Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity

In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearanc...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Suppaso, Chomponoot [verfasserIn] Pongkan, Nipaporn [verfasserIn] Intachai, Sonchai [verfasserIn] Inchongkol, Yollada [verfasserIn] Bureekaew, Sareeya [verfasserIn] Khaorapapong, Nithima [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Tin sulfide Cadmium sulfide Photocatalytic degradation Montmorillonite Rhodamine 6G

Übergeordnetes Werk:	Enthalten in: Applied clay science - New York, NY [u.a.] : Elsevier, 1985, 241
Übergeordnetes Werk:	volume:241

DOI / URN:	10.1016/j.clay.2023.106999

Katalog-ID:	ELV010399275

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245	1	0	\|a Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity
264		1	\|c 2023
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520			\|a In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. This result represented an important role of montmorillonite and the heterostructures of SnS and CdS in tailoring the photocatalytic properties.
650		4	\|a Tin sulfide
650		4	\|a Cadmium sulfide
650		4	\|a Photocatalytic degradation
650		4	\|a Montmorillonite
650		4	\|a Rhodamine 6G
700	1		\|a Pongkan, Nipaporn \|e verfasserin \|4 aut
700	1		\|a Intachai, Sonchai \|e verfasserin \|4 aut
700	1		\|a Inchongkol, Yollada \|e verfasserin \|4 aut
700	1		\|a Bureekaew, Sareeya \|e verfasserin \|4 aut
700	1		\|a Khaorapapong, Nithima \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Applied clay science \|d New York, NY [u.a.] : Elsevier, 1985 \|g 241 \|h Online-Ressource \|w (DE-627)302723021 \|w (DE-600)1492353-1 \|w (DE-576)256138613 \|7 nnns
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936	b	k	\|a 38.30 \|j Mineralogie \|q VZ
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951			\|a AR
952			\|d 241

Indexfelder

author_variant	c s cs n p np s i si y i yi s b sb n k nk
matchkey_str	suppasochomponootpongkannipapornintachai:2023----:islieadamuslieitrimnmrloieihnacdiill
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publishDate	2023
allfields	10.1016/j.clay.2023.106999 doi (DE-627)ELV010399275 (ELSEVIER)S0169-1317(23)00186-2 DE-627 ger DE-627 rda eng 550 VZ 38.30 bkl 58.45 bkl 38.69 bkl 56.20 bkl Suppaso, Chomponoot verfasserin aut Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. This result represented an important role of montmorillonite and the heterostructures of SnS and CdS in tailoring the photocatalytic properties. Tin sulfide Cadmium sulfide Photocatalytic degradation Montmorillonite Rhodamine 6G Pongkan, Nipaporn verfasserin aut Intachai, Sonchai verfasserin aut Inchongkol, Yollada verfasserin aut Bureekaew, Sareeya verfasserin aut Khaorapapong, Nithima verfasserin aut Enthalten in Applied clay science New York, NY [u.a.] : Elsevier, 1985 241 Online-Ressource (DE-627)302723021 (DE-600)1492353-1 (DE-576)256138613 nnns volume:241 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.30 Mineralogie VZ 58.45 Gesteinshüttenkunde VZ 38.69 Bodenkunde: Sonstiges Geowissenschaften VZ 56.20 Ingenieurgeologie Bodenmechanik VZ AR 241
spelling	10.1016/j.clay.2023.106999 doi (DE-627)ELV010399275 (ELSEVIER)S0169-1317(23)00186-2 DE-627 ger DE-627 rda eng 550 VZ 38.30 bkl 58.45 bkl 38.69 bkl 56.20 bkl Suppaso, Chomponoot verfasserin aut Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. This result represented an important role of montmorillonite and the heterostructures of SnS and CdS in tailoring the photocatalytic properties. Tin sulfide Cadmium sulfide Photocatalytic degradation Montmorillonite Rhodamine 6G Pongkan, Nipaporn verfasserin aut Intachai, Sonchai verfasserin aut Inchongkol, Yollada verfasserin aut Bureekaew, Sareeya verfasserin aut Khaorapapong, Nithima verfasserin aut Enthalten in Applied clay science New York, NY [u.a.] : Elsevier, 1985 241 Online-Ressource (DE-627)302723021 (DE-600)1492353-1 (DE-576)256138613 nnns volume:241 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.30 Mineralogie VZ 58.45 Gesteinshüttenkunde VZ 38.69 Bodenkunde: Sonstiges Geowissenschaften VZ 56.20 Ingenieurgeologie Bodenmechanik VZ AR 241
allfields_unstemmed	10.1016/j.clay.2023.106999 doi (DE-627)ELV010399275 (ELSEVIER)S0169-1317(23)00186-2 DE-627 ger DE-627 rda eng 550 VZ 38.30 bkl 58.45 bkl 38.69 bkl 56.20 bkl Suppaso, Chomponoot verfasserin aut Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. This result represented an important role of montmorillonite and the heterostructures of SnS and CdS in tailoring the photocatalytic properties. Tin sulfide Cadmium sulfide Photocatalytic degradation Montmorillonite Rhodamine 6G Pongkan, Nipaporn verfasserin aut Intachai, Sonchai verfasserin aut Inchongkol, Yollada verfasserin aut Bureekaew, Sareeya verfasserin aut Khaorapapong, Nithima verfasserin aut Enthalten in Applied clay science New York, NY [u.a.] : Elsevier, 1985 241 Online-Ressource (DE-627)302723021 (DE-600)1492353-1 (DE-576)256138613 nnns volume:241 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.30 Mineralogie VZ 58.45 Gesteinshüttenkunde VZ 38.69 Bodenkunde: Sonstiges Geowissenschaften VZ 56.20 Ingenieurgeologie Bodenmechanik VZ AR 241
allfieldsGer	10.1016/j.clay.2023.106999 doi (DE-627)ELV010399275 (ELSEVIER)S0169-1317(23)00186-2 DE-627 ger DE-627 rda eng 550 VZ 38.30 bkl 58.45 bkl 38.69 bkl 56.20 bkl Suppaso, Chomponoot verfasserin aut Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. This result represented an important role of montmorillonite and the heterostructures of SnS and CdS in tailoring the photocatalytic properties. Tin sulfide Cadmium sulfide Photocatalytic degradation Montmorillonite Rhodamine 6G Pongkan, Nipaporn verfasserin aut Intachai, Sonchai verfasserin aut Inchongkol, Yollada verfasserin aut Bureekaew, Sareeya verfasserin aut Khaorapapong, Nithima verfasserin aut Enthalten in Applied clay science New York, NY [u.a.] : Elsevier, 1985 241 Online-Ressource (DE-627)302723021 (DE-600)1492353-1 (DE-576)256138613 nnns volume:241 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.30 Mineralogie VZ 58.45 Gesteinshüttenkunde VZ 38.69 Bodenkunde: Sonstiges Geowissenschaften VZ 56.20 Ingenieurgeologie Bodenmechanik VZ AR 241
allfieldsSound	10.1016/j.clay.2023.106999 doi (DE-627)ELV010399275 (ELSEVIER)S0169-1317(23)00186-2 DE-627 ger DE-627 rda eng 550 VZ 38.30 bkl 58.45 bkl 38.69 bkl 56.20 bkl Suppaso, Chomponoot verfasserin aut Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. This result represented an important role of montmorillonite and the heterostructures of SnS and CdS in tailoring the photocatalytic properties. Tin sulfide Cadmium sulfide Photocatalytic degradation Montmorillonite Rhodamine 6G Pongkan, Nipaporn verfasserin aut Intachai, Sonchai verfasserin aut Inchongkol, Yollada verfasserin aut Bureekaew, Sareeya verfasserin aut Khaorapapong, Nithima verfasserin aut Enthalten in Applied clay science New York, NY [u.a.] : Elsevier, 1985 241 Online-Ressource (DE-627)302723021 (DE-600)1492353-1 (DE-576)256138613 nnns volume:241 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.30 Mineralogie VZ 58.45 Gesteinshüttenkunde VZ 38.69 Bodenkunde: Sonstiges Geowissenschaften VZ 56.20 Ingenieurgeologie Bodenmechanik VZ AR 241
language	English
source	Enthalten in Applied clay science 241 volume:241
sourceStr	Enthalten in Applied clay science 241 volume:241
format_phy_str_mv	Article
bklname	Mineralogie Gesteinshüttenkunde Bodenkunde: Sonstiges Ingenieurgeologie Bodenmechanik
institution	findex.gbv.de
topic_facet	Tin sulfide Cadmium sulfide Photocatalytic degradation Montmorillonite Rhodamine 6G
dewey-raw	550
isfreeaccess_bool	false
container_title	Applied clay science
authorswithroles_txt_mv	Suppaso, Chomponoot @@aut@@ Pongkan, Nipaporn @@aut@@ Intachai, Sonchai @@aut@@ Inchongkol, Yollada @@aut@@ Bureekaew, Sareeya @@aut@@ Khaorapapong, Nithima @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	302723021
dewey-sort	3550
id	ELV010399275
language_de	englisch
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author	Suppaso, Chomponoot
spellingShingle	Suppaso, Chomponoot ddc 550 bkl 38.30 bkl 58.45 bkl 38.69 bkl 56.20 misc Tin sulfide misc Cadmium sulfide misc Photocatalytic degradation misc Montmorillonite misc Rhodamine 6G Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity
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topic_title	550 VZ 38.30 bkl 58.45 bkl 38.69 bkl 56.20 bkl Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity Tin sulfide Cadmium sulfide Photocatalytic degradation Montmorillonite Rhodamine 6G
topic	ddc 550 bkl 38.30 bkl 58.45 bkl 38.69 bkl 56.20 misc Tin sulfide misc Cadmium sulfide misc Photocatalytic degradation misc Montmorillonite misc Rhodamine 6G
topic_unstemmed	ddc 550 bkl 38.30 bkl 58.45 bkl 38.69 bkl 56.20 misc Tin sulfide misc Cadmium sulfide misc Photocatalytic degradation misc Montmorillonite misc Rhodamine 6G
topic_browse	ddc 550 bkl 38.30 bkl 58.45 bkl 38.69 bkl 56.20 misc Tin sulfide misc Cadmium sulfide misc Photocatalytic degradation misc Montmorillonite misc Rhodamine 6G
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title	Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity
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title_full	Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity
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title_sort	tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity
title_auth	Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity
abstract	In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. This result represented an important role of montmorillonite and the heterostructures of SnS and CdS in tailoring the photocatalytic properties.
abstractGer	In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. This result represented an important role of montmorillonite and the heterostructures of SnS and CdS in tailoring the photocatalytic properties.
abstract_unstemmed	In situ formation of tin sulfide (SnS) and cadmium sulfide (CdS) mixture in montmorillonite was carried out by the reaction between an aqueous dispersion of Sn2+- and Cd2+-montmorillonite and an aqueous solution of S2− (from Na2S). The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. This result represented an important role of montmorillonite and the heterostructures of SnS and CdS in tailoring the photocatalytic properties.
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title_short	Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity
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author2	Pongkan, Nipaporn Intachai, Sonchai Inchongkol, Yollada Bureekaew, Sareeya Khaorapapong, Nithima
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up_date	2024-07-06T17:51:15.378Z
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The effects of Sn2+ / Cd2+ molar ratios were examined. The appearance of two diffraction peaks (d 001 = 1.3 and 1.4 nm) and/or the large mismatch (8%) of SnS and CdS lattices were attributed to the possible formation of SnS and CdS in two different interlayer spaces (segregation) of montmorillonite. The blue shifts of the absorption onset relating to the expansion of band gap energy, and the emission band as well as the increase of emission intensity of the intercalated SnS and CdS mixture were observed with increasing SnS / CdS molar ratio. The photodegradation of rhodamine 6G solution was achieved within 360 min by using the product, which has the molar ratio of Sn / Cd = 3:1. The photocatalytic process followed pseudo-first-order kinetic with a rate constant of 0.011 min−1. The scavenger test indicated that superoxide radical (O2 •-) was the predominant species involved in the photocatalytic process. 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Tin sulfides and cadmium sulfide mixture in montmorillonite with enhanced visible-light photocatalytic activity

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