Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies
Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous me...
Ausführliche Beschreibung
Autor*in: |
Liang, Kaiyuan [verfasserIn] Li, Xin [verfasserIn] Wang, Lei [verfasserIn] Xie, Zhiying [verfasserIn] Wang, Qimeng [verfasserIn] Wang, Kai [verfasserIn] Wu, Jianping [verfasserIn] Yu, Haizhou [verfasserIn] Qiu, Xiaoyan [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Übergeordnetes Werk: |
Enthalten in: Journal of membrane science - New York, NY [u.a.] : Elsevier, 1976, 669 |
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Übergeordnetes Werk: |
volume:669 |
DOI / URN: |
10.1016/j.memsci.2022.121277 |
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Katalog-ID: |
ELV009076417 |
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520 | |a Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous membrane with SNIPS method is difficult since PAA is extremely hydrophilic; (2) large consumption of block copolymer and non-solvent (water) might limit its application. Herein, isoporous membranes from Polystyrene-block-poly (acrylic acid) (PS-b-PAA) were well prepared with amine terminated poly(N-isopropylacrylamide) (pNIPAM-NH2) through the SNIPS and the airflow accelerated evaporation induced phase separation methods (acEIPS). Such membranes bear not only regularity in morphological structure, but also high water permeance (1500 L h−1 m−2 bar−1 for the SNIPS, and 3000 L h−1 m−2 bar−1 for the acEIPS). With the participation of pNIPAM-NH2 the consumption of the block copolymer is limited to 7.8 wt % for the SNIPS method, and even to 5.3 wt % for the acEIPS method without non-solvent precipitation process. Besides, the membrane exhibits pH and thermal responsiveness. | ||
700 | 1 | |a Li, Xin |e verfasserin |4 aut | |
700 | 1 | |a Wang, Lei |e verfasserin |4 aut | |
700 | 1 | |a Xie, Zhiying |e verfasserin |4 aut | |
700 | 1 | |a Wang, Qimeng |e verfasserin |4 aut | |
700 | 1 | |a Wang, Kai |e verfasserin |4 aut | |
700 | 1 | |a Wu, Jianping |e verfasserin |4 aut | |
700 | 1 | |a Yu, Haizhou |e verfasserin |4 aut | |
700 | 1 | |a Qiu, Xiaoyan |e verfasserin |4 aut | |
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912 | |a GBV_ILN_4335 | ||
912 | |a GBV_ILN_4338 | ||
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allfields |
10.1016/j.memsci.2022.121277 doi (DE-627)ELV009076417 (ELSEVIER)S0376-7388(22)01022-5 DE-627 ger DE-627 rda eng 570 VZ 58.11 bkl Liang, Kaiyuan verfasserin aut Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous membrane with SNIPS method is difficult since PAA is extremely hydrophilic; (2) large consumption of block copolymer and non-solvent (water) might limit its application. Herein, isoporous membranes from Polystyrene-block-poly (acrylic acid) (PS-b-PAA) were well prepared with amine terminated poly(N-isopropylacrylamide) (pNIPAM-NH2) through the SNIPS and the airflow accelerated evaporation induced phase separation methods (acEIPS). Such membranes bear not only regularity in morphological structure, but also high water permeance (1500 L h−1 m−2 bar−1 for the SNIPS, and 3000 L h−1 m−2 bar−1 for the acEIPS). With the participation of pNIPAM-NH2 the consumption of the block copolymer is limited to 7.8 wt % for the SNIPS method, and even to 5.3 wt % for the acEIPS method without non-solvent precipitation process. Besides, the membrane exhibits pH and thermal responsiveness. Li, Xin verfasserin aut Wang, Lei verfasserin aut Xie, Zhiying verfasserin aut Wang, Qimeng verfasserin aut Wang, Kai verfasserin aut Wu, Jianping verfasserin aut Yu, Haizhou verfasserin aut Qiu, Xiaoyan verfasserin aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 669 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:669 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik VZ AR 669 |
spelling |
10.1016/j.memsci.2022.121277 doi (DE-627)ELV009076417 (ELSEVIER)S0376-7388(22)01022-5 DE-627 ger DE-627 rda eng 570 VZ 58.11 bkl Liang, Kaiyuan verfasserin aut Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous membrane with SNIPS method is difficult since PAA is extremely hydrophilic; (2) large consumption of block copolymer and non-solvent (water) might limit its application. Herein, isoporous membranes from Polystyrene-block-poly (acrylic acid) (PS-b-PAA) were well prepared with amine terminated poly(N-isopropylacrylamide) (pNIPAM-NH2) through the SNIPS and the airflow accelerated evaporation induced phase separation methods (acEIPS). Such membranes bear not only regularity in morphological structure, but also high water permeance (1500 L h−1 m−2 bar−1 for the SNIPS, and 3000 L h−1 m−2 bar−1 for the acEIPS). With the participation of pNIPAM-NH2 the consumption of the block copolymer is limited to 7.8 wt % for the SNIPS method, and even to 5.3 wt % for the acEIPS method without non-solvent precipitation process. Besides, the membrane exhibits pH and thermal responsiveness. Li, Xin verfasserin aut Wang, Lei verfasserin aut Xie, Zhiying verfasserin aut Wang, Qimeng verfasserin aut Wang, Kai verfasserin aut Wu, Jianping verfasserin aut Yu, Haizhou verfasserin aut Qiu, Xiaoyan verfasserin aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 669 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:669 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik VZ AR 669 |
allfields_unstemmed |
10.1016/j.memsci.2022.121277 doi (DE-627)ELV009076417 (ELSEVIER)S0376-7388(22)01022-5 DE-627 ger DE-627 rda eng 570 VZ 58.11 bkl Liang, Kaiyuan verfasserin aut Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous membrane with SNIPS method is difficult since PAA is extremely hydrophilic; (2) large consumption of block copolymer and non-solvent (water) might limit its application. Herein, isoporous membranes from Polystyrene-block-poly (acrylic acid) (PS-b-PAA) were well prepared with amine terminated poly(N-isopropylacrylamide) (pNIPAM-NH2) through the SNIPS and the airflow accelerated evaporation induced phase separation methods (acEIPS). Such membranes bear not only regularity in morphological structure, but also high water permeance (1500 L h−1 m−2 bar−1 for the SNIPS, and 3000 L h−1 m−2 bar−1 for the acEIPS). With the participation of pNIPAM-NH2 the consumption of the block copolymer is limited to 7.8 wt % for the SNIPS method, and even to 5.3 wt % for the acEIPS method without non-solvent precipitation process. Besides, the membrane exhibits pH and thermal responsiveness. Li, Xin verfasserin aut Wang, Lei verfasserin aut Xie, Zhiying verfasserin aut Wang, Qimeng verfasserin aut Wang, Kai verfasserin aut Wu, Jianping verfasserin aut Yu, Haizhou verfasserin aut Qiu, Xiaoyan verfasserin aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 669 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:669 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik VZ AR 669 |
allfieldsGer |
10.1016/j.memsci.2022.121277 doi (DE-627)ELV009076417 (ELSEVIER)S0376-7388(22)01022-5 DE-627 ger DE-627 rda eng 570 VZ 58.11 bkl Liang, Kaiyuan verfasserin aut Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous membrane with SNIPS method is difficult since PAA is extremely hydrophilic; (2) large consumption of block copolymer and non-solvent (water) might limit its application. Herein, isoporous membranes from Polystyrene-block-poly (acrylic acid) (PS-b-PAA) were well prepared with amine terminated poly(N-isopropylacrylamide) (pNIPAM-NH2) through the SNIPS and the airflow accelerated evaporation induced phase separation methods (acEIPS). Such membranes bear not only regularity in morphological structure, but also high water permeance (1500 L h−1 m−2 bar−1 for the SNIPS, and 3000 L h−1 m−2 bar−1 for the acEIPS). With the participation of pNIPAM-NH2 the consumption of the block copolymer is limited to 7.8 wt % for the SNIPS method, and even to 5.3 wt % for the acEIPS method without non-solvent precipitation process. Besides, the membrane exhibits pH and thermal responsiveness. Li, Xin verfasserin aut Wang, Lei verfasserin aut Xie, Zhiying verfasserin aut Wang, Qimeng verfasserin aut Wang, Kai verfasserin aut Wu, Jianping verfasserin aut Yu, Haizhou verfasserin aut Qiu, Xiaoyan verfasserin aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 669 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:669 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik VZ AR 669 |
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10.1016/j.memsci.2022.121277 doi (DE-627)ELV009076417 (ELSEVIER)S0376-7388(22)01022-5 DE-627 ger DE-627 rda eng 570 VZ 58.11 bkl Liang, Kaiyuan verfasserin aut Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous membrane with SNIPS method is difficult since PAA is extremely hydrophilic; (2) large consumption of block copolymer and non-solvent (water) might limit its application. Herein, isoporous membranes from Polystyrene-block-poly (acrylic acid) (PS-b-PAA) were well prepared with amine terminated poly(N-isopropylacrylamide) (pNIPAM-NH2) through the SNIPS and the airflow accelerated evaporation induced phase separation methods (acEIPS). Such membranes bear not only regularity in morphological structure, but also high water permeance (1500 L h−1 m−2 bar−1 for the SNIPS, and 3000 L h−1 m−2 bar−1 for the acEIPS). With the participation of pNIPAM-NH2 the consumption of the block copolymer is limited to 7.8 wt % for the SNIPS method, and even to 5.3 wt % for the acEIPS method without non-solvent precipitation process. Besides, the membrane exhibits pH and thermal responsiveness. Li, Xin verfasserin aut Wang, Lei verfasserin aut Xie, Zhiying verfasserin aut Wang, Qimeng verfasserin aut Wang, Kai verfasserin aut Wu, Jianping verfasserin aut Yu, Haizhou verfasserin aut Qiu, Xiaoyan verfasserin aut Enthalten in Journal of membrane science New York, NY [u.a.] : Elsevier, 1976 669 Online-Ressource (DE-627)302468927 (DE-600)1491419-0 (DE-576)259483907 0376-7388 nnns volume:669 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.11 Mechanische Verfahrenstechnik VZ AR 669 |
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570 VZ 58.11 bkl Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies |
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Elektronische Aufsätze Aufsätze Elektronische Ressource |
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Journal of membrane science |
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title |
Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies |
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title_full |
Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies |
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Liang, Kaiyuan |
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Journal of membrane science |
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Journal of membrane science |
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Liang, Kaiyuan Li, Xin Wang, Lei Xie, Zhiying Wang, Qimeng Wang, Kai Wu, Jianping Yu, Haizhou Qiu, Xiaoyan |
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570 VZ 58.11 bkl |
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Elektronische Aufsätze |
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Liang, Kaiyuan |
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10.1016/j.memsci.2022.121277 |
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570 |
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verfasserin |
title_sort |
double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies |
title_auth |
Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies |
abstract |
Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous membrane with SNIPS method is difficult since PAA is extremely hydrophilic; (2) large consumption of block copolymer and non-solvent (water) might limit its application. Herein, isoporous membranes from Polystyrene-block-poly (acrylic acid) (PS-b-PAA) were well prepared with amine terminated poly(N-isopropylacrylamide) (pNIPAM-NH2) through the SNIPS and the airflow accelerated evaporation induced phase separation methods (acEIPS). Such membranes bear not only regularity in morphological structure, but also high water permeance (1500 L h−1 m−2 bar−1 for the SNIPS, and 3000 L h−1 m−2 bar−1 for the acEIPS). With the participation of pNIPAM-NH2 the consumption of the block copolymer is limited to 7.8 wt % for the SNIPS method, and even to 5.3 wt % for the acEIPS method without non-solvent precipitation process. Besides, the membrane exhibits pH and thermal responsiveness. |
abstractGer |
Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous membrane with SNIPS method is difficult since PAA is extremely hydrophilic; (2) large consumption of block copolymer and non-solvent (water) might limit its application. Herein, isoporous membranes from Polystyrene-block-poly (acrylic acid) (PS-b-PAA) were well prepared with amine terminated poly(N-isopropylacrylamide) (pNIPAM-NH2) through the SNIPS and the airflow accelerated evaporation induced phase separation methods (acEIPS). Such membranes bear not only regularity in morphological structure, but also high water permeance (1500 L h−1 m−2 bar−1 for the SNIPS, and 3000 L h−1 m−2 bar−1 for the acEIPS). With the participation of pNIPAM-NH2 the consumption of the block copolymer is limited to 7.8 wt % for the SNIPS method, and even to 5.3 wt % for the acEIPS method without non-solvent precipitation process. Besides, the membrane exhibits pH and thermal responsiveness. |
abstract_unstemmed |
Isoporous membranes from block copolymer commonly involves in the self-assembly and non-solvent induced phase separation (SNIPS), which could improve the selectivity and water permeance. However, such strategy face challenges: (1) to prepare poly (acrylic acid) PAA based block copolymer isoporous membrane with SNIPS method is difficult since PAA is extremely hydrophilic; (2) large consumption of block copolymer and non-solvent (water) might limit its application. Herein, isoporous membranes from Polystyrene-block-poly (acrylic acid) (PS-b-PAA) were well prepared with amine terminated poly(N-isopropylacrylamide) (pNIPAM-NH2) through the SNIPS and the airflow accelerated evaporation induced phase separation methods (acEIPS). Such membranes bear not only regularity in morphological structure, but also high water permeance (1500 L h−1 m−2 bar−1 for the SNIPS, and 3000 L h−1 m−2 bar−1 for the acEIPS). With the participation of pNIPAM-NH2 the consumption of the block copolymer is limited to 7.8 wt % for the SNIPS method, and even to 5.3 wt % for the acEIPS method without non-solvent precipitation process. Besides, the membrane exhibits pH and thermal responsiveness. |
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title_short |
Double stimuli-responsive isoporous block copolymer membranes upon phase separation strategies |
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Li, Xin Wang, Lei Xie, Zhiying Wang, Qimeng Wang, Kai Wu, Jianping Yu, Haizhou Qiu, Xiaoyan |
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up_date |
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