Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite
In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan...
Ausführliche Beschreibung
Autor*in: |
Dai, Hongjie [verfasserIn] Peng, Lin [verfasserIn] Wang, Hongxia [verfasserIn] Feng, Xin [verfasserIn] Ma, Liang [verfasserIn] Chen, Hai [verfasserIn] Yu, Yong [verfasserIn] Zhu, Hankun [verfasserIn] Zhang, Yuhao [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Food hydrocolloids - Amsterdam : Elsevier, 1986, 132 |
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Übergeordnetes Werk: |
volume:132 |
DOI / URN: |
10.1016/j.foodhyd.2022.107870 |
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Katalog-ID: |
ELV008150265 |
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245 | 1 | 0 | |a Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite |
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520 | |a In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan composite bilayer films (G + MMT-CS) involved transglutaminase (TG) cross-linking followed by ethanol precipitation and self-assembly process. The water contact angle of the composite bilayer films (G-CS and G + MMT-CS) was higher than 110° due to the formation of surface hydrophobic layer formed by self-assembly via hydrogen bonding and electrostatic interaction between gelatin and chitosan, but the MMT alone cannot improve the hydrophobicity of gelatin films. The water solubility (WS) of G + MMT, G-CS and G + MMT-CS films was significantly lower than that of G films. The mechanical and barrier properties were significantly improved due to the introduction of MMT and the surface deposition of chitosan, attributing to the increase of triple helix content and formation of bilayer structure, respectively. Moreover, MMT caused the decrease of sterilization thermal shrinkage from 49.54% to 34.00%. Interestingly, MMT facilitated the surface deposition of chitosan during self-assembly process. The mold growth of bread wrapped with G + MMT-CS was effectively inhibited during storage, implying potential application as antimicrobial food packaging materials. | ||
650 | 4 | |a Gelatin | |
650 | 4 | |a Chitosan | |
650 | 4 | |a Montmorillonite | |
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650 | 4 | |a Self-assembly | |
700 | 1 | |a Peng, Lin |e verfasserin |4 aut | |
700 | 1 | |a Wang, Hongxia |e verfasserin |4 aut | |
700 | 1 | |a Feng, Xin |e verfasserin |0 (orcid)0000-0002-9695-1542 |4 aut | |
700 | 1 | |a Ma, Liang |e verfasserin |4 aut | |
700 | 1 | |a Chen, Hai |e verfasserin |4 aut | |
700 | 1 | |a Yu, Yong |e verfasserin |4 aut | |
700 | 1 | |a Zhu, Hankun |e verfasserin |4 aut | |
700 | 1 | |a Zhang, Yuhao |e verfasserin |4 aut | |
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2022 |
allfields |
10.1016/j.foodhyd.2022.107870 doi (DE-627)ELV008150265 (ELSEVIER)S0268-005X(22)00390-3 DE-627 ger DE-627 rda eng 630 640 DE-600 58.34 bkl Dai, Hongjie verfasserin aut Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan composite bilayer films (G + MMT-CS) involved transglutaminase (TG) cross-linking followed by ethanol precipitation and self-assembly process. The water contact angle of the composite bilayer films (G-CS and G + MMT-CS) was higher than 110° due to the formation of surface hydrophobic layer formed by self-assembly via hydrogen bonding and electrostatic interaction between gelatin and chitosan, but the MMT alone cannot improve the hydrophobicity of gelatin films. The water solubility (WS) of G + MMT, G-CS and G + MMT-CS films was significantly lower than that of G films. The mechanical and barrier properties were significantly improved due to the introduction of MMT and the surface deposition of chitosan, attributing to the increase of triple helix content and formation of bilayer structure, respectively. Moreover, MMT caused the decrease of sterilization thermal shrinkage from 49.54% to 34.00%. Interestingly, MMT facilitated the surface deposition of chitosan during self-assembly process. The mold growth of bread wrapped with G + MMT-CS was effectively inhibited during storage, implying potential application as antimicrobial food packaging materials. Gelatin Chitosan Montmorillonite Film Self-assembly Peng, Lin verfasserin aut Wang, Hongxia verfasserin aut Feng, Xin verfasserin (orcid)0000-0002-9695-1542 aut Ma, Liang verfasserin aut Chen, Hai verfasserin aut Yu, Yong verfasserin aut Zhu, Hankun verfasserin aut Zhang, Yuhao verfasserin aut Enthalten in Food hydrocolloids Amsterdam : Elsevier, 1986 132 Online-Ressource (DE-627)324455631 (DE-600)2026957-2 (DE-576)259271993 1873-7137 nnns volume:132 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie AR 132 |
spelling |
10.1016/j.foodhyd.2022.107870 doi (DE-627)ELV008150265 (ELSEVIER)S0268-005X(22)00390-3 DE-627 ger DE-627 rda eng 630 640 DE-600 58.34 bkl Dai, Hongjie verfasserin aut Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan composite bilayer films (G + MMT-CS) involved transglutaminase (TG) cross-linking followed by ethanol precipitation and self-assembly process. The water contact angle of the composite bilayer films (G-CS and G + MMT-CS) was higher than 110° due to the formation of surface hydrophobic layer formed by self-assembly via hydrogen bonding and electrostatic interaction between gelatin and chitosan, but the MMT alone cannot improve the hydrophobicity of gelatin films. The water solubility (WS) of G + MMT, G-CS and G + MMT-CS films was significantly lower than that of G films. The mechanical and barrier properties were significantly improved due to the introduction of MMT and the surface deposition of chitosan, attributing to the increase of triple helix content and formation of bilayer structure, respectively. Moreover, MMT caused the decrease of sterilization thermal shrinkage from 49.54% to 34.00%. Interestingly, MMT facilitated the surface deposition of chitosan during self-assembly process. The mold growth of bread wrapped with G + MMT-CS was effectively inhibited during storage, implying potential application as antimicrobial food packaging materials. Gelatin Chitosan Montmorillonite Film Self-assembly Peng, Lin verfasserin aut Wang, Hongxia verfasserin aut Feng, Xin verfasserin (orcid)0000-0002-9695-1542 aut Ma, Liang verfasserin aut Chen, Hai verfasserin aut Yu, Yong verfasserin aut Zhu, Hankun verfasserin aut Zhang, Yuhao verfasserin aut Enthalten in Food hydrocolloids Amsterdam : Elsevier, 1986 132 Online-Ressource (DE-627)324455631 (DE-600)2026957-2 (DE-576)259271993 1873-7137 nnns volume:132 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie AR 132 |
allfields_unstemmed |
10.1016/j.foodhyd.2022.107870 doi (DE-627)ELV008150265 (ELSEVIER)S0268-005X(22)00390-3 DE-627 ger DE-627 rda eng 630 640 DE-600 58.34 bkl Dai, Hongjie verfasserin aut Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan composite bilayer films (G + MMT-CS) involved transglutaminase (TG) cross-linking followed by ethanol precipitation and self-assembly process. The water contact angle of the composite bilayer films (G-CS and G + MMT-CS) was higher than 110° due to the formation of surface hydrophobic layer formed by self-assembly via hydrogen bonding and electrostatic interaction between gelatin and chitosan, but the MMT alone cannot improve the hydrophobicity of gelatin films. The water solubility (WS) of G + MMT, G-CS and G + MMT-CS films was significantly lower than that of G films. The mechanical and barrier properties were significantly improved due to the introduction of MMT and the surface deposition of chitosan, attributing to the increase of triple helix content and formation of bilayer structure, respectively. Moreover, MMT caused the decrease of sterilization thermal shrinkage from 49.54% to 34.00%. Interestingly, MMT facilitated the surface deposition of chitosan during self-assembly process. The mold growth of bread wrapped with G + MMT-CS was effectively inhibited during storage, implying potential application as antimicrobial food packaging materials. Gelatin Chitosan Montmorillonite Film Self-assembly Peng, Lin verfasserin aut Wang, Hongxia verfasserin aut Feng, Xin verfasserin (orcid)0000-0002-9695-1542 aut Ma, Liang verfasserin aut Chen, Hai verfasserin aut Yu, Yong verfasserin aut Zhu, Hankun verfasserin aut Zhang, Yuhao verfasserin aut Enthalten in Food hydrocolloids Amsterdam : Elsevier, 1986 132 Online-Ressource (DE-627)324455631 (DE-600)2026957-2 (DE-576)259271993 1873-7137 nnns volume:132 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie AR 132 |
allfieldsGer |
10.1016/j.foodhyd.2022.107870 doi (DE-627)ELV008150265 (ELSEVIER)S0268-005X(22)00390-3 DE-627 ger DE-627 rda eng 630 640 DE-600 58.34 bkl Dai, Hongjie verfasserin aut Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan composite bilayer films (G + MMT-CS) involved transglutaminase (TG) cross-linking followed by ethanol precipitation and self-assembly process. The water contact angle of the composite bilayer films (G-CS and G + MMT-CS) was higher than 110° due to the formation of surface hydrophobic layer formed by self-assembly via hydrogen bonding and electrostatic interaction between gelatin and chitosan, but the MMT alone cannot improve the hydrophobicity of gelatin films. The water solubility (WS) of G + MMT, G-CS and G + MMT-CS films was significantly lower than that of G films. The mechanical and barrier properties were significantly improved due to the introduction of MMT and the surface deposition of chitosan, attributing to the increase of triple helix content and formation of bilayer structure, respectively. Moreover, MMT caused the decrease of sterilization thermal shrinkage from 49.54% to 34.00%. Interestingly, MMT facilitated the surface deposition of chitosan during self-assembly process. The mold growth of bread wrapped with G + MMT-CS was effectively inhibited during storage, implying potential application as antimicrobial food packaging materials. Gelatin Chitosan Montmorillonite Film Self-assembly Peng, Lin verfasserin aut Wang, Hongxia verfasserin aut Feng, Xin verfasserin (orcid)0000-0002-9695-1542 aut Ma, Liang verfasserin aut Chen, Hai verfasserin aut Yu, Yong verfasserin aut Zhu, Hankun verfasserin aut Zhang, Yuhao verfasserin aut Enthalten in Food hydrocolloids Amsterdam : Elsevier, 1986 132 Online-Ressource (DE-627)324455631 (DE-600)2026957-2 (DE-576)259271993 1873-7137 nnns volume:132 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie AR 132 |
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10.1016/j.foodhyd.2022.107870 doi (DE-627)ELV008150265 (ELSEVIER)S0268-005X(22)00390-3 DE-627 ger DE-627 rda eng 630 640 DE-600 58.34 bkl Dai, Hongjie verfasserin aut Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan composite bilayer films (G + MMT-CS) involved transglutaminase (TG) cross-linking followed by ethanol precipitation and self-assembly process. The water contact angle of the composite bilayer films (G-CS and G + MMT-CS) was higher than 110° due to the formation of surface hydrophobic layer formed by self-assembly via hydrogen bonding and electrostatic interaction between gelatin and chitosan, but the MMT alone cannot improve the hydrophobicity of gelatin films. The water solubility (WS) of G + MMT, G-CS and G + MMT-CS films was significantly lower than that of G films. The mechanical and barrier properties were significantly improved due to the introduction of MMT and the surface deposition of chitosan, attributing to the increase of triple helix content and formation of bilayer structure, respectively. Moreover, MMT caused the decrease of sterilization thermal shrinkage from 49.54% to 34.00%. Interestingly, MMT facilitated the surface deposition of chitosan during self-assembly process. The mold growth of bread wrapped with G + MMT-CS was effectively inhibited during storage, implying potential application as antimicrobial food packaging materials. Gelatin Chitosan Montmorillonite Film Self-assembly Peng, Lin verfasserin aut Wang, Hongxia verfasserin aut Feng, Xin verfasserin (orcid)0000-0002-9695-1542 aut Ma, Liang verfasserin aut Chen, Hai verfasserin aut Yu, Yong verfasserin aut Zhu, Hankun verfasserin aut Zhang, Yuhao verfasserin aut Enthalten in Food hydrocolloids Amsterdam : Elsevier, 1986 132 Online-Ressource (DE-627)324455631 (DE-600)2026957-2 (DE-576)259271993 1873-7137 nnns volume:132 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.34 Lebensmitteltechnologie AR 132 |
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630 640 DE-600 58.34 bkl Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite Gelatin Chitosan Montmorillonite Film Self-assembly |
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Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite |
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Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite |
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Dai, Hongjie |
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Dai, Hongjie Peng, Lin Wang, Hongxia Feng, Xin Ma, Liang Chen, Hai Yu, Yong Zhu, Hankun Zhang, Yuhao |
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10.1016/j.foodhyd.2022.107870 |
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title_sort |
improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: the self-assembly role of chitosan and montmorillonite |
title_auth |
Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite |
abstract |
In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan composite bilayer films (G + MMT-CS) involved transglutaminase (TG) cross-linking followed by ethanol precipitation and self-assembly process. The water contact angle of the composite bilayer films (G-CS and G + MMT-CS) was higher than 110° due to the formation of surface hydrophobic layer formed by self-assembly via hydrogen bonding and electrostatic interaction between gelatin and chitosan, but the MMT alone cannot improve the hydrophobicity of gelatin films. The water solubility (WS) of G + MMT, G-CS and G + MMT-CS films was significantly lower than that of G films. The mechanical and barrier properties were significantly improved due to the introduction of MMT and the surface deposition of chitosan, attributing to the increase of triple helix content and formation of bilayer structure, respectively. Moreover, MMT caused the decrease of sterilization thermal shrinkage from 49.54% to 34.00%. Interestingly, MMT facilitated the surface deposition of chitosan during self-assembly process. The mold growth of bread wrapped with G + MMT-CS was effectively inhibited during storage, implying potential application as antimicrobial food packaging materials. |
abstractGer |
In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan composite bilayer films (G + MMT-CS) involved transglutaminase (TG) cross-linking followed by ethanol precipitation and self-assembly process. The water contact angle of the composite bilayer films (G-CS and G + MMT-CS) was higher than 110° due to the formation of surface hydrophobic layer formed by self-assembly via hydrogen bonding and electrostatic interaction between gelatin and chitosan, but the MMT alone cannot improve the hydrophobicity of gelatin films. The water solubility (WS) of G + MMT, G-CS and G + MMT-CS films was significantly lower than that of G films. The mechanical and barrier properties were significantly improved due to the introduction of MMT and the surface deposition of chitosan, attributing to the increase of triple helix content and formation of bilayer structure, respectively. Moreover, MMT caused the decrease of sterilization thermal shrinkage from 49.54% to 34.00%. Interestingly, MMT facilitated the surface deposition of chitosan during self-assembly process. The mold growth of bread wrapped with G + MMT-CS was effectively inhibited during storage, implying potential application as antimicrobial food packaging materials. |
abstract_unstemmed |
In this study, the chitosan and montmorillonite (MMT) were synergistically introduced to improve the properties of the gelatin films through self-assembly. The preparation of gelatin films (G), gelatin + MMT composite films (G + MMT), gelatin-chitosan bilayer films (G-CS), and gelatin + MMT-chitosan composite bilayer films (G + MMT-CS) involved transglutaminase (TG) cross-linking followed by ethanol precipitation and self-assembly process. The water contact angle of the composite bilayer films (G-CS and G + MMT-CS) was higher than 110° due to the formation of surface hydrophobic layer formed by self-assembly via hydrogen bonding and electrostatic interaction between gelatin and chitosan, but the MMT alone cannot improve the hydrophobicity of gelatin films. The water solubility (WS) of G + MMT, G-CS and G + MMT-CS films was significantly lower than that of G films. The mechanical and barrier properties were significantly improved due to the introduction of MMT and the surface deposition of chitosan, attributing to the increase of triple helix content and formation of bilayer structure, respectively. Moreover, MMT caused the decrease of sterilization thermal shrinkage from 49.54% to 34.00%. Interestingly, MMT facilitated the surface deposition of chitosan during self-assembly process. The mold growth of bread wrapped with G + MMT-CS was effectively inhibited during storage, implying potential application as antimicrobial food packaging materials. |
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title_short |
Improved properties of gelatin films involving transglutaminase cross-linking and ethanol dehydration: The self-assembly role of chitosan and montmorillonite |
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