Mixed ligand complex formation of 2-aminobenzamide with Cu(II) in the presence of some amino acids: Synthesis, structural, biological, pH-metric, spectrophotometric and thermodynamic studies
Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows a...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Dharmaraja, Jeyaprakash [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2013transfer abstract |
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| Schlagwörter: |
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| Umfang: |
15 |
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| Übergeordnetes Werk: |
Enthalten in: Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training - An, Chen-Chi ELSEVIER, 2017, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:114 ; year:2013 ; pages:607-621 ; extent:15 |
| Links: |
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| DOI / URN: |
10.1016/j.saa.2013.05.043 |
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| 520 | |a Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. | ||
| 520 | |a Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. | ||
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10.1016/j.saa.2013.05.043 doi GBVA2013003000001.pica (DE-627)ELV011350172 (ELSEVIER)S1386-1425(13)00532-5 DE-627 ger DE-627 rakwb eng 540 530 540 DE-600 530 DE-600 660 VZ 50.21 bkl Dharmaraja, Jeyaprakash verfasserin aut Mixed ligand complex formation of 2-aminobenzamide with Cu(II) in the presence of some amino acids: Synthesis, structural, biological, pH-metric, spectrophotometric and thermodynamic studies 2013transfer abstract 15 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. 2AB Elsevier MIC Elsevier CT DNA Elsevier EB Elsevier Esakkidurai, Thirugnanasamy oth Subbaraj, Paramasivam oth Shobana, Sutha oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:114 year:2013 pages:607-621 extent:15 https://doi.org/10.1016/j.saa.2013.05.043 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 114 2013 607-621 15 045F 540 |
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10.1016/j.saa.2013.05.043 doi GBVA2013003000001.pica (DE-627)ELV011350172 (ELSEVIER)S1386-1425(13)00532-5 DE-627 ger DE-627 rakwb eng 540 530 540 DE-600 530 DE-600 660 VZ 50.21 bkl Dharmaraja, Jeyaprakash verfasserin aut Mixed ligand complex formation of 2-aminobenzamide with Cu(II) in the presence of some amino acids: Synthesis, structural, biological, pH-metric, spectrophotometric and thermodynamic studies 2013transfer abstract 15 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. 2AB Elsevier MIC Elsevier CT DNA Elsevier EB Elsevier Esakkidurai, Thirugnanasamy oth Subbaraj, Paramasivam oth Shobana, Sutha oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:114 year:2013 pages:607-621 extent:15 https://doi.org/10.1016/j.saa.2013.05.043 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 114 2013 607-621 15 045F 540 |
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10.1016/j.saa.2013.05.043 doi GBVA2013003000001.pica (DE-627)ELV011350172 (ELSEVIER)S1386-1425(13)00532-5 DE-627 ger DE-627 rakwb eng 540 530 540 DE-600 530 DE-600 660 VZ 50.21 bkl Dharmaraja, Jeyaprakash verfasserin aut Mixed ligand complex formation of 2-aminobenzamide with Cu(II) in the presence of some amino acids: Synthesis, structural, biological, pH-metric, spectrophotometric and thermodynamic studies 2013transfer abstract 15 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. 2AB Elsevier MIC Elsevier CT DNA Elsevier EB Elsevier Esakkidurai, Thirugnanasamy oth Subbaraj, Paramasivam oth Shobana, Sutha oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:114 year:2013 pages:607-621 extent:15 https://doi.org/10.1016/j.saa.2013.05.043 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 114 2013 607-621 15 045F 540 |
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10.1016/j.saa.2013.05.043 doi GBVA2013003000001.pica (DE-627)ELV011350172 (ELSEVIER)S1386-1425(13)00532-5 DE-627 ger DE-627 rakwb eng 540 530 540 DE-600 530 DE-600 660 VZ 50.21 bkl Dharmaraja, Jeyaprakash verfasserin aut Mixed ligand complex formation of 2-aminobenzamide with Cu(II) in the presence of some amino acids: Synthesis, structural, biological, pH-metric, spectrophotometric and thermodynamic studies 2013transfer abstract 15 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. 2AB Elsevier MIC Elsevier CT DNA Elsevier EB Elsevier Esakkidurai, Thirugnanasamy oth Subbaraj, Paramasivam oth Shobana, Sutha oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:114 year:2013 pages:607-621 extent:15 https://doi.org/10.1016/j.saa.2013.05.043 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 114 2013 607-621 15 045F 540 |
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10.1016/j.saa.2013.05.043 doi GBVA2013003000001.pica (DE-627)ELV011350172 (ELSEVIER)S1386-1425(13)00532-5 DE-627 ger DE-627 rakwb eng 540 530 540 DE-600 530 DE-600 660 VZ 50.21 bkl Dharmaraja, Jeyaprakash verfasserin aut Mixed ligand complex formation of 2-aminobenzamide with Cu(II) in the presence of some amino acids: Synthesis, structural, biological, pH-metric, spectrophotometric and thermodynamic studies 2013transfer abstract 15 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. 2AB Elsevier MIC Elsevier CT DNA Elsevier EB Elsevier Esakkidurai, Thirugnanasamy oth Subbaraj, Paramasivam oth Shobana, Sutha oth Enthalten in Elsevier Science An, Chen-Chi ELSEVIER Developing an audio analyzer for instantaneous stroke position identification on table tennis racket to assist technical training 2017 Amsterdam [u.a.] (DE-627)ELV000384860 volume:114 year:2013 pages:607-621 extent:15 https://doi.org/10.1016/j.saa.2013.05.043 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 50.21 Messtechnik VZ AR 114 2013 607-621 15 045F 540 |
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Mixed ligand complex formation of 2-aminobenzamide with Cu(II) in the presence of some amino acids: Synthesis, structural, biological, pH-metric, spectrophotometric and thermodynamic studies |
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Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. |
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Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. |
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Mixed ligand Cu(II) complexes of 2-aminobenzamide (2AB) and amino acids viz., glycine (gly), l-alanine (ala), l-valine (val) and l-phenylalanine (phe) have been synthesised and characterized by various physico-chemical and spectral techniques. The powder X-ray diffractogram and SEM pictogram shows all the complexes have homogeneous morphology with well-defined crystalline nature. The cleavage and binding interactions of mixed ligand complexes with calf thymus DNA under aerobic conditions show moderate activities. Also, the complex formation of Cu(II) involving 2-aminobenzamide and amino acids were carried out by a combined pH-metric and spectrophotometric techniques in 50% (v/v) water-ethanol mixture at 300, 310, 320 and 330±0.1K with I =0.15moldm−3 (NaClO4). In solution, CuAB and CuAB2 species has been detected and the calculated stabilization value indicates higher stabilities for the mixed ligand complexes rather than their binary species. Thermodynamic parameters have also been determined from the temperature dependence of stability constant. In vitro biological activities of 2-aminobenzamide, CuA and CuAB complexes show remarkable activities. |
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Mixed ligand complex formation of 2-aminobenzamide with Cu(II) in the presence of some amino acids: Synthesis, structural, biological, pH-metric, spectrophotometric and thermodynamic studies |
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