likely as a result of chemical heterogeneity arising from the diversity of surface terminal groups (F, O, and OH). The findings reported in this study provide a comprehensive understanding of the wettability of MXene. |
| abstract_unstemmed |
Hypothesis: One of the highlighted properties of Ti3C2T x MXene compared to other 2D nanomaterials is its hydrophilicity. However, the broad range of static contact angles of Ti3C2T x reported in the literature is misleading. To elucidate the experimental values of the static contact angles and get reproducible contact angle data, it is wiser to perform the advancing and receding contact angle measurements on smooth and compact Ti3C2T x layers and focus on deep understanding of the physical basis behind the wettability, which is provided by contact angle hysteresis.Experiments: Measurements of the advancing and receding contact angle on mono-, bi, and trilayer Ti3C2T x on two different substrates were performed. As substrates, UV-ozone treated silicon wafer and silicon wafer functionalized by (3-aminopropyl)triethoxysilane, were used.Findings: The values of the advancing contact angle on Ti3C2T x on both substrates were proved to be independent of the number of Ti3C2T x layers, demonstrating a negligible effect of the background substrate wettability. In addition, a giant contact angle hysteresis (44–52 °) was observed on very smooth surface, most likely as a result of chemical heterogeneity arising from the diversity of surface terminal groups (F, O, and OH). The findings reported in this study provide a comprehensive understanding of the wettability of MXene. |
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Wettability of MXene films |
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Hofbauerová, Monika Soyka, Yaryna Stepura, Anastasiia Truchan, Daniel Halahovets, Yuriy Mičušík, Matej Šiffalovič, Peter Majková, Eva Omastová, Mária |
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| score |
7.402356 |