Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale

A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to sim...
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Gespeichert in:

Autor*in:	Russo, Vincenzo [verfasserIn] Tesser, Riccardo [verfasserIn] Hreczuch, Wiesław [verfasserIn] Di Serio, Martino [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Ethoxylation Microreactors Modeling Laminar flow model Scale-up

Übergeordnetes Werk:	Enthalten in: Chemical engineering research and design - Amsterdam : Elsevier, 1983, 194, Seite 550-562
Übergeordnetes Werk:	volume:194 ; pages:550-562

DOI / URN:	10.1016/j.cherd.2023.04.051

Katalog-ID:	ELV010513035

Internformat


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520			\|a A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to simulate a wide range of conditions. Ethylene oxide diffusivity and liquid mixture viscosity were determined by applying existing correlations, carefully considering the change in viscosity with ethylene oxide conversion, temperature, and feed ethylene oxide/1-octanol ratio. The model was tested on literature data obtaining in every case good results. The obtained kinetic data were demonstrated to be in line with the ones obtained in separate investigations conducted in a fed-batch reactor, demonstrating that there was a real need in adopting the laminar flow reactor approach, as it allowed to retrieve of more precise information about the intrinsic kinetics of the ethoxylation reaction, when working with microreactors, compared with the ones obtainable with a plug-flow ideal fluid-dynamic model. The developed model was used to simulate the behavior of a milli-reactor (this device allows to reach sufficient productivity for industrial application) and it was forecasted the possibility to use continuous ethoxylation milli-reactors using fluid-dynamic conditions characterized by a high Reynolds number (>10000).
650		4	\|a Ethoxylation
650		4	\|a Microreactors
650		4	\|a Modeling
650		4	\|a Laminar flow model
650		4	\|a Scale-up
700	1		\|a Tesser, Riccardo \|e verfasserin \|4 aut
700	1		\|a Hreczuch, Wiesław \|e verfasserin \|4 aut
700	1		\|a Di Serio, Martino \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t Chemical engineering research and design \|d Amsterdam : Elsevier, 1983 \|g 194, Seite 550-562 \|h Online-Ressource \|w (DE-627)312841965 \|w (DE-600)2008006-2 \|w (DE-576)090893190 \|x 1744-3563 \|7 nnns
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allfields	10.1016/j.cherd.2023.04.051 doi (DE-627)ELV010513035 (ELSEVIER)S0263-8762(23)00263-0 DE-627 ger DE-627 rda eng 540 660 VZ 58.10 bkl Russo, Vincenzo verfasserin (orcid)0000-0002-1867-739X aut Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to simulate a wide range of conditions. Ethylene oxide diffusivity and liquid mixture viscosity were determined by applying existing correlations, carefully considering the change in viscosity with ethylene oxide conversion, temperature, and feed ethylene oxide/1-octanol ratio. The model was tested on literature data obtaining in every case good results. The obtained kinetic data were demonstrated to be in line with the ones obtained in separate investigations conducted in a fed-batch reactor, demonstrating that there was a real need in adopting the laminar flow reactor approach, as it allowed to retrieve of more precise information about the intrinsic kinetics of the ethoxylation reaction, when working with microreactors, compared with the ones obtainable with a plug-flow ideal fluid-dynamic model. The developed model was used to simulate the behavior of a milli-reactor (this device allows to reach sufficient productivity for industrial application) and it was forecasted the possibility to use continuous ethoxylation milli-reactors using fluid-dynamic conditions characterized by a high Reynolds number (>10000). Ethoxylation Microreactors Modeling Laminar flow model Scale-up Tesser, Riccardo verfasserin aut Hreczuch, Wiesław verfasserin aut Di Serio, Martino verfasserin aut Enthalten in Chemical engineering research and design Amsterdam : Elsevier, 1983 194, Seite 550-562 Online-Ressource (DE-627)312841965 (DE-600)2008006-2 (DE-576)090893190 1744-3563 nnns volume:194 pages:550-562 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.10 Verfahrenstechnik: Allgemeines VZ AR 194 550-562
spelling	10.1016/j.cherd.2023.04.051 doi (DE-627)ELV010513035 (ELSEVIER)S0263-8762(23)00263-0 DE-627 ger DE-627 rda eng 540 660 VZ 58.10 bkl Russo, Vincenzo verfasserin (orcid)0000-0002-1867-739X aut Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to simulate a wide range of conditions. Ethylene oxide diffusivity and liquid mixture viscosity were determined by applying existing correlations, carefully considering the change in viscosity with ethylene oxide conversion, temperature, and feed ethylene oxide/1-octanol ratio. The model was tested on literature data obtaining in every case good results. The obtained kinetic data were demonstrated to be in line with the ones obtained in separate investigations conducted in a fed-batch reactor, demonstrating that there was a real need in adopting the laminar flow reactor approach, as it allowed to retrieve of more precise information about the intrinsic kinetics of the ethoxylation reaction, when working with microreactors, compared with the ones obtainable with a plug-flow ideal fluid-dynamic model. The developed model was used to simulate the behavior of a milli-reactor (this device allows to reach sufficient productivity for industrial application) and it was forecasted the possibility to use continuous ethoxylation milli-reactors using fluid-dynamic conditions characterized by a high Reynolds number (>10000). Ethoxylation Microreactors Modeling Laminar flow model Scale-up Tesser, Riccardo verfasserin aut Hreczuch, Wiesław verfasserin aut Di Serio, Martino verfasserin aut Enthalten in Chemical engineering research and design Amsterdam : Elsevier, 1983 194, Seite 550-562 Online-Ressource (DE-627)312841965 (DE-600)2008006-2 (DE-576)090893190 1744-3563 nnns volume:194 pages:550-562 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.10 Verfahrenstechnik: Allgemeines VZ AR 194 550-562
allfields_unstemmed	10.1016/j.cherd.2023.04.051 doi (DE-627)ELV010513035 (ELSEVIER)S0263-8762(23)00263-0 DE-627 ger DE-627 rda eng 540 660 VZ 58.10 bkl Russo, Vincenzo verfasserin (orcid)0000-0002-1867-739X aut Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to simulate a wide range of conditions. Ethylene oxide diffusivity and liquid mixture viscosity were determined by applying existing correlations, carefully considering the change in viscosity with ethylene oxide conversion, temperature, and feed ethylene oxide/1-octanol ratio. The model was tested on literature data obtaining in every case good results. The obtained kinetic data were demonstrated to be in line with the ones obtained in separate investigations conducted in a fed-batch reactor, demonstrating that there was a real need in adopting the laminar flow reactor approach, as it allowed to retrieve of more precise information about the intrinsic kinetics of the ethoxylation reaction, when working with microreactors, compared with the ones obtainable with a plug-flow ideal fluid-dynamic model. The developed model was used to simulate the behavior of a milli-reactor (this device allows to reach sufficient productivity for industrial application) and it was forecasted the possibility to use continuous ethoxylation milli-reactors using fluid-dynamic conditions characterized by a high Reynolds number (>10000). Ethoxylation Microreactors Modeling Laminar flow model Scale-up Tesser, Riccardo verfasserin aut Hreczuch, Wiesław verfasserin aut Di Serio, Martino verfasserin aut Enthalten in Chemical engineering research and design Amsterdam : Elsevier, 1983 194, Seite 550-562 Online-Ressource (DE-627)312841965 (DE-600)2008006-2 (DE-576)090893190 1744-3563 nnns volume:194 pages:550-562 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.10 Verfahrenstechnik: Allgemeines VZ AR 194 550-562
allfieldsGer	10.1016/j.cherd.2023.04.051 doi (DE-627)ELV010513035 (ELSEVIER)S0263-8762(23)00263-0 DE-627 ger DE-627 rda eng 540 660 VZ 58.10 bkl Russo, Vincenzo verfasserin (orcid)0000-0002-1867-739X aut Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to simulate a wide range of conditions. Ethylene oxide diffusivity and liquid mixture viscosity were determined by applying existing correlations, carefully considering the change in viscosity with ethylene oxide conversion, temperature, and feed ethylene oxide/1-octanol ratio. The model was tested on literature data obtaining in every case good results. The obtained kinetic data were demonstrated to be in line with the ones obtained in separate investigations conducted in a fed-batch reactor, demonstrating that there was a real need in adopting the laminar flow reactor approach, as it allowed to retrieve of more precise information about the intrinsic kinetics of the ethoxylation reaction, when working with microreactors, compared with the ones obtainable with a plug-flow ideal fluid-dynamic model. The developed model was used to simulate the behavior of a milli-reactor (this device allows to reach sufficient productivity for industrial application) and it was forecasted the possibility to use continuous ethoxylation milli-reactors using fluid-dynamic conditions characterized by a high Reynolds number (>10000). Ethoxylation Microreactors Modeling Laminar flow model Scale-up Tesser, Riccardo verfasserin aut Hreczuch, Wiesław verfasserin aut Di Serio, Martino verfasserin aut Enthalten in Chemical engineering research and design Amsterdam : Elsevier, 1983 194, Seite 550-562 Online-Ressource (DE-627)312841965 (DE-600)2008006-2 (DE-576)090893190 1744-3563 nnns volume:194 pages:550-562 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.10 Verfahrenstechnik: Allgemeines VZ AR 194 550-562
allfieldsSound	10.1016/j.cherd.2023.04.051 doi (DE-627)ELV010513035 (ELSEVIER)S0263-8762(23)00263-0 DE-627 ger DE-627 rda eng 540 660 VZ 58.10 bkl Russo, Vincenzo verfasserin (orcid)0000-0002-1867-739X aut Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to simulate a wide range of conditions. Ethylene oxide diffusivity and liquid mixture viscosity were determined by applying existing correlations, carefully considering the change in viscosity with ethylene oxide conversion, temperature, and feed ethylene oxide/1-octanol ratio. The model was tested on literature data obtaining in every case good results. The obtained kinetic data were demonstrated to be in line with the ones obtained in separate investigations conducted in a fed-batch reactor, demonstrating that there was a real need in adopting the laminar flow reactor approach, as it allowed to retrieve of more precise information about the intrinsic kinetics of the ethoxylation reaction, when working with microreactors, compared with the ones obtainable with a plug-flow ideal fluid-dynamic model. The developed model was used to simulate the behavior of a milli-reactor (this device allows to reach sufficient productivity for industrial application) and it was forecasted the possibility to use continuous ethoxylation milli-reactors using fluid-dynamic conditions characterized by a high Reynolds number (>10000). Ethoxylation Microreactors Modeling Laminar flow model Scale-up Tesser, Riccardo verfasserin aut Hreczuch, Wiesław verfasserin aut Di Serio, Martino verfasserin aut Enthalten in Chemical engineering research and design Amsterdam : Elsevier, 1983 194, Seite 550-562 Online-Ressource (DE-627)312841965 (DE-600)2008006-2 (DE-576)090893190 1744-3563 nnns volume:194 pages:550-562 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.10 Verfahrenstechnik: Allgemeines VZ AR 194 550-562
language	English
source	Enthalten in Chemical engineering research and design 194, Seite 550-562 volume:194 pages:550-562
sourceStr	Enthalten in Chemical engineering research and design 194, Seite 550-562 volume:194 pages:550-562
format_phy_str_mv	Article
bklname	Verfahrenstechnik: Allgemeines
institution	findex.gbv.de
topic_facet	Ethoxylation Microreactors Modeling Laminar flow model Scale-up
dewey-raw	540
isfreeaccess_bool	false
container_title	Chemical engineering research and design
authorswithroles_txt_mv	Russo, Vincenzo @@aut@@ Tesser, Riccardo @@aut@@ Hreczuch, Wiesław @@aut@@ Di Serio, Martino @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	312841965
dewey-sort	3540
id	ELV010513035
language_de	englisch
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author	Russo, Vincenzo
spellingShingle	Russo, Vincenzo ddc 540 bkl 58.10 misc Ethoxylation misc Microreactors misc Modeling misc Laminar flow model misc Scale-up Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale
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topic_title	540 660 VZ 58.10 bkl Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale Ethoxylation Microreactors Modeling Laminar flow model Scale-up
topic	ddc 540 bkl 58.10 misc Ethoxylation misc Microreactors misc Modeling misc Laminar flow model misc Scale-up
topic_unstemmed	ddc 540 bkl 58.10 misc Ethoxylation misc Microreactors misc Modeling misc Laminar flow model misc Scale-up
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title	Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale
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title_full	Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale
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author_browse	Russo, Vincenzo Tesser, Riccardo Hreczuch, Wiesław Di Serio, Martino
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title_sort	design of a continuous device for ethoxylation reaction: the choice between micro and milli scale
title_auth	Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale
abstract	A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to simulate a wide range of conditions. Ethylene oxide diffusivity and liquid mixture viscosity were determined by applying existing correlations, carefully considering the change in viscosity with ethylene oxide conversion, temperature, and feed ethylene oxide/1-octanol ratio. The model was tested on literature data obtaining in every case good results. The obtained kinetic data were demonstrated to be in line with the ones obtained in separate investigations conducted in a fed-batch reactor, demonstrating that there was a real need in adopting the laminar flow reactor approach, as it allowed to retrieve of more precise information about the intrinsic kinetics of the ethoxylation reaction, when working with microreactors, compared with the ones obtainable with a plug-flow ideal fluid-dynamic model. The developed model was used to simulate the behavior of a milli-reactor (this device allows to reach sufficient productivity for industrial application) and it was forecasted the possibility to use continuous ethoxylation milli-reactors using fluid-dynamic conditions characterized by a high Reynolds number (>10000).
abstractGer	A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to simulate a wide range of conditions. Ethylene oxide diffusivity and liquid mixture viscosity were determined by applying existing correlations, carefully considering the change in viscosity with ethylene oxide conversion, temperature, and feed ethylene oxide/1-octanol ratio. The model was tested on literature data obtaining in every case good results. The obtained kinetic data were demonstrated to be in line with the ones obtained in separate investigations conducted in a fed-batch reactor, demonstrating that there was a real need in adopting the laminar flow reactor approach, as it allowed to retrieve of more precise information about the intrinsic kinetics of the ethoxylation reaction, when working with microreactors, compared with the ones obtainable with a plug-flow ideal fluid-dynamic model. The developed model was used to simulate the behavior of a milli-reactor (this device allows to reach sufficient productivity for industrial application) and it was forecasted the possibility to use continuous ethoxylation milli-reactors using fluid-dynamic conditions characterized by a high Reynolds number (>10000).
abstract_unstemmed	A laminar flow model was developed to investigate the reaction kinetics of 1-dodecanol ethoxylation promoted by KOH, elaborating the data collected in microreactors. A generic laminar flow model was coded, and a sensitivity analysis was conducted highlighting the good flexibility of the model to simulate a wide range of conditions. Ethylene oxide diffusivity and liquid mixture viscosity were determined by applying existing correlations, carefully considering the change in viscosity with ethylene oxide conversion, temperature, and feed ethylene oxide/1-octanol ratio. The model was tested on literature data obtaining in every case good results. The obtained kinetic data were demonstrated to be in line with the ones obtained in separate investigations conducted in a fed-batch reactor, demonstrating that there was a real need in adopting the laminar flow reactor approach, as it allowed to retrieve of more precise information about the intrinsic kinetics of the ethoxylation reaction, when working with microreactors, compared with the ones obtainable with a plug-flow ideal fluid-dynamic model. The developed model was used to simulate the behavior of a milli-reactor (this device allows to reach sufficient productivity for industrial application) and it was forecasted the possibility to use continuous ethoxylation milli-reactors using fluid-dynamic conditions characterized by a high Reynolds number (>10000).
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title_short	Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale
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author2	Tesser, Riccardo Hreczuch, Wiesław Di Serio, Martino
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up_date	2024-07-06T18:15:17.379Z
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Design of a continuous device for ethoxylation reaction: The choice between micro and milli scale

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