Capacitive Behaviours of Phosphorus-Rich Carbons Derived from Lignocelluloses
A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorp...
Ausführliche Beschreibung
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| Autor*in: |
Huang, Congcong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014transfer abstract |
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| Umfang: |
9 |
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| Übergeordnetes Werk: |
Enthalten in: Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch - Zhang, Lei ELSEVIER, 2018, the journal of the International Society of Electrochemistry (ISE), New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:137 ; year:2014 ; day:10 ; month:08 ; pages:219-227 ; extent:9 |
| Links: |
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| DOI / URN: |
10.1016/j.electacta.2014.05.101 |
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ELV012571180 |
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| 520 | |a A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. | ||
| 520 | |a A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. | ||
| 650 | 7 | |a Phosphorus-rich carbon |2 Elsevier | |
| 650 | 7 | |a Surface functional groups |2 Elsevier | |
| 650 | 7 | |a Supercapacitor |2 Elsevier | |
| 650 | 7 | |a Biomass |2 Elsevier | |
| 700 | 1 | |a Puziy, Alexander M. |4 oth | |
| 700 | 1 | |a Sun, Ting |4 oth | |
| 700 | 1 | |a Poddubnaya, Olga I. |4 oth | |
| 700 | 1 | |a Suárez-García, Fabián |4 oth | |
| 700 | 1 | |a Tascón, Juan M.D. |4 oth | |
| 700 | 1 | |a Hulicova-Jurcakova, Denisa |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Zhang, Lei ELSEVIER |t Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch |d 2018 |d the journal of the International Society of Electrochemistry (ISE) |g New York, NY [u.a.] |w (DE-627)ELV001212419 |
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10.1016/j.electacta.2014.05.101 doi GBVA2014020000023.pica (DE-627)ELV012571180 (ELSEVIER)S0013-4686(14)01102-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.00 bkl Huang, Congcong verfasserin aut Capacitive Behaviours of Phosphorus-Rich Carbons Derived from Lignocelluloses 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. Phosphorus-rich carbon Elsevier Surface functional groups Elsevier Supercapacitor Elsevier Biomass Elsevier Puziy, Alexander M. oth Sun, Ting oth Poddubnaya, Olga I. oth Suárez-García, Fabián oth Tascón, Juan M.D. oth Hulicova-Jurcakova, Denisa oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:137 year:2014 day:10 month:08 pages:219-227 extent:9 https://doi.org/10.1016/j.electacta.2014.05.101 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 137 2014 10 0810 219-227 9 045F 540 |
| spelling |
10.1016/j.electacta.2014.05.101 doi GBVA2014020000023.pica (DE-627)ELV012571180 (ELSEVIER)S0013-4686(14)01102-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.00 bkl Huang, Congcong verfasserin aut Capacitive Behaviours of Phosphorus-Rich Carbons Derived from Lignocelluloses 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. Phosphorus-rich carbon Elsevier Surface functional groups Elsevier Supercapacitor Elsevier Biomass Elsevier Puziy, Alexander M. oth Sun, Ting oth Poddubnaya, Olga I. oth Suárez-García, Fabián oth Tascón, Juan M.D. oth Hulicova-Jurcakova, Denisa oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:137 year:2014 day:10 month:08 pages:219-227 extent:9 https://doi.org/10.1016/j.electacta.2014.05.101 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 137 2014 10 0810 219-227 9 045F 540 |
| allfields_unstemmed |
10.1016/j.electacta.2014.05.101 doi GBVA2014020000023.pica (DE-627)ELV012571180 (ELSEVIER)S0013-4686(14)01102-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.00 bkl Huang, Congcong verfasserin aut Capacitive Behaviours of Phosphorus-Rich Carbons Derived from Lignocelluloses 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. Phosphorus-rich carbon Elsevier Surface functional groups Elsevier Supercapacitor Elsevier Biomass Elsevier Puziy, Alexander M. oth Sun, Ting oth Poddubnaya, Olga I. oth Suárez-García, Fabián oth Tascón, Juan M.D. oth Hulicova-Jurcakova, Denisa oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:137 year:2014 day:10 month:08 pages:219-227 extent:9 https://doi.org/10.1016/j.electacta.2014.05.101 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 137 2014 10 0810 219-227 9 045F 540 |
| allfieldsGer |
10.1016/j.electacta.2014.05.101 doi GBVA2014020000023.pica (DE-627)ELV012571180 (ELSEVIER)S0013-4686(14)01102-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.00 bkl Huang, Congcong verfasserin aut Capacitive Behaviours of Phosphorus-Rich Carbons Derived from Lignocelluloses 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. Phosphorus-rich carbon Elsevier Surface functional groups Elsevier Supercapacitor Elsevier Biomass Elsevier Puziy, Alexander M. oth Sun, Ting oth Poddubnaya, Olga I. oth Suárez-García, Fabián oth Tascón, Juan M.D. oth Hulicova-Jurcakova, Denisa oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:137 year:2014 day:10 month:08 pages:219-227 extent:9 https://doi.org/10.1016/j.electacta.2014.05.101 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 137 2014 10 0810 219-227 9 045F 540 |
| allfieldsSound |
10.1016/j.electacta.2014.05.101 doi GBVA2014020000023.pica (DE-627)ELV012571180 (ELSEVIER)S0013-4686(14)01102-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.00 bkl Huang, Congcong verfasserin aut Capacitive Behaviours of Phosphorus-Rich Carbons Derived from Lignocelluloses 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. Phosphorus-rich carbon Elsevier Surface functional groups Elsevier Supercapacitor Elsevier Biomass Elsevier Puziy, Alexander M. oth Sun, Ting oth Poddubnaya, Olga I. oth Suárez-García, Fabián oth Tascón, Juan M.D. oth Hulicova-Jurcakova, Denisa oth Enthalten in Elsevier Zhang, Lei ELSEVIER Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch 2018 the journal of the International Society of Electrochemistry (ISE) New York, NY [u.a.] (DE-627)ELV001212419 volume:137 year:2014 day:10 month:08 pages:219-227 extent:9 https://doi.org/10.1016/j.electacta.2014.05.101 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.00 Medizin: Allgemeines VZ AR 137 2014 10 0810 219-227 9 045F 540 |
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Enthalten in Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch New York, NY [u.a.] volume:137 year:2014 day:10 month:08 pages:219-227 extent:9 |
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Enthalten in Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch New York, NY [u.a.] volume:137 year:2014 day:10 month:08 pages:219-227 extent:9 |
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Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch |
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Huang, Congcong @@aut@@ Puziy, Alexander M. @@oth@@ Sun, Ting @@oth@@ Poddubnaya, Olga I. @@oth@@ Suárez-García, Fabián @@oth@@ Tascón, Juan M.D. @@oth@@ Hulicova-Jurcakova, Denisa @@oth@@ |
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This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. 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Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch |
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Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch |
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Computed tomographic morphometric analysis of lateral inclination C1 pedicle screw for atlantoaxial instability patients with a narrow C1 posterior arch |
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capacitive behaviours of phosphorus-rich carbons derived from lignocelluloses |
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Capacitive Behaviours of Phosphorus-Rich Carbons Derived from Lignocelluloses |
| abstract |
A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. |
| abstractGer |
A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. |
| abstract_unstemmed |
A series of phosphorus and oxygen enriched carbons prepared by phosphoric acid activation of the lignocellulosic waste, fruit stones, are studied as the electrodes of supercapacitor in 1M H2SO4 electrolyte. The microstructure and surface properties of the carbons are characterized by N2 and CO2 sorptions and X-ray photoelectron spectroscopy (XPS), respectively. Cyclic voltammetry, galvanostatic charge/discharge and wide potential window test are carried out to evaluate the electrochemical performances of the carbon electrodes. Statistical analysis is employed to confirm the limitation of the operation potential of the supercapacitors. The results show that the sample with balanced porous structure and higher phosphorus content exhibits a specific capacitance of 165 F g−1, delivers an energy density of 13 Wh kg−1 at an operation window of 1.5V, and shows stable cycling performance with a retention ratio of 99% even after 20000 cycles. This work suggests that the adjusted pore structure and surface functional groups which influenced the capacitive performance of the carbon electrode can be finely adjusted by the activation temperature. |
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Puziy, Alexander M. Sun, Ting Poddubnaya, Olga I. Suárez-García, Fabián Tascón, Juan M.D. Hulicova-Jurcakova, Denisa |
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