Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions
The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Hongen [verfasserIn] Cui, Xianbao [verfasserIn] Li, Pengqi [verfasserIn] Feng, Tianyang [verfasserIn] Feng, Huisheng [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2022 |
|---|
| Schlagwörter: |
|---|
| Übergeordnetes Werk: |
Enthalten in: Journal of molecular liquids - New York, NY [u.a.] : Elsevier, 1983, 365 |
|---|---|
| Übergeordnetes Werk: |
volume:365 |
| DOI / URN: |
10.1016/j.molliq.2022.120193 |
|---|
| Katalog-ID: |
ELV008443149 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | ELV008443149 | ||
| 003 | DE-627 | ||
| 005 | 20230524151315.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 230508s2022 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.molliq.2022.120193 |2 doi | |
| 035 | |a (DE-627)ELV008443149 | ||
| 035 | |a (ELSEVIER)S0167-7322(22)01732-9 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 540 |q DE-600 |
| 084 | |a 35.21 |2 bkl | ||
| 100 | 1 | |a Zhang, Hongen |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions |
| 264 | 1 | |c 2022 | |
| 336 | |a nicht spezifiziert |b zzz |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 520 | |a The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data. | ||
| 650 | 4 | |a Ionic liquid | |
| 650 | 4 | |a Electrical conductivity | |
| 650 | 4 | |a Correlation | |
| 650 | 4 | |a Double salt ionic liquids | |
| 650 | 4 | |a Ionic liquid mixture | |
| 700 | 1 | |a Cui, Xianbao |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Pengqi |e verfasserin |4 aut | |
| 700 | 1 | |a Feng, Tianyang |e verfasserin |4 aut | |
| 700 | 1 | |a Feng, Huisheng |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Journal of molecular liquids |d New York, NY [u.a.] : Elsevier, 1983 |g 365 |h Online-Ressource |w (DE-627)302469664 |w (DE-600)1491496-7 |w (DE-576)259483915 |x 1873-3166 |7 nnns |
| 773 | 1 | 8 | |g volume:365 |
| 912 | |a GBV_USEFLAG_U | ||
| 912 | |a SYSFLAG_U | ||
| 912 | |a GBV_ELV | ||
| 912 | |a SSG-OLC-PHA | ||
| 912 | |a GBV_ILN_20 | ||
| 912 | |a GBV_ILN_22 | ||
| 912 | |a GBV_ILN_23 | ||
| 912 | |a GBV_ILN_24 | ||
| 912 | |a GBV_ILN_31 | ||
| 912 | |a GBV_ILN_32 | ||
| 912 | |a GBV_ILN_40 | ||
| 912 | |a GBV_ILN_60 | ||
| 912 | |a GBV_ILN_62 | ||
| 912 | |a GBV_ILN_63 | ||
| 912 | |a GBV_ILN_65 | ||
| 912 | |a GBV_ILN_69 | ||
| 912 | |a GBV_ILN_70 | ||
| 912 | |a GBV_ILN_73 | ||
| 912 | |a GBV_ILN_74 | ||
| 912 | |a GBV_ILN_90 | ||
| 912 | |a GBV_ILN_95 | ||
| 912 | |a GBV_ILN_100 | ||
| 912 | |a GBV_ILN_101 | ||
| 912 | |a GBV_ILN_105 | ||
| 912 | |a GBV_ILN_110 | ||
| 912 | |a GBV_ILN_150 | ||
| 912 | |a GBV_ILN_151 | ||
| 912 | |a GBV_ILN_224 | ||
| 912 | |a GBV_ILN_370 | ||
| 912 | |a GBV_ILN_374 | ||
| 912 | |a GBV_ILN_602 | ||
| 912 | |a GBV_ILN_702 | ||
| 912 | |a GBV_ILN_2003 | ||
| 912 | |a GBV_ILN_2004 | ||
| 912 | |a GBV_ILN_2005 | ||
| 912 | |a GBV_ILN_2011 | ||
| 912 | |a GBV_ILN_2014 | ||
| 912 | |a GBV_ILN_2015 | ||
| 912 | |a GBV_ILN_2020 | ||
| 912 | |a GBV_ILN_2021 | ||
| 912 | |a GBV_ILN_2025 | ||
| 912 | |a GBV_ILN_2027 | ||
| 912 | |a GBV_ILN_2034 | ||
| 912 | |a GBV_ILN_2038 | ||
| 912 | |a GBV_ILN_2044 | ||
| 912 | |a GBV_ILN_2048 | ||
| 912 | |a GBV_ILN_2049 | ||
| 912 | |a GBV_ILN_2050 | ||
| 912 | |a GBV_ILN_2056 | ||
| 912 | |a GBV_ILN_2059 | ||
| 912 | |a GBV_ILN_2061 | ||
| 912 | |a GBV_ILN_2064 | ||
| 912 | |a GBV_ILN_2065 | ||
| 912 | |a GBV_ILN_2068 | ||
| 912 | |a GBV_ILN_2111 | ||
| 912 | |a GBV_ILN_2112 | ||
| 912 | |a GBV_ILN_2113 | ||
| 912 | |a GBV_ILN_2118 | ||
| 912 | |a GBV_ILN_2122 | ||
| 912 | |a GBV_ILN_2129 | ||
| 912 | |a GBV_ILN_2143 | ||
| 912 | |a GBV_ILN_2147 | ||
| 912 | |a GBV_ILN_2148 | ||
| 912 | |a GBV_ILN_2152 | ||
| 912 | |a GBV_ILN_2153 | ||
| 912 | |a GBV_ILN_2190 | ||
| 912 | |a GBV_ILN_2336 | ||
| 912 | |a GBV_ILN_2507 | ||
| 912 | |a GBV_ILN_2522 | ||
| 912 | |a GBV_ILN_2807 | ||
| 912 | |a GBV_ILN_4035 | ||
| 912 | |a GBV_ILN_4037 | ||
| 912 | |a GBV_ILN_4112 | ||
| 912 | |a GBV_ILN_4125 | ||
| 912 | |a GBV_ILN_4126 | ||
| 912 | |a GBV_ILN_4242 | ||
| 912 | |a GBV_ILN_4251 | ||
| 912 | |a GBV_ILN_4305 | ||
| 912 | |a GBV_ILN_4313 | ||
| 912 | |a GBV_ILN_4323 | ||
| 912 | |a GBV_ILN_4324 | ||
| 912 | |a GBV_ILN_4326 | ||
| 912 | |a GBV_ILN_4333 | ||
| 912 | |a GBV_ILN_4334 | ||
| 912 | |a GBV_ILN_4335 | ||
| 912 | |a GBV_ILN_4338 | ||
| 912 | |a GBV_ILN_4393 | ||
| 936 | b | k | |a 35.21 |j Lösungen |j Flüssigkeiten |x Physikalische Chemie |
| 951 | |a AR | ||
| 952 | |d 365 | ||
| author_variant |
h z hz x c xc p l pl t f tf h f hf |
|---|---|
| matchkey_str |
article:18733166:2022----::esrmnadorltofrheetiacnutvtodulsli |
| hierarchy_sort_str |
2022 |
| bklnumber |
35.21 |
| publishDate |
2022 |
| allfields |
10.1016/j.molliq.2022.120193 doi (DE-627)ELV008443149 (ELSEVIER)S0167-7322(22)01732-9 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Zhang, Hongen verfasserin aut Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data. Ionic liquid Electrical conductivity Correlation Double salt ionic liquids Ionic liquid mixture Cui, Xianbao verfasserin aut Li, Pengqi verfasserin aut Feng, Tianyang verfasserin aut Feng, Huisheng verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 365 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:365 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 365 |
| spelling |
10.1016/j.molliq.2022.120193 doi (DE-627)ELV008443149 (ELSEVIER)S0167-7322(22)01732-9 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Zhang, Hongen verfasserin aut Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data. Ionic liquid Electrical conductivity Correlation Double salt ionic liquids Ionic liquid mixture Cui, Xianbao verfasserin aut Li, Pengqi verfasserin aut Feng, Tianyang verfasserin aut Feng, Huisheng verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 365 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:365 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 365 |
| allfields_unstemmed |
10.1016/j.molliq.2022.120193 doi (DE-627)ELV008443149 (ELSEVIER)S0167-7322(22)01732-9 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Zhang, Hongen verfasserin aut Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data. Ionic liquid Electrical conductivity Correlation Double salt ionic liquids Ionic liquid mixture Cui, Xianbao verfasserin aut Li, Pengqi verfasserin aut Feng, Tianyang verfasserin aut Feng, Huisheng verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 365 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:365 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 365 |
| allfieldsGer |
10.1016/j.molliq.2022.120193 doi (DE-627)ELV008443149 (ELSEVIER)S0167-7322(22)01732-9 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Zhang, Hongen verfasserin aut Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data. Ionic liquid Electrical conductivity Correlation Double salt ionic liquids Ionic liquid mixture Cui, Xianbao verfasserin aut Li, Pengqi verfasserin aut Feng, Tianyang verfasserin aut Feng, Huisheng verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 365 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:365 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 365 |
| allfieldsSound |
10.1016/j.molliq.2022.120193 doi (DE-627)ELV008443149 (ELSEVIER)S0167-7322(22)01732-9 DE-627 ger DE-627 rda eng 540 DE-600 35.21 bkl Zhang, Hongen verfasserin aut Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data. Ionic liquid Electrical conductivity Correlation Double salt ionic liquids Ionic liquid mixture Cui, Xianbao verfasserin aut Li, Pengqi verfasserin aut Feng, Tianyang verfasserin aut Feng, Huisheng verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 365 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:365 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.21 Lösungen Flüssigkeiten Physikalische Chemie AR 365 |
| language |
English |
| source |
Enthalten in Journal of molecular liquids 365 volume:365 |
| sourceStr |
Enthalten in Journal of molecular liquids 365 volume:365 |
| format_phy_str_mv |
Article |
| bklname |
Lösungen Flüssigkeiten |
| institution |
findex.gbv.de |
| topic_facet |
Ionic liquid Electrical conductivity Correlation Double salt ionic liquids Ionic liquid mixture |
| dewey-raw |
540 |
| isfreeaccess_bool |
false |
| container_title |
Journal of molecular liquids |
| authorswithroles_txt_mv |
Zhang, Hongen @@aut@@ Cui, Xianbao @@aut@@ Li, Pengqi @@aut@@ Feng, Tianyang @@aut@@ Feng, Huisheng @@aut@@ |
| publishDateDaySort_date |
2022-01-01T00:00:00Z |
| hierarchy_top_id |
302469664 |
| dewey-sort |
3540 |
| id |
ELV008443149 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV008443149</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524151315.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230508s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.molliq.2022.120193</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV008443149</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0167-7322(22)01732-9</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.21</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zhang, Hongen</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ionic liquid</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Electrical conductivity</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Correlation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Double salt ionic liquids</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ionic liquid mixture</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cui, Xianbao</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Pengqi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Feng, Tianyang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Feng, Huisheng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of molecular liquids</subfield><subfield code="d">New York, NY [u.a.] : Elsevier, 1983</subfield><subfield code="g">365</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)302469664</subfield><subfield code="w">(DE-600)1491496-7</subfield><subfield code="w">(DE-576)259483915</subfield><subfield code="x">1873-3166</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:365</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_374</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2807</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.21</subfield><subfield code="j">Lösungen</subfield><subfield code="j">Flüssigkeiten</subfield><subfield code="x">Physikalische Chemie</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">365</subfield></datafield></record></collection>
|
| author |
Zhang, Hongen |
| spellingShingle |
Zhang, Hongen ddc 540 bkl 35.21 misc Ionic liquid misc Electrical conductivity misc Correlation misc Double salt ionic liquids misc Ionic liquid mixture Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions |
| authorStr |
Zhang, Hongen |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)302469664 |
| format |
electronic Article |
| dewey-ones |
540 - Chemistry & allied sciences |
| delete_txt_mv |
keep |
| author_role |
aut aut aut aut aut |
| collection |
elsevier |
| remote_str |
true |
| illustrated |
Not Illustrated |
| issn |
1873-3166 |
| topic_title |
540 DE-600 35.21 bkl Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions Ionic liquid Electrical conductivity Correlation Double salt ionic liquids Ionic liquid mixture |
| topic |
ddc 540 bkl 35.21 misc Ionic liquid misc Electrical conductivity misc Correlation misc Double salt ionic liquids misc Ionic liquid mixture |
| topic_unstemmed |
ddc 540 bkl 35.21 misc Ionic liquid misc Electrical conductivity misc Correlation misc Double salt ionic liquids misc Ionic liquid mixture |
| topic_browse |
ddc 540 bkl 35.21 misc Ionic liquid misc Electrical conductivity misc Correlation misc Double salt ionic liquids misc Ionic liquid mixture |
| format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
cr |
| hierarchy_parent_title |
Journal of molecular liquids |
| hierarchy_parent_id |
302469664 |
| dewey-tens |
540 - Chemistry |
| hierarchy_top_title |
Journal of molecular liquids |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 |
| title |
Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions |
| ctrlnum |
(DE-627)ELV008443149 (ELSEVIER)S0167-7322(22)01732-9 |
| title_full |
Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions |
| author_sort |
Zhang, Hongen |
| journal |
Journal of molecular liquids |
| journalStr |
Journal of molecular liquids |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
500 - Science |
| recordtype |
marc |
| publishDateSort |
2022 |
| contenttype_str_mv |
zzz |
| author_browse |
Zhang, Hongen Cui, Xianbao Li, Pengqi Feng, Tianyang Feng, Huisheng |
| container_volume |
365 |
| class |
540 DE-600 35.21 bkl |
| format_se |
Elektronische Aufsätze |
| author-letter |
Zhang, Hongen |
| doi_str_mv |
10.1016/j.molliq.2022.120193 |
| dewey-full |
540 |
| author2-role |
verfasserin |
| title_sort |
measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions |
| title_auth |
Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions |
| abstract |
The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data. |
| abstractGer |
The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data. |
| abstract_unstemmed |
The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data. |
| collection_details |
GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 |
| title_short |
Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions |
| remote_bool |
true |
| author2 |
Cui, Xianbao Li, Pengqi Feng, Tianyang Feng, Huisheng |
| author2Str |
Cui, Xianbao Li, Pengqi Feng, Tianyang Feng, Huisheng |
| ppnlink |
302469664 |
| mediatype_str_mv |
c |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1016/j.molliq.2022.120193 |
| up_date |
2024-07-06T19:43:12.393Z |
| _version_ |
1803860041944530944 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV008443149</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230524151315.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230508s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.molliq.2022.120193</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV008443149</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0167-7322(22)01732-9</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.21</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zhang, Hongen</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Measurement and correlation for the electrical conductivity of double salt ionic liquids with triple ions</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The neat ionic liquids 1-butyl-2,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4C1C1im][NTf2]), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([C4C1C1im][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([Deme][BF4]), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis[(trifluoromethyl)sulfonyl]imide ([Deme][NTf2]) were used as parent ionic liquids to generate double salt ionic liquids (DSILs) with triple ions. The conductivity of DSILs [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4], [C4C1C1im][NTf2]x[BF4](1-x) and [Deme][NTf2]x[BF4](1-x) were measured. There is a linear positive deviation for [Deme]x[C4C1C1im](1-x)[NTf2], [Deme]x[C4C1C1im](1-x)[BF4] and [C4C1C1im][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of DSILs are greater than those of linear averages of the corresponding parent neat ionic liquids. The electrical conductivities of [Deme]x[C4C1C1im](1-x)[NTf2] and [Deme]x[C4C1C1im](1-x)[BF4] lie in the range of those of their corresponding parent neat ionic liquids. The electrical conductivity of [C4C1C1im][NTf2]x[BF4](1-x) rises with the concentration of [NTf2], and it has a maximum value at x = 0.9, which is larger than either of its parent neat ionic liquids. There is a linear negative deviation for [Deme][NTf2]x[BF4](1-x), which indicates that most of the electrical conductivities of the DSIL is less than that of linear average of the corresponding parent neat ionic liquids. The electrical conductivity of the DSIL lies between those of its parent neat ionic liquids and increases with the concentration of [NTf2]. The VTF equation and the Arrhenius equation were utilized to correlate the temperature dependence of DSILs, and VTF equation is more accurate than Arrhenius equation. The relationships between parameters of VTF equation and ion composition can be expressed by first-order Fourier equation. A transformed VTF equation based on VTF and Fourier equation was proposed to describe the combined effects of ion composition and temperature on the electrical conductivity. The experimental electrical conductivities of DSILs were correlated by the transformed VTF equation, and the correlation results agree well with experimental data.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ionic liquid</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Electrical conductivity</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Correlation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Double salt ionic liquids</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ionic liquid mixture</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cui, Xianbao</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Pengqi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Feng, Tianyang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Feng, Huisheng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of molecular liquids</subfield><subfield code="d">New York, NY [u.a.] : Elsevier, 1983</subfield><subfield code="g">365</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)302469664</subfield><subfield code="w">(DE-600)1491496-7</subfield><subfield code="w">(DE-576)259483915</subfield><subfield code="x">1873-3166</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:365</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_374</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2807</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.21</subfield><subfield code="j">Lösungen</subfield><subfield code="j">Flüssigkeiten</subfield><subfield code="x">Physikalische Chemie</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">365</subfield></datafield></record></collection>
|
| score |
7.401063 |