Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O

The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Li, Qiong [verfasserIn] Qian, Hao [verfasserIn] Zheng, Tianyang [verfasserIn] Sun, Xiaoyuan [verfasserIn] Liu, Yunfei [verfasserIn] Lyu, Yinong [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	Barium titanate Polar nanoregions Cation displacement BO

Übergeordnetes Werk:	Enthalten in: Journal of alloys and compounds - Lausanne : Elsevier, 1991, 922
Übergeordnetes Werk:	volume:922

DOI / URN:	10.1016/j.jallcom.2022.166210

Katalog-ID:	ELV008303916

Internformat


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520			\|a The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12CT-0.1BZS ceramic, which achieves the enhanced strain of 0.19 % with a hysteresis of 6.56 %. The atomic level structure is revealed by aberration corrected scanning transmission electron microscope (AC-STEM). The AC-STEM HAADF images reveal the coexisting of polar nanoregions with O and T symmetries. Such a microstructure has a lower energy barrier, facilitating dynamic polarization rotation flexibly under external stimuli. The AC-STEM ABF image reveals the existence of the BO6 octahedral rotation, with rotation patterns of the a 0 b 0 c 0 and a - b + c - , and rotation angles are quantitatively measured. The BO6 octahedral rotation and cation displacement are found to be consistent, the greater octahedral rotation with greater cation displacements. These results have important implications for understanding the structural origin of the excellent properties in ferroelectrics.
650		4	\|a Barium titanate
650		4	\|a Polar nanoregions
650		4	\|a Cation displacement
650		4	\|a BO
700	1		\|a Qian, Hao \|e verfasserin \|4 aut
700	1		\|a Zheng, Tianyang \|e verfasserin \|4 aut
700	1		\|a Sun, Xiaoyuan \|e verfasserin \|4 aut
700	1		\|a Liu, Yunfei \|e verfasserin \|4 aut
700	1		\|a Lyu, Yinong \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Journal of alloys and compounds \|d Lausanne : Elsevier, 1991 \|g 922 \|h Online-Ressource \|w (DE-627)320504646 \|w (DE-600)2012675-X \|w (DE-576)098615009 \|7 nnns
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912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_101
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_224
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
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912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
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912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
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912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
936	b	k	\|a 51.54 \|j Nichteisenmetalle und ihre Legierungen
936	b	k	\|a 33.61 \|j Festkörperphysik
936	b	k	\|a 35.90 \|j Festkörperchemie
951			\|a AR
952			\|d 922

Indexfelder

author_variant	q l ql h q hq t z tz x s xs y l yl y l yl
matchkey_str	liqiongqianhaozhengtianyangsunxiaoyuanli:2022----:nacdtanfa
hierarchy_sort_str	2022
bklnumber	51.54 33.61 35.90
publishDate	2022
allfields	10.1016/j.jallcom.2022.166210 doi (DE-627)ELV008303916 (ELSEVIER)S0925-8388(22)02601-9 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Li, Qiong verfasserin aut Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12CT-0.1BZS ceramic, which achieves the enhanced strain of 0.19 % with a hysteresis of 6.56 %. The atomic level structure is revealed by aberration corrected scanning transmission electron microscope (AC-STEM). The AC-STEM HAADF images reveal the coexisting of polar nanoregions with O and T symmetries. Such a microstructure has a lower energy barrier, facilitating dynamic polarization rotation flexibly under external stimuli. The AC-STEM ABF image reveals the existence of the BO6 octahedral rotation, with rotation patterns of the a 0 b 0 c 0 and a - b + c - , and rotation angles are quantitatively measured. The BO6 octahedral rotation and cation displacement are found to be consistent, the greater octahedral rotation with greater cation displacements. These results have important implications for understanding the structural origin of the excellent properties in ferroelectrics. Barium titanate Polar nanoregions Cation displacement BO Qian, Hao verfasserin aut Zheng, Tianyang verfasserin aut Sun, Xiaoyuan verfasserin aut Liu, Yunfei verfasserin aut Lyu, Yinong verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 922 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:922 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 922
spelling	10.1016/j.jallcom.2022.166210 doi (DE-627)ELV008303916 (ELSEVIER)S0925-8388(22)02601-9 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Li, Qiong verfasserin aut Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12CT-0.1BZS ceramic, which achieves the enhanced strain of 0.19 % with a hysteresis of 6.56 %. The atomic level structure is revealed by aberration corrected scanning transmission electron microscope (AC-STEM). The AC-STEM HAADF images reveal the coexisting of polar nanoregions with O and T symmetries. Such a microstructure has a lower energy barrier, facilitating dynamic polarization rotation flexibly under external stimuli. The AC-STEM ABF image reveals the existence of the BO6 octahedral rotation, with rotation patterns of the a 0 b 0 c 0 and a - b + c - , and rotation angles are quantitatively measured. The BO6 octahedral rotation and cation displacement are found to be consistent, the greater octahedral rotation with greater cation displacements. These results have important implications for understanding the structural origin of the excellent properties in ferroelectrics. Barium titanate Polar nanoregions Cation displacement BO Qian, Hao verfasserin aut Zheng, Tianyang verfasserin aut Sun, Xiaoyuan verfasserin aut Liu, Yunfei verfasserin aut Lyu, Yinong verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 922 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:922 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 922
allfields_unstemmed	10.1016/j.jallcom.2022.166210 doi (DE-627)ELV008303916 (ELSEVIER)S0925-8388(22)02601-9 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Li, Qiong verfasserin aut Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12CT-0.1BZS ceramic, which achieves the enhanced strain of 0.19 % with a hysteresis of 6.56 %. The atomic level structure is revealed by aberration corrected scanning transmission electron microscope (AC-STEM). The AC-STEM HAADF images reveal the coexisting of polar nanoregions with O and T symmetries. Such a microstructure has a lower energy barrier, facilitating dynamic polarization rotation flexibly under external stimuli. The AC-STEM ABF image reveals the existence of the BO6 octahedral rotation, with rotation patterns of the a 0 b 0 c 0 and a - b + c - , and rotation angles are quantitatively measured. The BO6 octahedral rotation and cation displacement are found to be consistent, the greater octahedral rotation with greater cation displacements. These results have important implications for understanding the structural origin of the excellent properties in ferroelectrics. Barium titanate Polar nanoregions Cation displacement BO Qian, Hao verfasserin aut Zheng, Tianyang verfasserin aut Sun, Xiaoyuan verfasserin aut Liu, Yunfei verfasserin aut Lyu, Yinong verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 922 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:922 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 922
allfieldsGer	10.1016/j.jallcom.2022.166210 doi (DE-627)ELV008303916 (ELSEVIER)S0925-8388(22)02601-9 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Li, Qiong verfasserin aut Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12CT-0.1BZS ceramic, which achieves the enhanced strain of 0.19 % with a hysteresis of 6.56 %. The atomic level structure is revealed by aberration corrected scanning transmission electron microscope (AC-STEM). The AC-STEM HAADF images reveal the coexisting of polar nanoregions with O and T symmetries. Such a microstructure has a lower energy barrier, facilitating dynamic polarization rotation flexibly under external stimuli. The AC-STEM ABF image reveals the existence of the BO6 octahedral rotation, with rotation patterns of the a 0 b 0 c 0 and a - b + c - , and rotation angles are quantitatively measured. The BO6 octahedral rotation and cation displacement are found to be consistent, the greater octahedral rotation with greater cation displacements. These results have important implications for understanding the structural origin of the excellent properties in ferroelectrics. Barium titanate Polar nanoregions Cation displacement BO Qian, Hao verfasserin aut Zheng, Tianyang verfasserin aut Sun, Xiaoyuan verfasserin aut Liu, Yunfei verfasserin aut Lyu, Yinong verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 922 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:922 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 922
allfieldsSound	10.1016/j.jallcom.2022.166210 doi (DE-627)ELV008303916 (ELSEVIER)S0925-8388(22)02601-9 DE-627 ger DE-627 rda eng 670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Li, Qiong verfasserin aut Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12CT-0.1BZS ceramic, which achieves the enhanced strain of 0.19 % with a hysteresis of 6.56 %. The atomic level structure is revealed by aberration corrected scanning transmission electron microscope (AC-STEM). The AC-STEM HAADF images reveal the coexisting of polar nanoregions with O and T symmetries. Such a microstructure has a lower energy barrier, facilitating dynamic polarization rotation flexibly under external stimuli. The AC-STEM ABF image reveals the existence of the BO6 octahedral rotation, with rotation patterns of the a 0 b 0 c 0 and a - b + c - , and rotation angles are quantitatively measured. The BO6 octahedral rotation and cation displacement are found to be consistent, the greater octahedral rotation with greater cation displacements. These results have important implications for understanding the structural origin of the excellent properties in ferroelectrics. Barium titanate Polar nanoregions Cation displacement BO Qian, Hao verfasserin aut Zheng, Tianyang verfasserin aut Sun, Xiaoyuan verfasserin aut Liu, Yunfei verfasserin aut Lyu, Yinong verfasserin aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 922 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:922 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.54 Nichteisenmetalle und ihre Legierungen 33.61 Festkörperphysik 35.90 Festkörperchemie AR 922
language	English
source	Enthalten in Journal of alloys and compounds 922 volume:922
sourceStr	Enthalten in Journal of alloys and compounds 922 volume:922
format_phy_str_mv	Article
bklname	Nichteisenmetalle und ihre Legierungen Festkörperphysik Festkörperchemie
institution	findex.gbv.de
topic_facet	Barium titanate Polar nanoregions Cation displacement BO
dewey-raw	670
isfreeaccess_bool	false
container_title	Journal of alloys and compounds
authorswithroles_txt_mv	Li, Qiong @@aut@@ Qian, Hao @@aut@@ Zheng, Tianyang @@aut@@ Sun, Xiaoyuan @@aut@@ Liu, Yunfei @@aut@@ Lyu, Yinong @@aut@@
publishDateDaySort_date	2022-01-01T00:00:00Z
hierarchy_top_id	320504646
dewey-sort	3670
id	ELV008303916
language_de	englisch
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author	Li, Qiong
spellingShingle	Li, Qiong ddc 670 bkl 51.54 bkl 33.61 bkl 35.90 misc Barium titanate misc Polar nanoregions misc Cation displacement misc BO Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O
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topic_title	670 540 DE-600 51.54 bkl 33.61 bkl 35.90 bkl Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O Barium titanate Polar nanoregions Cation displacement BO
topic	ddc 670 bkl 51.54 bkl 33.61 bkl 35.90 misc Barium titanate misc Polar nanoregions misc Cation displacement misc BO
topic_unstemmed	ddc 670 bkl 51.54 bkl 33.61 bkl 35.90 misc Barium titanate misc Polar nanoregions misc Cation displacement misc BO
topic_browse	ddc 670 bkl 51.54 bkl 33.61 bkl 35.90 misc Barium titanate misc Polar nanoregions misc Cation displacement misc BO
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title	Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O
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title_full	Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O
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doi_str_mv	10.1016/j.jallcom.2022.166210
dewey-full	670 540
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title_sort	enhanced strain of (ba, ca)(ti, zr, sn)o
title_auth	Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O
abstract	The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12CT-0.1BZS ceramic, which achieves the enhanced strain of 0.19 % with a hysteresis of 6.56 %. The atomic level structure is revealed by aberration corrected scanning transmission electron microscope (AC-STEM). The AC-STEM HAADF images reveal the coexisting of polar nanoregions with O and T symmetries. Such a microstructure has a lower energy barrier, facilitating dynamic polarization rotation flexibly under external stimuli. The AC-STEM ABF image reveals the existence of the BO6 octahedral rotation, with rotation patterns of the a 0 b 0 c 0 and a - b + c - , and rotation angles are quantitatively measured. The BO6 octahedral rotation and cation displacement are found to be consistent, the greater octahedral rotation with greater cation displacements. These results have important implications for understanding the structural origin of the excellent properties in ferroelectrics.
abstractGer	The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12CT-0.1BZS ceramic, which achieves the enhanced strain of 0.19 % with a hysteresis of 6.56 %. The atomic level structure is revealed by aberration corrected scanning transmission electron microscope (AC-STEM). The AC-STEM HAADF images reveal the coexisting of polar nanoregions with O and T symmetries. Such a microstructure has a lower energy barrier, facilitating dynamic polarization rotation flexibly under external stimuli. The AC-STEM ABF image reveals the existence of the BO6 octahedral rotation, with rotation patterns of the a 0 b 0 c 0 and a - b + c - , and rotation angles are quantitatively measured. The BO6 octahedral rotation and cation displacement are found to be consistent, the greater octahedral rotation with greater cation displacements. These results have important implications for understanding the structural origin of the excellent properties in ferroelectrics.
abstract_unstemmed	The cation displacement closely related to the local symmetry and corner-connected oxygen octahedral rotation are the structural origin of macroscopic properties in ABO3 perovskite oxides. This work describes in detail the relationship between microstructure and macroscopic properties in 0.78BT-0.12CT-0.1BZS ceramic, which achieves the enhanced strain of 0.19 % with a hysteresis of 6.56 %. The atomic level structure is revealed by aberration corrected scanning transmission electron microscope (AC-STEM). The AC-STEM HAADF images reveal the coexisting of polar nanoregions with O and T symmetries. Such a microstructure has a lower energy barrier, facilitating dynamic polarization rotation flexibly under external stimuli. The AC-STEM ABF image reveals the existence of the BO6 octahedral rotation, with rotation patterns of the a 0 b 0 c 0 and a - b + c - , and rotation angles are quantitatively measured. The BO6 octahedral rotation and cation displacement are found to be consistent, the greater octahedral rotation with greater cation displacements. These results have important implications for understanding the structural origin of the excellent properties in ferroelectrics.
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title_short	Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O
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author2	Qian, Hao Zheng, Tianyang Sun, Xiaoyuan Liu, Yunfei Lyu, Yinong
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doi_str	10.1016/j.jallcom.2022.166210
up_date	2024-07-06T19:14:28.809Z
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score	7.397312

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Enhanced strain of (Ba, Ca)(Ti, Zr, Sn)O

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Zugang & Verfügbarkeit

Vorhandene Bände

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