Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity

A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Sharma, Shubham [verfasserIn] Mehtab, Sameena [verfasserIn] Zaidi, M.G.H. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	Supercritical processing Multiwalled carbon nanotube Boron nitride Nanohybrids Electrical conductivity Thermal stability

Übergeordnetes Werk:	Enthalten in: Materials chemistry and physics - New York, NY [u.a.] : Elsevier, 1983, 296
Übergeordnetes Werk:	volume:296

DOI / URN:	10.1016/j.matchemphys.2022.127278

Katalog-ID:	ELV01054402X

Internformat


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245	1	0	\|a Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity
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520			\|a A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-BN) into carboxylate functional multiwalled carbon nanotube (c-MWCNT) at 1200 psi, 90 ± 1°C over 5 hr in SCC. Formation of NHs was ascertained through diverse analytical methods. Scanning electron microscopy coupled with energy dispersive spectra, elemental mapping and X-ray diffraction analysis reveals deposition of h-BN over the surface of c-MWCNT. NHs derived at 5 wt% of h-BN has shown reduced optical band gap (Eg, 3.34 eV) with 41 % increase in crystallite size. Working electrodes (WEs) derived from NHs has rendered increasing trend of DC conductivity (mS/cm) with concentration of h-BN up to 5 wt% at 100 V. WEs involving h-BN (5 wt%) has shown enhanced DC conductivity (0.93) followed by c-MWCNT (0.63) and h-BN (0.41) at 100 V. Present investigation delivers a clean, dry and environmentally benign method of processing of NHs suitable for development of inexpensive WEs for potential applications in hydrogen storage, electrocatalysis and sensors.
650		4	\|a Supercritical processing
650		4	\|a Multiwalled carbon nanotube
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650		4	\|a Nanohybrids
650		4	\|a Electrical conductivity
650		4	\|a Thermal stability
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publishDate	2022
allfields	10.1016/j.matchemphys.2022.127278 doi (DE-627)ELV01054402X (ELSEVIER)S0254-0584(22)01584-X DE-627 ger DE-627 rda eng 540 530 VZ ASIEN DE-1a fid 6,25 ssgn 35.90 bkl 33.61 bkl 51.00 bkl Sharma, Shubham verfasserin aut Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-BN) into carboxylate functional multiwalled carbon nanotube (c-MWCNT) at 1200 psi, 90 ± 1°C over 5 hr in SCC. Formation of NHs was ascertained through diverse analytical methods. Scanning electron microscopy coupled with energy dispersive spectra, elemental mapping and X-ray diffraction analysis reveals deposition of h-BN over the surface of c-MWCNT. NHs derived at 5 wt% of h-BN has shown reduced optical band gap (Eg, 3.34 eV) with 41 % increase in crystallite size. Working electrodes (WEs) derived from NHs has rendered increasing trend of DC conductivity (mS/cm) with concentration of h-BN up to 5 wt% at 100 V. WEs involving h-BN (5 wt%) has shown enhanced DC conductivity (0.93) followed by c-MWCNT (0.63) and h-BN (0.41) at 100 V. Present investigation delivers a clean, dry and environmentally benign method of processing of NHs suitable for development of inexpensive WEs for potential applications in hydrogen storage, electrocatalysis and sensors. Supercritical processing Multiwalled carbon nanotube Boron nitride Nanohybrids Electrical conductivity Thermal stability Mehtab, Sameena verfasserin (orcid)0000-0002-8110-4770 aut Zaidi, M.G.H. verfasserin aut Enthalten in Materials chemistry and physics New York, NY [u.a.] : Elsevier, 1983 296 Online-Ressource (DE-627)302719350 (DE-600)1491959-X (DE-576)096806435 nnns volume:296 GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-ASIEN SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.90 Festkörperchemie VZ 33.61 Festkörperphysik VZ 51.00 Werkstoffkunde: Allgemeines VZ AR 296
spelling	10.1016/j.matchemphys.2022.127278 doi (DE-627)ELV01054402X (ELSEVIER)S0254-0584(22)01584-X DE-627 ger DE-627 rda eng 540 530 VZ ASIEN DE-1a fid 6,25 ssgn 35.90 bkl 33.61 bkl 51.00 bkl Sharma, Shubham verfasserin aut Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-BN) into carboxylate functional multiwalled carbon nanotube (c-MWCNT) at 1200 psi, 90 ± 1°C over 5 hr in SCC. Formation of NHs was ascertained through diverse analytical methods. Scanning electron microscopy coupled with energy dispersive spectra, elemental mapping and X-ray diffraction analysis reveals deposition of h-BN over the surface of c-MWCNT. NHs derived at 5 wt% of h-BN has shown reduced optical band gap (Eg, 3.34 eV) with 41 % increase in crystallite size. Working electrodes (WEs) derived from NHs has rendered increasing trend of DC conductivity (mS/cm) with concentration of h-BN up to 5 wt% at 100 V. WEs involving h-BN (5 wt%) has shown enhanced DC conductivity (0.93) followed by c-MWCNT (0.63) and h-BN (0.41) at 100 V. Present investigation delivers a clean, dry and environmentally benign method of processing of NHs suitable for development of inexpensive WEs for potential applications in hydrogen storage, electrocatalysis and sensors. Supercritical processing Multiwalled carbon nanotube Boron nitride Nanohybrids Electrical conductivity Thermal stability Mehtab, Sameena verfasserin (orcid)0000-0002-8110-4770 aut Zaidi, M.G.H. verfasserin aut Enthalten in Materials chemistry and physics New York, NY [u.a.] : Elsevier, 1983 296 Online-Ressource (DE-627)302719350 (DE-600)1491959-X (DE-576)096806435 nnns volume:296 GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-ASIEN SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.90 Festkörperchemie VZ 33.61 Festkörperphysik VZ 51.00 Werkstoffkunde: Allgemeines VZ AR 296
allfields_unstemmed	10.1016/j.matchemphys.2022.127278 doi (DE-627)ELV01054402X (ELSEVIER)S0254-0584(22)01584-X DE-627 ger DE-627 rda eng 540 530 VZ ASIEN DE-1a fid 6,25 ssgn 35.90 bkl 33.61 bkl 51.00 bkl Sharma, Shubham verfasserin aut Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-BN) into carboxylate functional multiwalled carbon nanotube (c-MWCNT) at 1200 psi, 90 ± 1°C over 5 hr in SCC. Formation of NHs was ascertained through diverse analytical methods. Scanning electron microscopy coupled with energy dispersive spectra, elemental mapping and X-ray diffraction analysis reveals deposition of h-BN over the surface of c-MWCNT. NHs derived at 5 wt% of h-BN has shown reduced optical band gap (Eg, 3.34 eV) with 41 % increase in crystallite size. Working electrodes (WEs) derived from NHs has rendered increasing trend of DC conductivity (mS/cm) with concentration of h-BN up to 5 wt% at 100 V. WEs involving h-BN (5 wt%) has shown enhanced DC conductivity (0.93) followed by c-MWCNT (0.63) and h-BN (0.41) at 100 V. Present investigation delivers a clean, dry and environmentally benign method of processing of NHs suitable for development of inexpensive WEs for potential applications in hydrogen storage, electrocatalysis and sensors. Supercritical processing Multiwalled carbon nanotube Boron nitride Nanohybrids Electrical conductivity Thermal stability Mehtab, Sameena verfasserin (orcid)0000-0002-8110-4770 aut Zaidi, M.G.H. verfasserin aut Enthalten in Materials chemistry and physics New York, NY [u.a.] : Elsevier, 1983 296 Online-Ressource (DE-627)302719350 (DE-600)1491959-X (DE-576)096806435 nnns volume:296 GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-ASIEN SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.90 Festkörperchemie VZ 33.61 Festkörperphysik VZ 51.00 Werkstoffkunde: Allgemeines VZ AR 296
allfieldsGer	10.1016/j.matchemphys.2022.127278 doi (DE-627)ELV01054402X (ELSEVIER)S0254-0584(22)01584-X DE-627 ger DE-627 rda eng 540 530 VZ ASIEN DE-1a fid 6,25 ssgn 35.90 bkl 33.61 bkl 51.00 bkl Sharma, Shubham verfasserin aut Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-BN) into carboxylate functional multiwalled carbon nanotube (c-MWCNT) at 1200 psi, 90 ± 1°C over 5 hr in SCC. Formation of NHs was ascertained through diverse analytical methods. Scanning electron microscopy coupled with energy dispersive spectra, elemental mapping and X-ray diffraction analysis reveals deposition of h-BN over the surface of c-MWCNT. NHs derived at 5 wt% of h-BN has shown reduced optical band gap (Eg, 3.34 eV) with 41 % increase in crystallite size. Working electrodes (WEs) derived from NHs has rendered increasing trend of DC conductivity (mS/cm) with concentration of h-BN up to 5 wt% at 100 V. WEs involving h-BN (5 wt%) has shown enhanced DC conductivity (0.93) followed by c-MWCNT (0.63) and h-BN (0.41) at 100 V. Present investigation delivers a clean, dry and environmentally benign method of processing of NHs suitable for development of inexpensive WEs for potential applications in hydrogen storage, electrocatalysis and sensors. Supercritical processing Multiwalled carbon nanotube Boron nitride Nanohybrids Electrical conductivity Thermal stability Mehtab, Sameena verfasserin (orcid)0000-0002-8110-4770 aut Zaidi, M.G.H. verfasserin aut Enthalten in Materials chemistry and physics New York, NY [u.a.] : Elsevier, 1983 296 Online-Ressource (DE-627)302719350 (DE-600)1491959-X (DE-576)096806435 nnns volume:296 GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-ASIEN SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.90 Festkörperchemie VZ 33.61 Festkörperphysik VZ 51.00 Werkstoffkunde: Allgemeines VZ AR 296
allfieldsSound	10.1016/j.matchemphys.2022.127278 doi (DE-627)ELV01054402X (ELSEVIER)S0254-0584(22)01584-X DE-627 ger DE-627 rda eng 540 530 VZ ASIEN DE-1a fid 6,25 ssgn 35.90 bkl 33.61 bkl 51.00 bkl Sharma, Shubham verfasserin aut Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-BN) into carboxylate functional multiwalled carbon nanotube (c-MWCNT) at 1200 psi, 90 ± 1°C over 5 hr in SCC. Formation of NHs was ascertained through diverse analytical methods. Scanning electron microscopy coupled with energy dispersive spectra, elemental mapping and X-ray diffraction analysis reveals deposition of h-BN over the surface of c-MWCNT. NHs derived at 5 wt% of h-BN has shown reduced optical band gap (Eg, 3.34 eV) with 41 % increase in crystallite size. Working electrodes (WEs) derived from NHs has rendered increasing trend of DC conductivity (mS/cm) with concentration of h-BN up to 5 wt% at 100 V. WEs involving h-BN (5 wt%) has shown enhanced DC conductivity (0.93) followed by c-MWCNT (0.63) and h-BN (0.41) at 100 V. Present investigation delivers a clean, dry and environmentally benign method of processing of NHs suitable for development of inexpensive WEs for potential applications in hydrogen storage, electrocatalysis and sensors. Supercritical processing Multiwalled carbon nanotube Boron nitride Nanohybrids Electrical conductivity Thermal stability Mehtab, Sameena verfasserin (orcid)0000-0002-8110-4770 aut Zaidi, M.G.H. verfasserin aut Enthalten in Materials chemistry and physics New York, NY [u.a.] : Elsevier, 1983 296 Online-Ressource (DE-627)302719350 (DE-600)1491959-X (DE-576)096806435 nnns volume:296 GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-ASIEN SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 35.90 Festkörperchemie VZ 33.61 Festkörperphysik VZ 51.00 Werkstoffkunde: Allgemeines VZ AR 296
language	English
source	Enthalten in Materials chemistry and physics 296 volume:296
sourceStr	Enthalten in Materials chemistry and physics 296 volume:296
format_phy_str_mv	Article
bklname	Festkörperchemie Festkörperphysik Werkstoffkunde: Allgemeines
institution	findex.gbv.de
topic_facet	Supercritical processing Multiwalled carbon nanotube Boron nitride Nanohybrids Electrical conductivity Thermal stability
dewey-raw	540
isfreeaccess_bool	false
container_title	Materials chemistry and physics
authorswithroles_txt_mv	Sharma, Shubham @@aut@@ Mehtab, Sameena @@aut@@ Zaidi, M.G.H. @@aut@@
publishDateDaySort_date	2022-01-01T00:00:00Z
hierarchy_top_id	302719350
dewey-sort	3540
id	ELV01054402X
language_de	englisch
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author	Sharma, Shubham
spellingShingle	Sharma, Shubham ddc 540 fid ASIEN ssgn 6,25 bkl 35.90 bkl 33.61 bkl 51.00 misc Supercritical processing misc Multiwalled carbon nanotube misc Boron nitride misc Nanohybrids misc Electrical conductivity misc Thermal stability Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity
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topic_title	540 530 VZ ASIEN DE-1a fid 6,25 ssgn 35.90 bkl 33.61 bkl 51.00 bkl Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity Supercritical processing Multiwalled carbon nanotube Boron nitride Nanohybrids Electrical conductivity Thermal stability
topic	ddc 540 fid ASIEN ssgn 6,25 bkl 35.90 bkl 33.61 bkl 51.00 misc Supercritical processing misc Multiwalled carbon nanotube misc Boron nitride misc Nanohybrids misc Electrical conductivity misc Thermal stability
topic_unstemmed	ddc 540 fid ASIEN ssgn 6,25 bkl 35.90 bkl 33.61 bkl 51.00 misc Supercritical processing misc Multiwalled carbon nanotube misc Boron nitride misc Nanohybrids misc Electrical conductivity misc Thermal stability
topic_browse	ddc 540 fid ASIEN ssgn 6,25 bkl 35.90 bkl 33.61 bkl 51.00 misc Supercritical processing misc Multiwalled carbon nanotube misc Boron nitride misc Nanohybrids misc Electrical conductivity misc Thermal stability
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title	Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity
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title_full	Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity
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title_sort	supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity
title_auth	Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity
abstract	A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-BN) into carboxylate functional multiwalled carbon nanotube (c-MWCNT) at 1200 psi, 90 ± 1°C over 5 hr in SCC. Formation of NHs was ascertained through diverse analytical methods. Scanning electron microscopy coupled with energy dispersive spectra, elemental mapping and X-ray diffraction analysis reveals deposition of h-BN over the surface of c-MWCNT. NHs derived at 5 wt% of h-BN has shown reduced optical band gap (Eg, 3.34 eV) with 41 % increase in crystallite size. Working electrodes (WEs) derived from NHs has rendered increasing trend of DC conductivity (mS/cm) with concentration of h-BN up to 5 wt% at 100 V. WEs involving h-BN (5 wt%) has shown enhanced DC conductivity (0.93) followed by c-MWCNT (0.63) and h-BN (0.41) at 100 V. Present investigation delivers a clean, dry and environmentally benign method of processing of NHs suitable for development of inexpensive WEs for potential applications in hydrogen storage, electrocatalysis and sensors.
abstractGer	A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-BN) into carboxylate functional multiwalled carbon nanotube (c-MWCNT) at 1200 psi, 90 ± 1°C over 5 hr in SCC. Formation of NHs was ascertained through diverse analytical methods. Scanning electron microscopy coupled with energy dispersive spectra, elemental mapping and X-ray diffraction analysis reveals deposition of h-BN over the surface of c-MWCNT. NHs derived at 5 wt% of h-BN has shown reduced optical band gap (Eg, 3.34 eV) with 41 % increase in crystallite size. Working electrodes (WEs) derived from NHs has rendered increasing trend of DC conductivity (mS/cm) with concentration of h-BN up to 5 wt% at 100 V. WEs involving h-BN (5 wt%) has shown enhanced DC conductivity (0.93) followed by c-MWCNT (0.63) and h-BN (0.41) at 100 V. Present investigation delivers a clean, dry and environmentally benign method of processing of NHs suitable for development of inexpensive WEs for potential applications in hydrogen storage, electrocatalysis and sensors.
abstract_unstemmed	A novel method of processing of thermally stable nanohybrids (NHs) with synergistically improved electrical conductivity (σDC) has been developed in supercritical carbon dioxide (SCC). Processing of NHs was executed through dispersion of selected weight fractions (wt%) of hexagonal boron nitride (h-BN) into carboxylate functional multiwalled carbon nanotube (c-MWCNT) at 1200 psi, 90 ± 1°C over 5 hr in SCC. Formation of NHs was ascertained through diverse analytical methods. Scanning electron microscopy coupled with energy dispersive spectra, elemental mapping and X-ray diffraction analysis reveals deposition of h-BN over the surface of c-MWCNT. NHs derived at 5 wt% of h-BN has shown reduced optical band gap (Eg, 3.34 eV) with 41 % increase in crystallite size. Working electrodes (WEs) derived from NHs has rendered increasing trend of DC conductivity (mS/cm) with concentration of h-BN up to 5 wt% at 100 V. WEs involving h-BN (5 wt%) has shown enhanced DC conductivity (0.93) followed by c-MWCNT (0.63) and h-BN (0.41) at 100 V. Present investigation delivers a clean, dry and environmentally benign method of processing of NHs suitable for development of inexpensive WEs for potential applications in hydrogen storage, electrocatalysis and sensors.
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title_short	Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity
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author2	Mehtab, Sameena Zaidi, M.G.H.
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up_date	2024-07-06T18:21:54.715Z
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Supercritical processing of thermally stable multiwalled carbon nanotube/boron nitride nanohybrids with synergistically improved electrical conductivity

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