Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties

It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent t...
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Gespeichert in:

Autor*in:	Shen, Shuai [verfasserIn] Xin, Yi [verfasserIn] Niu, Zhaoqi [verfasserIn] Ma, Xutao [verfasserIn] Zhang, Junan [verfasserIn] Hou, Xiao [verfasserIn] Ma, Xiaoyan [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	Silicon rubber Phosphazene derivative Thermal protection Ablation mechanism

Übergeordnetes Werk:	Enthalten in: Polymer degradation and stability - Amsterdam [u.a.] : Elsevier Science, 1979, 203
Übergeordnetes Werk:	volume:203

DOI / URN:	10.1016/j.polymdegradstab.2022.110086

Katalog-ID:	ELV009833463

Internformat


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245	1	0	\|a Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties
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520			\|a It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent to cure the condensed room temperature vulcanizing liquid silicone rubber (RTV-CLSR) . The results show that APESP can effectively complete the curing process of condensed silicone rubber taking the place of tetraethyl orthosilicate (TEOS), and enhance the restriction of cross-linking point to molecular chains, thereby effectively improving the mechanical strength, thermal stability, and ablation resistance of SR. Compared with unmodified SR, the tensile strength of APESP modified SR increased by 272%, the elongation at break decreased slightly but still remained at 362%, and the mass residual rate at 800 °C significantly increased by 19.86% when 11 phr APESP was added. The linear ablation rate and mass ablation rate of SR were reduced to 0.239 mm·s−1 and 0.095 g·s−1, a decrease of 60.63% and 44.41%, respectively. This work may provide a new perspective for the application of liquid silicone rubber in the fields with high thermal performance requirements.
650		4	\|a Silicon rubber
650		4	\|a Phosphazene derivative
650		4	\|a Thermal protection
650		4	\|a Ablation mechanism
700	1		\|a Xin, Yi \|e verfasserin \|4 aut
700	1		\|a Niu, Zhaoqi \|e verfasserin \|4 aut
700	1		\|a Ma, Xutao \|e verfasserin \|4 aut
700	1		\|a Zhang, Junan \|e verfasserin \|4 aut
700	1		\|a Hou, Xiao \|e verfasserin \|4 aut
700	1		\|a Ma, Xiaoyan \|e verfasserin \|4 aut
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publishDate	2022
allfields	10.1016/j.polymdegradstab.2022.110086 doi (DE-627)ELV009833463 (ELSEVIER)S0141-3910(22)00264-6 DE-627 ger DE-627 rda eng 540 660 VZ 51.70 bkl 35.80 bkl Shen, Shuai verfasserin aut Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent to cure the condensed room temperature vulcanizing liquid silicone rubber (RTV-CLSR) . The results show that APESP can effectively complete the curing process of condensed silicone rubber taking the place of tetraethyl orthosilicate (TEOS), and enhance the restriction of cross-linking point to molecular chains, thereby effectively improving the mechanical strength, thermal stability, and ablation resistance of SR. Compared with unmodified SR, the tensile strength of APESP modified SR increased by 272%, the elongation at break decreased slightly but still remained at 362%, and the mass residual rate at 800 °C significantly increased by 19.86% when 11 phr APESP was added. The linear ablation rate and mass ablation rate of SR were reduced to 0.239 mm·s−1 and 0.095 g·s−1, a decrease of 60.63% and 44.41%, respectively. This work may provide a new perspective for the application of liquid silicone rubber in the fields with high thermal performance requirements. Silicon rubber Phosphazene derivative Thermal protection Ablation mechanism Xin, Yi verfasserin aut Niu, Zhaoqi verfasserin aut Ma, Xutao verfasserin aut Zhang, Junan verfasserin aut Hou, Xiao verfasserin aut Ma, Xiaoyan verfasserin aut Enthalten in Polymer degradation and stability Amsterdam [u.a.] : Elsevier Science, 1979 203 Online-Ressource (DE-627)308447352 (DE-600)1502217-1 (DE-576)259484288 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde VZ 35.80 Makromolekulare Chemie VZ AR 203
spelling	10.1016/j.polymdegradstab.2022.110086 doi (DE-627)ELV009833463 (ELSEVIER)S0141-3910(22)00264-6 DE-627 ger DE-627 rda eng 540 660 VZ 51.70 bkl 35.80 bkl Shen, Shuai verfasserin aut Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent to cure the condensed room temperature vulcanizing liquid silicone rubber (RTV-CLSR) . The results show that APESP can effectively complete the curing process of condensed silicone rubber taking the place of tetraethyl orthosilicate (TEOS), and enhance the restriction of cross-linking point to molecular chains, thereby effectively improving the mechanical strength, thermal stability, and ablation resistance of SR. Compared with unmodified SR, the tensile strength of APESP modified SR increased by 272%, the elongation at break decreased slightly but still remained at 362%, and the mass residual rate at 800 °C significantly increased by 19.86% when 11 phr APESP was added. The linear ablation rate and mass ablation rate of SR were reduced to 0.239 mm·s−1 and 0.095 g·s−1, a decrease of 60.63% and 44.41%, respectively. This work may provide a new perspective for the application of liquid silicone rubber in the fields with high thermal performance requirements. Silicon rubber Phosphazene derivative Thermal protection Ablation mechanism Xin, Yi verfasserin aut Niu, Zhaoqi verfasserin aut Ma, Xutao verfasserin aut Zhang, Junan verfasserin aut Hou, Xiao verfasserin aut Ma, Xiaoyan verfasserin aut Enthalten in Polymer degradation and stability Amsterdam [u.a.] : Elsevier Science, 1979 203 Online-Ressource (DE-627)308447352 (DE-600)1502217-1 (DE-576)259484288 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde VZ 35.80 Makromolekulare Chemie VZ AR 203
allfields_unstemmed	10.1016/j.polymdegradstab.2022.110086 doi (DE-627)ELV009833463 (ELSEVIER)S0141-3910(22)00264-6 DE-627 ger DE-627 rda eng 540 660 VZ 51.70 bkl 35.80 bkl Shen, Shuai verfasserin aut Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent to cure the condensed room temperature vulcanizing liquid silicone rubber (RTV-CLSR) . The results show that APESP can effectively complete the curing process of condensed silicone rubber taking the place of tetraethyl orthosilicate (TEOS), and enhance the restriction of cross-linking point to molecular chains, thereby effectively improving the mechanical strength, thermal stability, and ablation resistance of SR. Compared with unmodified SR, the tensile strength of APESP modified SR increased by 272%, the elongation at break decreased slightly but still remained at 362%, and the mass residual rate at 800 °C significantly increased by 19.86% when 11 phr APESP was added. The linear ablation rate and mass ablation rate of SR were reduced to 0.239 mm·s−1 and 0.095 g·s−1, a decrease of 60.63% and 44.41%, respectively. This work may provide a new perspective for the application of liquid silicone rubber in the fields with high thermal performance requirements. Silicon rubber Phosphazene derivative Thermal protection Ablation mechanism Xin, Yi verfasserin aut Niu, Zhaoqi verfasserin aut Ma, Xutao verfasserin aut Zhang, Junan verfasserin aut Hou, Xiao verfasserin aut Ma, Xiaoyan verfasserin aut Enthalten in Polymer degradation and stability Amsterdam [u.a.] : Elsevier Science, 1979 203 Online-Ressource (DE-627)308447352 (DE-600)1502217-1 (DE-576)259484288 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde VZ 35.80 Makromolekulare Chemie VZ AR 203
allfieldsGer	10.1016/j.polymdegradstab.2022.110086 doi (DE-627)ELV009833463 (ELSEVIER)S0141-3910(22)00264-6 DE-627 ger DE-627 rda eng 540 660 VZ 51.70 bkl 35.80 bkl Shen, Shuai verfasserin aut Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent to cure the condensed room temperature vulcanizing liquid silicone rubber (RTV-CLSR) . The results show that APESP can effectively complete the curing process of condensed silicone rubber taking the place of tetraethyl orthosilicate (TEOS), and enhance the restriction of cross-linking point to molecular chains, thereby effectively improving the mechanical strength, thermal stability, and ablation resistance of SR. Compared with unmodified SR, the tensile strength of APESP modified SR increased by 272%, the elongation at break decreased slightly but still remained at 362%, and the mass residual rate at 800 °C significantly increased by 19.86% when 11 phr APESP was added. The linear ablation rate and mass ablation rate of SR were reduced to 0.239 mm·s−1 and 0.095 g·s−1, a decrease of 60.63% and 44.41%, respectively. This work may provide a new perspective for the application of liquid silicone rubber in the fields with high thermal performance requirements. Silicon rubber Phosphazene derivative Thermal protection Ablation mechanism Xin, Yi verfasserin aut Niu, Zhaoqi verfasserin aut Ma, Xutao verfasserin aut Zhang, Junan verfasserin aut Hou, Xiao verfasserin aut Ma, Xiaoyan verfasserin aut Enthalten in Polymer degradation and stability Amsterdam [u.a.] : Elsevier Science, 1979 203 Online-Ressource (DE-627)308447352 (DE-600)1502217-1 (DE-576)259484288 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde VZ 35.80 Makromolekulare Chemie VZ AR 203
allfieldsSound	10.1016/j.polymdegradstab.2022.110086 doi (DE-627)ELV009833463 (ELSEVIER)S0141-3910(22)00264-6 DE-627 ger DE-627 rda eng 540 660 VZ 51.70 bkl 35.80 bkl Shen, Shuai verfasserin aut Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent to cure the condensed room temperature vulcanizing liquid silicone rubber (RTV-CLSR) . The results show that APESP can effectively complete the curing process of condensed silicone rubber taking the place of tetraethyl orthosilicate (TEOS), and enhance the restriction of cross-linking point to molecular chains, thereby effectively improving the mechanical strength, thermal stability, and ablation resistance of SR. Compared with unmodified SR, the tensile strength of APESP modified SR increased by 272%, the elongation at break decreased slightly but still remained at 362%, and the mass residual rate at 800 °C significantly increased by 19.86% when 11 phr APESP was added. The linear ablation rate and mass ablation rate of SR were reduced to 0.239 mm·s−1 and 0.095 g·s−1, a decrease of 60.63% and 44.41%, respectively. This work may provide a new perspective for the application of liquid silicone rubber in the fields with high thermal performance requirements. Silicon rubber Phosphazene derivative Thermal protection Ablation mechanism Xin, Yi verfasserin aut Niu, Zhaoqi verfasserin aut Ma, Xutao verfasserin aut Zhang, Junan verfasserin aut Hou, Xiao verfasserin aut Ma, Xiaoyan verfasserin aut Enthalten in Polymer degradation and stability Amsterdam [u.a.] : Elsevier Science, 1979 203 Online-Ressource (DE-627)308447352 (DE-600)1502217-1 (DE-576)259484288 nnns volume:203 GBV_USEFLAG_U SYSFLAG_U GBV_ELV SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2008 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 51.70 Polymerwerkstoffe Kunststoffe Werkstoffkunde VZ 35.80 Makromolekulare Chemie VZ AR 203
language	English
source	Enthalten in Polymer degradation and stability 203 volume:203
sourceStr	Enthalten in Polymer degradation and stability 203 volume:203
format_phy_str_mv	Article
bklname	Polymerwerkstoffe Kunststoffe Makromolekulare Chemie
institution	findex.gbv.de
topic_facet	Silicon rubber Phosphazene derivative Thermal protection Ablation mechanism
dewey-raw	540
isfreeaccess_bool	false
container_title	Polymer degradation and stability
authorswithroles_txt_mv	Shen, Shuai @@aut@@ Xin, Yi @@aut@@ Niu, Zhaoqi @@aut@@ Ma, Xutao @@aut@@ Zhang, Junan @@aut@@ Hou, Xiao @@aut@@ Ma, Xiaoyan @@aut@@
publishDateDaySort_date	2022-01-01T00:00:00Z
hierarchy_top_id	308447352
dewey-sort	3540
id	ELV009833463
language_de	englisch
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author	Shen, Shuai
spellingShingle	Shen, Shuai ddc 540 bkl 51.70 bkl 35.80 misc Silicon rubber misc Phosphazene derivative misc Thermal protection misc Ablation mechanism Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties
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topic_title	540 660 VZ 51.70 bkl 35.80 bkl Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties Silicon rubber Phosphazene derivative Thermal protection Ablation mechanism
topic	ddc 540 bkl 51.70 bkl 35.80 misc Silicon rubber misc Phosphazene derivative misc Thermal protection misc Ablation mechanism
topic_unstemmed	ddc 540 bkl 51.70 bkl 35.80 misc Silicon rubber misc Phosphazene derivative misc Thermal protection misc Ablation mechanism
topic_browse	ddc 540 bkl 51.70 bkl 35.80 misc Silicon rubber misc Phosphazene derivative misc Thermal protection misc Ablation mechanism
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title	Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties
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title_full	Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties
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author_browse	Shen, Shuai Xin, Yi Niu, Zhaoqi Ma, Xutao Zhang, Junan Hou, Xiao Ma, Xiaoyan
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title_sort	phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties
title_auth	Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties
abstract	It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent to cure the condensed room temperature vulcanizing liquid silicone rubber (RTV-CLSR) . The results show that APESP can effectively complete the curing process of condensed silicone rubber taking the place of tetraethyl orthosilicate (TEOS), and enhance the restriction of cross-linking point to molecular chains, thereby effectively improving the mechanical strength, thermal stability, and ablation resistance of SR. Compared with unmodified SR, the tensile strength of APESP modified SR increased by 272%, the elongation at break decreased slightly but still remained at 362%, and the mass residual rate at 800 °C significantly increased by 19.86% when 11 phr APESP was added. The linear ablation rate and mass ablation rate of SR were reduced to 0.239 mm·s−1 and 0.095 g·s−1, a decrease of 60.63% and 44.41%, respectively. This work may provide a new perspective for the application of liquid silicone rubber in the fields with high thermal performance requirements.
abstractGer	It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent to cure the condensed room temperature vulcanizing liquid silicone rubber (RTV-CLSR) . The results show that APESP can effectively complete the curing process of condensed silicone rubber taking the place of tetraethyl orthosilicate (TEOS), and enhance the restriction of cross-linking point to molecular chains, thereby effectively improving the mechanical strength, thermal stability, and ablation resistance of SR. Compared with unmodified SR, the tensile strength of APESP modified SR increased by 272%, the elongation at break decreased slightly but still remained at 362%, and the mass residual rate at 800 °C significantly increased by 19.86% when 11 phr APESP was added. The linear ablation rate and mass ablation rate of SR were reduced to 0.239 mm·s−1 and 0.095 g·s−1, a decrease of 60.63% and 44.41%, respectively. This work may provide a new perspective for the application of liquid silicone rubber in the fields with high thermal performance requirements.
abstract_unstemmed	It is still a challenge for liquid silicone rubber to meet the needs of aerospace and electronics in terms of mechanical and thermal properties. In this study, N3P3 [NH(CH2)3Si(OCH2CH3)3]6 (APESP), a phosphazene derivative containing multiple siliconethoxy groups was adopted as cross-linking agent to cure the condensed room temperature vulcanizing liquid silicone rubber (RTV-CLSR) . The results show that APESP can effectively complete the curing process of condensed silicone rubber taking the place of tetraethyl orthosilicate (TEOS), and enhance the restriction of cross-linking point to molecular chains, thereby effectively improving the mechanical strength, thermal stability, and ablation resistance of SR. Compared with unmodified SR, the tensile strength of APESP modified SR increased by 272%, the elongation at break decreased slightly but still remained at 362%, and the mass residual rate at 800 °C significantly increased by 19.86% when 11 phr APESP was added. The linear ablation rate and mass ablation rate of SR were reduced to 0.239 mm·s−1 and 0.095 g·s−1, a decrease of 60.63% and 44.41%, respectively. This work may provide a new perspective for the application of liquid silicone rubber in the fields with high thermal performance requirements.
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title_short	Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties
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author2	Xin, Yi Niu, Zhaoqi Ma, Xutao Zhang, Junan Hou, Xiao Ma, Xiaoyan
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doi_str	10.1016/j.polymdegradstab.2022.110086
up_date	2024-07-07T00:30:38.383Z
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Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties

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