Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow

As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Li, Jian [verfasserIn] Zhao, Fang [verfasserIn] Fan, Wenting [verfasserIn] Chen, Ming [verfasserIn] Guo, Xuhong [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	Homogeneous photocatalytic reaction kinetics Automatic control Continuous microflow Reaction rate equation Photocatalyst concentration Light intensity

Übergeordnetes Werk:	Enthalten in: The chemical engineering journal - Amsterdam : Elsevier, 1997, 447
Übergeordnetes Werk:	volume:447

DOI / URN:	10.1016/j.cej.2022.137546

Katalog-ID:	ELV008133964

Internformat


LEADER	01000caa a22002652 4500
001	ELV008133964
003	DE-627
005	20230524131820.0
007	cr uuu---uuuuu
008	230508s2022 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.1016/j.cej.2022.137546 \|2 doi
035			\|a (DE-627)ELV008133964
035			\|a (ELSEVIER)S1385-8947(22)03034-0
040			\|a DE-627 \|b ger \|c DE-627 \|e rda
041			\|a eng
082	0		\|a 660.05 \|q DE-101
082	0	4	\|a 660 \|q DE-101
082	0	4	\|a 660 \|q DE-600
084			\|a 58.10 \|2 bkl
100	1		\|a Li, Jian \|e verfasserin \|4 aut
245	1	0	\|a Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow
264		1	\|c 2022
336			\|a nicht spezifiziert \|b zzz \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions.
650		4	\|a Homogeneous photocatalytic reaction kinetics
650		4	\|a Automatic control
650		4	\|a Continuous microflow
650		4	\|a Reaction rate equation
650		4	\|a Photocatalyst concentration
650		4	\|a Light intensity
700	1		\|a Zhao, Fang \|e verfasserin \|4 aut
700	1		\|a Fan, Wenting \|e verfasserin \|4 aut
700	1		\|a Chen, Ming \|e verfasserin \|4 aut
700	1		\|a Guo, Xuhong \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t The chemical engineering journal \|d Amsterdam : Elsevier, 1997 \|g 447 \|h Online-Ressource \|w (DE-627)320500322 \|w (DE-600)2012137-4 \|w (DE-576)098330152 \|x 1873-3212 \|7 nnns
773	1	8	\|g volume:447
912			\|a GBV_USEFLAG_U
912			\|a SYSFLAG_U
912			\|a GBV_ELV
912			\|a SSG-OLC-PHA
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 58.10 \|j Verfahrenstechnik: Allgemeines
951			\|a AR
952			\|d 447
953			\|2 045F \|a 660.05

Indexfelder

author_variant	j l jl f z fz w f wf m c mc x g xg
matchkey_str	article:18733212:2022----::uoaimaueetnaayiokntcfrhtctltcecin
hierarchy_sort_str	2022
bklnumber	58.10
publishDate	2022
allfields	10.1016/j.cej.2022.137546 doi (DE-627)ELV008133964 (ELSEVIER)S1385-8947(22)03034-0 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Li, Jian verfasserin aut Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions. Homogeneous photocatalytic reaction kinetics Automatic control Continuous microflow Reaction rate equation Photocatalyst concentration Light intensity Zhao, Fang verfasserin aut Fan, Wenting verfasserin aut Chen, Ming verfasserin aut Guo, Xuhong verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 447 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:447 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 447 045F 660.05
spelling	10.1016/j.cej.2022.137546 doi (DE-627)ELV008133964 (ELSEVIER)S1385-8947(22)03034-0 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Li, Jian verfasserin aut Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions. Homogeneous photocatalytic reaction kinetics Automatic control Continuous microflow Reaction rate equation Photocatalyst concentration Light intensity Zhao, Fang verfasserin aut Fan, Wenting verfasserin aut Chen, Ming verfasserin aut Guo, Xuhong verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 447 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:447 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 447 045F 660.05
allfields_unstemmed	10.1016/j.cej.2022.137546 doi (DE-627)ELV008133964 (ELSEVIER)S1385-8947(22)03034-0 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Li, Jian verfasserin aut Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions. Homogeneous photocatalytic reaction kinetics Automatic control Continuous microflow Reaction rate equation Photocatalyst concentration Light intensity Zhao, Fang verfasserin aut Fan, Wenting verfasserin aut Chen, Ming verfasserin aut Guo, Xuhong verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 447 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:447 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 447 045F 660.05
allfieldsGer	10.1016/j.cej.2022.137546 doi (DE-627)ELV008133964 (ELSEVIER)S1385-8947(22)03034-0 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Li, Jian verfasserin aut Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions. Homogeneous photocatalytic reaction kinetics Automatic control Continuous microflow Reaction rate equation Photocatalyst concentration Light intensity Zhao, Fang verfasserin aut Fan, Wenting verfasserin aut Chen, Ming verfasserin aut Guo, Xuhong verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 447 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:447 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 447 045F 660.05
allfieldsSound	10.1016/j.cej.2022.137546 doi (DE-627)ELV008133964 (ELSEVIER)S1385-8947(22)03034-0 DE-627 ger DE-627 rda eng 660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Li, Jian verfasserin aut Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions. Homogeneous photocatalytic reaction kinetics Automatic control Continuous microflow Reaction rate equation Photocatalyst concentration Light intensity Zhao, Fang verfasserin aut Fan, Wenting verfasserin aut Chen, Ming verfasserin aut Guo, Xuhong verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 447 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:447 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines AR 447 045F 660.05
language	English
source	Enthalten in The chemical engineering journal 447 volume:447
sourceStr	Enthalten in The chemical engineering journal 447 volume:447
format_phy_str_mv	Article
bklname	Verfahrenstechnik: Allgemeines
institution	findex.gbv.de
topic_facet	Homogeneous photocatalytic reaction kinetics Automatic control Continuous microflow Reaction rate equation Photocatalyst concentration Light intensity
dewey-raw	660.05
isfreeaccess_bool	false
container_title	The chemical engineering journal
authorswithroles_txt_mv	Li, Jian @@aut@@ Zhao, Fang @@aut@@ Fan, Wenting @@aut@@ Chen, Ming @@aut@@ Guo, Xuhong @@aut@@
publishDateDaySort_date	2022-01-01T00:00:00Z
hierarchy_top_id	320500322
dewey-sort	3660.05
id	ELV008133964
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV008133964</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524131820.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230508s2022 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.cej.2022.137546</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV008133964</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S1385-8947(22)03034-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">660.05</subfield><subfield code="q">DE-101</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-101</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.10</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Li, Jian</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Homogeneous photocatalytic reaction kinetics</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Automatic control</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Continuous microflow</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Reaction rate equation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Photocatalyst concentration</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Light intensity</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhao, Fang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Fan, Wenting</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Ming</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Guo, Xuhong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">The chemical engineering journal</subfield><subfield code="d">Amsterdam : Elsevier, 1997</subfield><subfield code="g">447</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)320500322</subfield><subfield code="w">(DE-600)2012137-4</subfield><subfield code="w">(DE-576)098330152</subfield><subfield code="x">1873-3212</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:447</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.10</subfield><subfield code="j">Verfahrenstechnik: Allgemeines</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">447</subfield></datafield><datafield tag="953" ind1=" " ind2=" "><subfield code="2">045F</subfield><subfield code="a">660.05</subfield></datafield></record></collection>
author	Li, Jian
spellingShingle	Li, Jian ddc 660.05 ddc 660 bkl 58.10 misc Homogeneous photocatalytic reaction kinetics misc Automatic control misc Continuous microflow misc Reaction rate equation misc Photocatalyst concentration misc Light intensity Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow
authorStr	Li, Jian
ppnlink_with_tag_str_mv	@@773@@(DE-627)320500322
format	electronic Article
dewey-ones	660 - Chemical engineering
delete_txt_mv	keep
author_role	aut aut aut aut aut
collection	elsevier
remote_str	true
illustrated	Not Illustrated
issn	1873-3212
topic_title	660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow Homogeneous photocatalytic reaction kinetics Automatic control Continuous microflow Reaction rate equation Photocatalyst concentration Light intensity
topic	ddc 660.05 ddc 660 bkl 58.10 misc Homogeneous photocatalytic reaction kinetics misc Automatic control misc Continuous microflow misc Reaction rate equation misc Photocatalyst concentration misc Light intensity
topic_unstemmed	ddc 660.05 ddc 660 bkl 58.10 misc Homogeneous photocatalytic reaction kinetics misc Automatic control misc Continuous microflow misc Reaction rate equation misc Photocatalyst concentration misc Light intensity
topic_browse	ddc 660.05 ddc 660 bkl 58.10 misc Homogeneous photocatalytic reaction kinetics misc Automatic control misc Continuous microflow misc Reaction rate equation misc Photocatalyst concentration misc Light intensity
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	The chemical engineering journal
hierarchy_parent_id	320500322
dewey-tens	660 - Chemical engineering
hierarchy_top_title	The chemical engineering journal
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152
title	Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow
ctrlnum	(DE-627)ELV008133964 (ELSEVIER)S1385-8947(22)03034-0
title_full	Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow
author_sort	Li, Jian
journal	The chemical engineering journal
journalStr	The chemical engineering journal
lang_code	eng
isOA_bool	false
dewey-hundreds	600 - Technology
recordtype	marc
publishDateSort	2022
contenttype_str_mv	zzz
author_browse	Li, Jian Zhao, Fang Fan, Wenting Chen, Ming Guo, Xuhong
container_volume	447
class	660.05 DE-101 660 DE-101 660 DE-600 58.10 bkl
format_se	Elektronische Aufsätze
author-letter	Li, Jian
doi_str_mv	10.1016/j.cej.2022.137546
dewey-full	660.05 660
author2-role	verfasserin
title_sort	automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow
title_auth	Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow
abstract	As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions.
abstractGer	As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions.
abstract_unstemmed	As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions.
collection_details	GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393
title_short	Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow
remote_bool	true
author2	Zhao, Fang Fan, Wenting Chen, Ming Guo, Xuhong
author2Str	Zhao, Fang Fan, Wenting Chen, Ming Guo, Xuhong
ppnlink	320500322
mediatype_str_mv	c
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1016/j.cej.2022.137546
up_date	2024-07-06T18:39:37.178Z
_version_	1803856041402695680
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV008133964</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524131820.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230508s2022 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.cej.2022.137546</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV008133964</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S1385-8947(22)03034-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">660.05</subfield><subfield code="q">DE-101</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-101</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.10</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Li, Jian</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">As photocatalysis has been demonstrated to be a powerful tool for chemical synthesis over the last decades, it is essential to acquire reaction kinetics and kinetic model for the implementation of photocatalytic reactions. However, traditional kinetic study for photocatalytic reactions has problems including low accuracy, repeatability and efficiency in measurement, and difficulty in controlling the reaction conditions. Herein, we report an automatic continuous microflow platform for kinetics measurement and analysis of homogeneous photocatalytic reactions, with accurate control of reaction conditions (species concentrations, light intensity and residence time), efficient online measurement and sophisticated data analysis. Via the automatic platform, the rate law for the homogeneous photocatalysis of 9,10-diphenylanthracene (DPA) was acquired by investigating 70 different reaction conditions in 14 h, from which the reaction orders with respect to light intensity, photocatalyst concentration and substrate concentration were determined as 0.62, 0.82 and 1.00, respectively. Subsequently, a reaction rate constant independent of species concentration, light intensity and residence time was derived (with a value of 1.00). By doing so, reaction kinetics and the influence of multiple factors manifested in the as-derived rate law in a direct and concise manner. Furtherly, the as-obtained rate law was demonstrated to make good predictions on reaction kinetics, with an average of relative deviations of 3.18%, even for a range of new reaction conditions extending that used to obtain the rate law. The automatic kinetics measurement and analysis platform and the rate law incorporating the influence of multiple factors reported in this work can pave the way towards deeper understanding and faster implementation of homogeneous photocatalytic reactions.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Homogeneous photocatalytic reaction kinetics</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Automatic control</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Continuous microflow</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Reaction rate equation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Photocatalyst concentration</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Light intensity</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhao, Fang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Fan, Wenting</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Ming</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Guo, Xuhong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">The chemical engineering journal</subfield><subfield code="d">Amsterdam : Elsevier, 1997</subfield><subfield code="g">447</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)320500322</subfield><subfield code="w">(DE-600)2012137-4</subfield><subfield code="w">(DE-576)098330152</subfield><subfield code="x">1873-3212</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:447</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.10</subfield><subfield code="j">Verfahrenstechnik: Allgemeines</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">447</subfield></datafield><datafield tag="953" ind1=" " ind2=" "><subfield code="2">045F</subfield><subfield code="a">660.05</subfield></datafield></record></collection>
score	7.39939

Nicht das Richtige dabei?

Schreiben Sie uns!

Automatic measurement and analysis of kinetics for photocatalytic reactions in continuous microflow

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?