Engineering
Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cat...
Ausführliche Beschreibung
Autor*in: |
Zhang, Shu [verfasserIn] Fang, Susu [verfasserIn] Chen, Jun [verfasserIn] Ni, Lianshan [verfasserIn] Deng, Wentao [verfasserIn] Zou, Guoqiang [verfasserIn] Hou, Hongshuai [verfasserIn] Ji, Xiaobo [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Übergeordnetes Werk: |
Enthalten in: The chemical engineering journal - Amsterdam : Elsevier, 1997, 451 |
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Übergeordnetes Werk: |
volume:451 |
DOI / URN: |
10.1016/j.cej.2022.138511 |
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Katalog-ID: |
ELV008566771 |
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520 | |a Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cathode with stable crystallographic structure is rationally designed based on valence-bond theory with introduction of Ru dopant. The enhanced orbital hybridization between Mn 3d and O 2p is successfully achieved owing to the reinforcing band coherency of Mn–O aroused from the electrostatic interaction between Mn and Ru atoms. Notably, the robust crystal structure framework is effectively reconstructed, which is beneficial for ameliorating phase evolution and inhibiting structural degradation substantiated by the state-of-the-art synchrotron X-ray absorption spectroscopy and in-situ X-ray diffraction. Concomitantly, LiO4 tetrahedron is effectively weakened, further facilitating the rapid Li+ diffusion kinetics intensively confirmed by theoretical calculations and electrochemical tests. Remarkably, the as-designed Ru-doped LiMn2O4 manifests splendid long cycling stability, affording a respectable capacity retention of 88.2 % after 200 loops. Given this, the intriguing work might inaugurate an explicit direction for rationally tuning the orbital hybridization towards advanced electrodes in alkali metal batteries. | ||
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700 | 1 | |a Fang, Susu |e verfasserin |4 aut | |
700 | 1 | |a Chen, Jun |e verfasserin |4 aut | |
700 | 1 | |a Ni, Lianshan |e verfasserin |4 aut | |
700 | 1 | |a Deng, Wentao |e verfasserin |4 aut | |
700 | 1 | |a Zou, Guoqiang |e verfasserin |4 aut | |
700 | 1 | |a Hou, Hongshuai |e verfasserin |4 aut | |
700 | 1 | |a Ji, Xiaobo |e verfasserin |4 aut | |
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10.1016/j.cej.2022.138511 doi (DE-627)ELV008566771 (ELSEVIER)S1385-8947(22)03992-4 DE-627 ger DE-627 rda eng 660 VZ 660 VZ 58.10 bkl Zhang, Shu verfasserin aut Engineering 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cathode with stable crystallographic structure is rationally designed based on valence-bond theory with introduction of Ru dopant. The enhanced orbital hybridization between Mn 3d and O 2p is successfully achieved owing to the reinforcing band coherency of Mn–O aroused from the electrostatic interaction between Mn and Ru atoms. Notably, the robust crystal structure framework is effectively reconstructed, which is beneficial for ameliorating phase evolution and inhibiting structural degradation substantiated by the state-of-the-art synchrotron X-ray absorption spectroscopy and in-situ X-ray diffraction. Concomitantly, LiO4 tetrahedron is effectively weakened, further facilitating the rapid Li+ diffusion kinetics intensively confirmed by theoretical calculations and electrochemical tests. Remarkably, the as-designed Ru-doped LiMn2O4 manifests splendid long cycling stability, affording a respectable capacity retention of 88.2 % after 200 loops. Given this, the intriguing work might inaugurate an explicit direction for rationally tuning the orbital hybridization towards advanced electrodes in alkali metal batteries. LiMn Orbital hybridization Cathode materials Ru Fang, Susu verfasserin aut Chen, Jun verfasserin aut Ni, Lianshan verfasserin aut Deng, Wentao verfasserin aut Zou, Guoqiang verfasserin aut Hou, Hongshuai verfasserin aut Ji, Xiaobo verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 451 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:451 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines VZ AR 451 |
spelling |
10.1016/j.cej.2022.138511 doi (DE-627)ELV008566771 (ELSEVIER)S1385-8947(22)03992-4 DE-627 ger DE-627 rda eng 660 VZ 660 VZ 58.10 bkl Zhang, Shu verfasserin aut Engineering 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cathode with stable crystallographic structure is rationally designed based on valence-bond theory with introduction of Ru dopant. The enhanced orbital hybridization between Mn 3d and O 2p is successfully achieved owing to the reinforcing band coherency of Mn–O aroused from the electrostatic interaction between Mn and Ru atoms. Notably, the robust crystal structure framework is effectively reconstructed, which is beneficial for ameliorating phase evolution and inhibiting structural degradation substantiated by the state-of-the-art synchrotron X-ray absorption spectroscopy and in-situ X-ray diffraction. Concomitantly, LiO4 tetrahedron is effectively weakened, further facilitating the rapid Li+ diffusion kinetics intensively confirmed by theoretical calculations and electrochemical tests. Remarkably, the as-designed Ru-doped LiMn2O4 manifests splendid long cycling stability, affording a respectable capacity retention of 88.2 % after 200 loops. Given this, the intriguing work might inaugurate an explicit direction for rationally tuning the orbital hybridization towards advanced electrodes in alkali metal batteries. LiMn Orbital hybridization Cathode materials Ru Fang, Susu verfasserin aut Chen, Jun verfasserin aut Ni, Lianshan verfasserin aut Deng, Wentao verfasserin aut Zou, Guoqiang verfasserin aut Hou, Hongshuai verfasserin aut Ji, Xiaobo verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 451 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:451 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines VZ AR 451 |
allfields_unstemmed |
10.1016/j.cej.2022.138511 doi (DE-627)ELV008566771 (ELSEVIER)S1385-8947(22)03992-4 DE-627 ger DE-627 rda eng 660 VZ 660 VZ 58.10 bkl Zhang, Shu verfasserin aut Engineering 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cathode with stable crystallographic structure is rationally designed based on valence-bond theory with introduction of Ru dopant. The enhanced orbital hybridization between Mn 3d and O 2p is successfully achieved owing to the reinforcing band coherency of Mn–O aroused from the electrostatic interaction between Mn and Ru atoms. Notably, the robust crystal structure framework is effectively reconstructed, which is beneficial for ameliorating phase evolution and inhibiting structural degradation substantiated by the state-of-the-art synchrotron X-ray absorption spectroscopy and in-situ X-ray diffraction. Concomitantly, LiO4 tetrahedron is effectively weakened, further facilitating the rapid Li+ diffusion kinetics intensively confirmed by theoretical calculations and electrochemical tests. Remarkably, the as-designed Ru-doped LiMn2O4 manifests splendid long cycling stability, affording a respectable capacity retention of 88.2 % after 200 loops. Given this, the intriguing work might inaugurate an explicit direction for rationally tuning the orbital hybridization towards advanced electrodes in alkali metal batteries. LiMn Orbital hybridization Cathode materials Ru Fang, Susu verfasserin aut Chen, Jun verfasserin aut Ni, Lianshan verfasserin aut Deng, Wentao verfasserin aut Zou, Guoqiang verfasserin aut Hou, Hongshuai verfasserin aut Ji, Xiaobo verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 451 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:451 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines VZ AR 451 |
allfieldsGer |
10.1016/j.cej.2022.138511 doi (DE-627)ELV008566771 (ELSEVIER)S1385-8947(22)03992-4 DE-627 ger DE-627 rda eng 660 VZ 660 VZ 58.10 bkl Zhang, Shu verfasserin aut Engineering 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cathode with stable crystallographic structure is rationally designed based on valence-bond theory with introduction of Ru dopant. The enhanced orbital hybridization between Mn 3d and O 2p is successfully achieved owing to the reinforcing band coherency of Mn–O aroused from the electrostatic interaction between Mn and Ru atoms. Notably, the robust crystal structure framework is effectively reconstructed, which is beneficial for ameliorating phase evolution and inhibiting structural degradation substantiated by the state-of-the-art synchrotron X-ray absorption spectroscopy and in-situ X-ray diffraction. Concomitantly, LiO4 tetrahedron is effectively weakened, further facilitating the rapid Li+ diffusion kinetics intensively confirmed by theoretical calculations and electrochemical tests. Remarkably, the as-designed Ru-doped LiMn2O4 manifests splendid long cycling stability, affording a respectable capacity retention of 88.2 % after 200 loops. Given this, the intriguing work might inaugurate an explicit direction for rationally tuning the orbital hybridization towards advanced electrodes in alkali metal batteries. LiMn Orbital hybridization Cathode materials Ru Fang, Susu verfasserin aut Chen, Jun verfasserin aut Ni, Lianshan verfasserin aut Deng, Wentao verfasserin aut Zou, Guoqiang verfasserin aut Hou, Hongshuai verfasserin aut Ji, Xiaobo verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 451 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:451 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines VZ AR 451 |
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10.1016/j.cej.2022.138511 doi (DE-627)ELV008566771 (ELSEVIER)S1385-8947(22)03992-4 DE-627 ger DE-627 rda eng 660 VZ 660 VZ 58.10 bkl Zhang, Shu verfasserin aut Engineering 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cathode with stable crystallographic structure is rationally designed based on valence-bond theory with introduction of Ru dopant. The enhanced orbital hybridization between Mn 3d and O 2p is successfully achieved owing to the reinforcing band coherency of Mn–O aroused from the electrostatic interaction between Mn and Ru atoms. Notably, the robust crystal structure framework is effectively reconstructed, which is beneficial for ameliorating phase evolution and inhibiting structural degradation substantiated by the state-of-the-art synchrotron X-ray absorption spectroscopy and in-situ X-ray diffraction. Concomitantly, LiO4 tetrahedron is effectively weakened, further facilitating the rapid Li+ diffusion kinetics intensively confirmed by theoretical calculations and electrochemical tests. Remarkably, the as-designed Ru-doped LiMn2O4 manifests splendid long cycling stability, affording a respectable capacity retention of 88.2 % after 200 loops. Given this, the intriguing work might inaugurate an explicit direction for rationally tuning the orbital hybridization towards advanced electrodes in alkali metal batteries. LiMn Orbital hybridization Cathode materials Ru Fang, Susu verfasserin aut Chen, Jun verfasserin aut Ni, Lianshan verfasserin aut Deng, Wentao verfasserin aut Zou, Guoqiang verfasserin aut Hou, Hongshuai verfasserin aut Ji, Xiaobo verfasserin aut Enthalten in The chemical engineering journal Amsterdam : Elsevier, 1997 451 Online-Ressource (DE-627)320500322 (DE-600)2012137-4 (DE-576)098330152 1873-3212 nnns volume:451 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.10 Verfahrenstechnik: Allgemeines VZ AR 451 |
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Engineering |
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Zhang, Shu |
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The chemical engineering journal |
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600 - Technology |
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2022 |
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Zhang, Shu Fang, Susu Chen, Jun Ni, Lianshan Deng, Wentao Zou, Guoqiang Hou, Hongshuai Ji, Xiaobo |
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451 |
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Elektronische Aufsätze |
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Zhang, Shu |
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10.1016/j.cej.2022.138511 |
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660 |
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engineering |
title_auth |
Engineering |
abstract |
Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cathode with stable crystallographic structure is rationally designed based on valence-bond theory with introduction of Ru dopant. The enhanced orbital hybridization between Mn 3d and O 2p is successfully achieved owing to the reinforcing band coherency of Mn–O aroused from the electrostatic interaction between Mn and Ru atoms. Notably, the robust crystal structure framework is effectively reconstructed, which is beneficial for ameliorating phase evolution and inhibiting structural degradation substantiated by the state-of-the-art synchrotron X-ray absorption spectroscopy and in-situ X-ray diffraction. Concomitantly, LiO4 tetrahedron is effectively weakened, further facilitating the rapid Li+ diffusion kinetics intensively confirmed by theoretical calculations and electrochemical tests. Remarkably, the as-designed Ru-doped LiMn2O4 manifests splendid long cycling stability, affording a respectable capacity retention of 88.2 % after 200 loops. Given this, the intriguing work might inaugurate an explicit direction for rationally tuning the orbital hybridization towards advanced electrodes in alkali metal batteries. |
abstractGer |
Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cathode with stable crystallographic structure is rationally designed based on valence-bond theory with introduction of Ru dopant. The enhanced orbital hybridization between Mn 3d and O 2p is successfully achieved owing to the reinforcing band coherency of Mn–O aroused from the electrostatic interaction between Mn and Ru atoms. Notably, the robust crystal structure framework is effectively reconstructed, which is beneficial for ameliorating phase evolution and inhibiting structural degradation substantiated by the state-of-the-art synchrotron X-ray absorption spectroscopy and in-situ X-ray diffraction. Concomitantly, LiO4 tetrahedron is effectively weakened, further facilitating the rapid Li+ diffusion kinetics intensively confirmed by theoretical calculations and electrochemical tests. Remarkably, the as-designed Ru-doped LiMn2O4 manifests splendid long cycling stability, affording a respectable capacity retention of 88.2 % after 200 loops. Given this, the intriguing work might inaugurate an explicit direction for rationally tuning the orbital hybridization towards advanced electrodes in alkali metal batteries. |
abstract_unstemmed |
Spinel LiMn2O4 is a prevalent cathode material due to its environmental benignities and high operating voltage. Nevertheless, capacity attenuation and structural collapse are still inevitable, caused by the native Jahn–Teller distortion and spontaneous disproportionation of Mn3+. Hereby, LiMn2O4 cathode with stable crystallographic structure is rationally designed based on valence-bond theory with introduction of Ru dopant. The enhanced orbital hybridization between Mn 3d and O 2p is successfully achieved owing to the reinforcing band coherency of Mn–O aroused from the electrostatic interaction between Mn and Ru atoms. Notably, the robust crystal structure framework is effectively reconstructed, which is beneficial for ameliorating phase evolution and inhibiting structural degradation substantiated by the state-of-the-art synchrotron X-ray absorption spectroscopy and in-situ X-ray diffraction. Concomitantly, LiO4 tetrahedron is effectively weakened, further facilitating the rapid Li+ diffusion kinetics intensively confirmed by theoretical calculations and electrochemical tests. Remarkably, the as-designed Ru-doped LiMn2O4 manifests splendid long cycling stability, affording a respectable capacity retention of 88.2 % after 200 loops. Given this, the intriguing work might inaugurate an explicit direction for rationally tuning the orbital hybridization towards advanced electrodes in alkali metal batteries. |
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title_short |
Engineering |
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Fang, Susu Chen, Jun Ni, Lianshan Deng, Wentao Zou, Guoqiang Hou, Hongshuai Ji, Xiaobo |
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up_date |
2024-07-06T20:08:31.798Z |
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