Solubility Phase Diagrams of ternary systems of CsCl–CdCl

Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof...
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Autor*in:	Qiao, Zhan-Ping [verfasserIn] Chen, Xin [verfasserIn] Yang, Qi-Chao [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	Phase equilibrium Cesium chloride Cesium bromide Cadmium chloride Cadmium bromide Standard molar enthalpy of formation

Übergeordnetes Werk:	Enthalten in: The journal of chemical thermodynamics - London : Academic Press, 1969, 173
Übergeordnetes Werk:	volume:173

DOI / URN:	10.1016/j.jct.2022.106852

Katalog-ID:	ELV008174865

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245	1	0	\|a Solubility Phase Diagrams of ternary systems of CsCl–CdCl
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520			\|a Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof the system CsBr–CdBr2–H2O contains five crystallization fields for the solidphases CdBr2·4H2O, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 and CsBr. The new solidphasesof CsCdCl3 and CsCdBr3 are congruently soluble, and Cs2CdCl4, Cs5Cd2Br9 and Cs3CdBr5 are incongruently soluble in the aqueous system. The experimental solubility data and phase diagrams for the ternary systems show more practical application for the obtained cadmium-based halide perovskite. The five new solid phase have been analyzed by X-ray diffraction and thermogravimetry/derivative thermogravimetry. By measuring the standard molar enthalpies of solution of the compounds, the standard molar enthalpies of formation of CsCdCl3, Cs2CdCl4, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 were determined to be –(873.3 ± 0.7) kJ·mol−1, –(1325.6 ± 0.9) kJ·mol−1, –(742.8 ± 0.7) kJ·mol−1, –(2710.0 ± 1.3) kJ·mol−1 and –(1558.1 ± 1.0) kJ·mol−1, respectively.
650		4	\|a Phase equilibrium
650		4	\|a Cesium chloride
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650		4	\|a Cadmium chloride
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650		4	\|a Standard molar enthalpy of formation
700	1		\|a Chen, Xin \|e verfasserin \|4 aut
700	1		\|a Yang, Qi-Chao \|e verfasserin \|4 aut
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912			\|a GBV_ILN_2021
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912			\|a GBV_ILN_4393
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allfields	10.1016/j.jct.2022.106852 doi (DE-627)ELV008174865 (ELSEVIER)S0021-9614(22)00131-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Qiao, Zhan-Ping verfasserin aut Solubility Phase Diagrams of ternary systems of CsCl–CdCl 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof the system CsBr–CdBr2–H2O contains five crystallization fields for the solidphases CdBr2·4H2O, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 and CsBr. The new solidphasesof CsCdCl3 and CsCdBr3 are congruently soluble, and Cs2CdCl4, Cs5Cd2Br9 and Cs3CdBr5 are incongruently soluble in the aqueous system. The experimental solubility data and phase diagrams for the ternary systems show more practical application for the obtained cadmium-based halide perovskite. The five new solid phase have been analyzed by X-ray diffraction and thermogravimetry/derivative thermogravimetry. By measuring the standard molar enthalpies of solution of the compounds, the standard molar enthalpies of formation of CsCdCl3, Cs2CdCl4, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 were determined to be –(873.3 ± 0.7) kJ·mol−1, –(1325.6 ± 0.9) kJ·mol−1, –(742.8 ± 0.7) kJ·mol−1, –(2710.0 ± 1.3) kJ·mol−1 and –(1558.1 ± 1.0) kJ·mol−1, respectively. Phase equilibrium Cesium chloride Cesium bromide Cadmium chloride Cadmium bromide Standard molar enthalpy of formation Chen, Xin verfasserin aut Yang, Qi-Chao verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 173 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:173 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 173
spelling	10.1016/j.jct.2022.106852 doi (DE-627)ELV008174865 (ELSEVIER)S0021-9614(22)00131-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Qiao, Zhan-Ping verfasserin aut Solubility Phase Diagrams of ternary systems of CsCl–CdCl 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof the system CsBr–CdBr2–H2O contains five crystallization fields for the solidphases CdBr2·4H2O, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 and CsBr. The new solidphasesof CsCdCl3 and CsCdBr3 are congruently soluble, and Cs2CdCl4, Cs5Cd2Br9 and Cs3CdBr5 are incongruently soluble in the aqueous system. The experimental solubility data and phase diagrams for the ternary systems show more practical application for the obtained cadmium-based halide perovskite. The five new solid phase have been analyzed by X-ray diffraction and thermogravimetry/derivative thermogravimetry. By measuring the standard molar enthalpies of solution of the compounds, the standard molar enthalpies of formation of CsCdCl3, Cs2CdCl4, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 were determined to be –(873.3 ± 0.7) kJ·mol−1, –(1325.6 ± 0.9) kJ·mol−1, –(742.8 ± 0.7) kJ·mol−1, –(2710.0 ± 1.3) kJ·mol−1 and –(1558.1 ± 1.0) kJ·mol−1, respectively. Phase equilibrium Cesium chloride Cesium bromide Cadmium chloride Cadmium bromide Standard molar enthalpy of formation Chen, Xin verfasserin aut Yang, Qi-Chao verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 173 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:173 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 173
allfields_unstemmed	10.1016/j.jct.2022.106852 doi (DE-627)ELV008174865 (ELSEVIER)S0021-9614(22)00131-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Qiao, Zhan-Ping verfasserin aut Solubility Phase Diagrams of ternary systems of CsCl–CdCl 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof the system CsBr–CdBr2–H2O contains five crystallization fields for the solidphases CdBr2·4H2O, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 and CsBr. The new solidphasesof CsCdCl3 and CsCdBr3 are congruently soluble, and Cs2CdCl4, Cs5Cd2Br9 and Cs3CdBr5 are incongruently soluble in the aqueous system. The experimental solubility data and phase diagrams for the ternary systems show more practical application for the obtained cadmium-based halide perovskite. The five new solid phase have been analyzed by X-ray diffraction and thermogravimetry/derivative thermogravimetry. By measuring the standard molar enthalpies of solution of the compounds, the standard molar enthalpies of formation of CsCdCl3, Cs2CdCl4, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 were determined to be –(873.3 ± 0.7) kJ·mol−1, –(1325.6 ± 0.9) kJ·mol−1, –(742.8 ± 0.7) kJ·mol−1, –(2710.0 ± 1.3) kJ·mol−1 and –(1558.1 ± 1.0) kJ·mol−1, respectively. Phase equilibrium Cesium chloride Cesium bromide Cadmium chloride Cadmium bromide Standard molar enthalpy of formation Chen, Xin verfasserin aut Yang, Qi-Chao verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 173 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:173 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 173
allfieldsGer	10.1016/j.jct.2022.106852 doi (DE-627)ELV008174865 (ELSEVIER)S0021-9614(22)00131-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Qiao, Zhan-Ping verfasserin aut Solubility Phase Diagrams of ternary systems of CsCl–CdCl 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof the system CsBr–CdBr2–H2O contains five crystallization fields for the solidphases CdBr2·4H2O, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 and CsBr. The new solidphasesof CsCdCl3 and CsCdBr3 are congruently soluble, and Cs2CdCl4, Cs5Cd2Br9 and Cs3CdBr5 are incongruently soluble in the aqueous system. The experimental solubility data and phase diagrams for the ternary systems show more practical application for the obtained cadmium-based halide perovskite. The five new solid phase have been analyzed by X-ray diffraction and thermogravimetry/derivative thermogravimetry. By measuring the standard molar enthalpies of solution of the compounds, the standard molar enthalpies of formation of CsCdCl3, Cs2CdCl4, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 were determined to be –(873.3 ± 0.7) kJ·mol−1, –(1325.6 ± 0.9) kJ·mol−1, –(742.8 ± 0.7) kJ·mol−1, –(2710.0 ± 1.3) kJ·mol−1 and –(1558.1 ± 1.0) kJ·mol−1, respectively. Phase equilibrium Cesium chloride Cesium bromide Cadmium chloride Cadmium bromide Standard molar enthalpy of formation Chen, Xin verfasserin aut Yang, Qi-Chao verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 173 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:173 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 173
allfieldsSound	10.1016/j.jct.2022.106852 doi (DE-627)ELV008174865 (ELSEVIER)S0021-9614(22)00131-8 DE-627 ger DE-627 rda eng 540 DE-600 35.00 bkl Qiao, Zhan-Ping verfasserin aut Solubility Phase Diagrams of ternary systems of CsCl–CdCl 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof the system CsBr–CdBr2–H2O contains five crystallization fields for the solidphases CdBr2·4H2O, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 and CsBr. The new solidphasesof CsCdCl3 and CsCdBr3 are congruently soluble, and Cs2CdCl4, Cs5Cd2Br9 and Cs3CdBr5 are incongruently soluble in the aqueous system. The experimental solubility data and phase diagrams for the ternary systems show more practical application for the obtained cadmium-based halide perovskite. The five new solid phase have been analyzed by X-ray diffraction and thermogravimetry/derivative thermogravimetry. By measuring the standard molar enthalpies of solution of the compounds, the standard molar enthalpies of formation of CsCdCl3, Cs2CdCl4, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 were determined to be –(873.3 ± 0.7) kJ·mol−1, –(1325.6 ± 0.9) kJ·mol−1, –(742.8 ± 0.7) kJ·mol−1, –(2710.0 ± 1.3) kJ·mol−1 and –(1558.1 ± 1.0) kJ·mol−1, respectively. Phase equilibrium Cesium chloride Cesium bromide Cadmium chloride Cadmium bromide Standard molar enthalpy of formation Chen, Xin verfasserin aut Yang, Qi-Chao verfasserin aut Enthalten in The journal of chemical thermodynamics London : Academic Press, 1969 173 Online-Ressource (DE-627)266891039 (DE-600)1469011-1 (DE-576)103373152 0021-9614 nnns volume:173 GBV_USEFLAG_U SYSFLAG_U GBV_ELV GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.00 Chemie: Allgemeines AR 173
language	English
source	Enthalten in The journal of chemical thermodynamics 173 volume:173
sourceStr	Enthalten in The journal of chemical thermodynamics 173 volume:173
format_phy_str_mv	Article
bklname	Chemie: Allgemeines
institution	findex.gbv.de
topic_facet	Phase equilibrium Cesium chloride Cesium bromide Cadmium chloride Cadmium bromide Standard molar enthalpy of formation
dewey-raw	540
isfreeaccess_bool	false
container_title	The journal of chemical thermodynamics
authorswithroles_txt_mv	Qiao, Zhan-Ping @@aut@@ Chen, Xin @@aut@@ Yang, Qi-Chao @@aut@@
publishDateDaySort_date	2022-01-01T00:00:00Z
hierarchy_top_id	266891039
dewey-sort	3540
id	ELV008174865
language_de	englisch
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author	Qiao, Zhan-Ping
spellingShingle	Qiao, Zhan-Ping ddc 540 bkl 35.00 misc Phase equilibrium misc Cesium chloride misc Cesium bromide misc Cadmium chloride misc Cadmium bromide misc Standard molar enthalpy of formation Solubility Phase Diagrams of ternary systems of CsCl–CdCl
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topic_title	540 DE-600 35.00 bkl Solubility Phase Diagrams of ternary systems of CsCl–CdCl Phase equilibrium Cesium chloride Cesium bromide Cadmium chloride Cadmium bromide Standard molar enthalpy of formation
topic	ddc 540 bkl 35.00 misc Phase equilibrium misc Cesium chloride misc Cesium bromide misc Cadmium chloride misc Cadmium bromide misc Standard molar enthalpy of formation
topic_unstemmed	ddc 540 bkl 35.00 misc Phase equilibrium misc Cesium chloride misc Cesium bromide misc Cadmium chloride misc Cadmium bromide misc Standard molar enthalpy of formation
topic_browse	ddc 540 bkl 35.00 misc Phase equilibrium misc Cesium chloride misc Cesium bromide misc Cadmium chloride misc Cadmium bromide misc Standard molar enthalpy of formation
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title	Solubility Phase Diagrams of ternary systems of CsCl–CdCl
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title_full	Solubility Phase Diagrams of ternary systems of CsCl–CdCl
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author_browse	Qiao, Zhan-Ping Chen, Xin Yang, Qi-Chao
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title_sort	solubility phase diagrams of ternary systems of cscl–cdcl
title_auth	Solubility Phase Diagrams of ternary systems of CsCl–CdCl
abstract	Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof the system CsBr–CdBr2–H2O contains five crystallization fields for the solidphases CdBr2·4H2O, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 and CsBr. The new solidphasesof CsCdCl3 and CsCdBr3 are congruently soluble, and Cs2CdCl4, Cs5Cd2Br9 and Cs3CdBr5 are incongruently soluble in the aqueous system. The experimental solubility data and phase diagrams for the ternary systems show more practical application for the obtained cadmium-based halide perovskite. The five new solid phase have been analyzed by X-ray diffraction and thermogravimetry/derivative thermogravimetry. By measuring the standard molar enthalpies of solution of the compounds, the standard molar enthalpies of formation of CsCdCl3, Cs2CdCl4, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 were determined to be –(873.3 ± 0.7) kJ·mol−1, –(1325.6 ± 0.9) kJ·mol−1, –(742.8 ± 0.7) kJ·mol−1, –(2710.0 ± 1.3) kJ·mol−1 and –(1558.1 ± 1.0) kJ·mol−1, respectively.
abstractGer	Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof the system CsBr–CdBr2–H2O contains five crystallization fields for the solidphases CdBr2·4H2O, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 and CsBr. The new solidphasesof CsCdCl3 and CsCdBr3 are congruently soluble, and Cs2CdCl4, Cs5Cd2Br9 and Cs3CdBr5 are incongruently soluble in the aqueous system. The experimental solubility data and phase diagrams for the ternary systems show more practical application for the obtained cadmium-based halide perovskite. The five new solid phase have been analyzed by X-ray diffraction and thermogravimetry/derivative thermogravimetry. By measuring the standard molar enthalpies of solution of the compounds, the standard molar enthalpies of formation of CsCdCl3, Cs2CdCl4, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 were determined to be –(873.3 ± 0.7) kJ·mol−1, –(1325.6 ± 0.9) kJ·mol−1, –(742.8 ± 0.7) kJ·mol−1, –(2710.0 ± 1.3) kJ·mol−1 and –(1558.1 ± 1.0) kJ·mol−1, respectively.
abstract_unstemmed	Using an isothermal equilibrium method, thephaseequilibrium of the ternary systems CsCl–CdCl2–H2O and CsBr–CdBr2–H2O were studied at T = 298.1 K. In thephasediagram of the system CsCl–CdCl2–H2O, the solidphasesof CsCdCl3 and Cs2CdCl4, besides CsCl and CdCl2·2.5H2O, were discovered. Thephasediagramof the system CsBr–CdBr2–H2O contains five crystallization fields for the solidphases CdBr2·4H2O, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 and CsBr. The new solidphasesof CsCdCl3 and CsCdBr3 are congruently soluble, and Cs2CdCl4, Cs5Cd2Br9 and Cs3CdBr5 are incongruently soluble in the aqueous system. The experimental solubility data and phase diagrams for the ternary systems show more practical application for the obtained cadmium-based halide perovskite. The five new solid phase have been analyzed by X-ray diffraction and thermogravimetry/derivative thermogravimetry. By measuring the standard molar enthalpies of solution of the compounds, the standard molar enthalpies of formation of CsCdCl3, Cs2CdCl4, CsCdBr3, Cs5Cd2Br9, Cs3CdBr5 were determined to be –(873.3 ± 0.7) kJ·mol−1, –(1325.6 ± 0.9) kJ·mol−1, –(742.8 ± 0.7) kJ·mol−1, –(2710.0 ± 1.3) kJ·mol−1 and –(1558.1 ± 1.0) kJ·mol−1, respectively.
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title_short	Solubility Phase Diagrams of ternary systems of CsCl–CdCl
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doi_str	10.1016/j.jct.2022.106852
up_date	2024-07-06T18:48:03.175Z
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Solubility Phase Diagrams of ternary systems of CsCl–CdCl

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