Determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: A lixiviation study
An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for u...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Camino-Sánchez, F.J. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016transfer abstract |
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| Schlagwörter: |
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| Umfang: |
10 |
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| Übergeordnetes Werk: |
Enthalten in: Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications - Mohamed, S.H. ELSEVIER, 2019, the international journal of pure and applied analytical chemistry, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:150 ; year:2016 ; day:1 ; month:04 ; pages:415-424 ; extent:10 |
| Links: |
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| DOI / URN: |
10.1016/j.talanta.2015.12.031 |
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| 245 | 1 | 0 | |a Determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: A lixiviation study |
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| 520 | |a An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. | ||
| 520 | |a An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. | ||
| 650 | 7 | |a Ultrasound assisted extraction |2 Elsevier | |
| 650 | 7 | |a UHPLC-MS/MS |2 Elsevier | |
| 650 | 7 | |a Lixiviation |2 Elsevier | |
| 650 | 7 | |a Compost and soil pollution |2 Elsevier | |
| 650 | 7 | |a Sewage sludge |2 Elsevier | |
| 650 | 7 | |a Endocrine disrupting chemicals |2 Elsevier | |
| 700 | 1 | |a Zafra-Gómez, A. |4 oth | |
| 700 | 1 | |a Dorival-García, N. |4 oth | |
| 700 | 1 | |a Juárez-Jiménez, B. |4 oth | |
| 700 | 1 | |a Vílchez, J.L. |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Mohamed, S.H. ELSEVIER |t Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications |d 2019 |d the international journal of pure and applied analytical chemistry |g Amsterdam [u.a.] |w (DE-627)ELV003060667 |
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10.1016/j.talanta.2015.12.031 doi GBVA2016001000022.pica (DE-627)ELV013635905 (ELSEVIER)S0039-9140(15)30561-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 620 VZ 53.56 bkl Camino-Sánchez, F.J. verfasserin aut Determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: A lixiviation study 2016transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. Ultrasound assisted extraction Elsevier UHPLC-MS/MS Elsevier Lixiviation Elsevier Compost and soil pollution Elsevier Sewage sludge Elsevier Endocrine disrupting chemicals Elsevier Zafra-Gómez, A. oth Dorival-García, N. oth Juárez-Jiménez, B. oth Vílchez, J.L. oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:150 year:2016 day:1 month:04 pages:415-424 extent:10 https://doi.org/10.1016/j.talanta.2015.12.031 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 150 2016 1 0401 415-424 10 045F 540 |
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10.1016/j.talanta.2015.12.031 doi GBVA2016001000022.pica (DE-627)ELV013635905 (ELSEVIER)S0039-9140(15)30561-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 620 VZ 53.56 bkl Camino-Sánchez, F.J. verfasserin aut Determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: A lixiviation study 2016transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. Ultrasound assisted extraction Elsevier UHPLC-MS/MS Elsevier Lixiviation Elsevier Compost and soil pollution Elsevier Sewage sludge Elsevier Endocrine disrupting chemicals Elsevier Zafra-Gómez, A. oth Dorival-García, N. oth Juárez-Jiménez, B. oth Vílchez, J.L. oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:150 year:2016 day:1 month:04 pages:415-424 extent:10 https://doi.org/10.1016/j.talanta.2015.12.031 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 150 2016 1 0401 415-424 10 045F 540 |
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10.1016/j.talanta.2015.12.031 doi GBVA2016001000022.pica (DE-627)ELV013635905 (ELSEVIER)S0039-9140(15)30561-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 620 VZ 53.56 bkl Camino-Sánchez, F.J. verfasserin aut Determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: A lixiviation study 2016transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. Ultrasound assisted extraction Elsevier UHPLC-MS/MS Elsevier Lixiviation Elsevier Compost and soil pollution Elsevier Sewage sludge Elsevier Endocrine disrupting chemicals Elsevier Zafra-Gómez, A. oth Dorival-García, N. oth Juárez-Jiménez, B. oth Vílchez, J.L. oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:150 year:2016 day:1 month:04 pages:415-424 extent:10 https://doi.org/10.1016/j.talanta.2015.12.031 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 150 2016 1 0401 415-424 10 045F 540 |
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10.1016/j.talanta.2015.12.031 doi GBVA2016001000022.pica (DE-627)ELV013635905 (ELSEVIER)S0039-9140(15)30561-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 620 VZ 53.56 bkl Camino-Sánchez, F.J. verfasserin aut Determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: A lixiviation study 2016transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. Ultrasound assisted extraction Elsevier UHPLC-MS/MS Elsevier Lixiviation Elsevier Compost and soil pollution Elsevier Sewage sludge Elsevier Endocrine disrupting chemicals Elsevier Zafra-Gómez, A. oth Dorival-García, N. oth Juárez-Jiménez, B. oth Vílchez, J.L. oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:150 year:2016 day:1 month:04 pages:415-424 extent:10 https://doi.org/10.1016/j.talanta.2015.12.031 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 150 2016 1 0401 415-424 10 045F 540 |
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10.1016/j.talanta.2015.12.031 doi GBVA2016001000022.pica (DE-627)ELV013635905 (ELSEVIER)S0039-9140(15)30561-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 620 VZ 53.56 bkl Camino-Sánchez, F.J. verfasserin aut Determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: A lixiviation study 2016transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. Ultrasound assisted extraction Elsevier UHPLC-MS/MS Elsevier Lixiviation Elsevier Compost and soil pollution Elsevier Sewage sludge Elsevier Endocrine disrupting chemicals Elsevier Zafra-Gómez, A. oth Dorival-García, N. oth Juárez-Jiménez, B. oth Vílchez, J.L. oth Enthalten in Elsevier Science Mohamed, S.H. ELSEVIER Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications 2019 the international journal of pure and applied analytical chemistry Amsterdam [u.a.] (DE-627)ELV003060667 volume:150 year:2016 day:1 month:04 pages:415-424 extent:10 https://doi.org/10.1016/j.talanta.2015.12.031 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 53.56 Halbleitertechnologie VZ AR 150 2016 1 0401 415-424 10 045F 540 |
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Enthalten in Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications Amsterdam [u.a.] volume:150 year:2016 day:1 month:04 pages:415-424 extent:10 |
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Enthalten in Optical, water splitting and wettability of titanium nitride/titanium oxynitride bilayer films for hydrogen generation and solar cells applications Amsterdam [u.a.] volume:150 year:2016 day:1 month:04 pages:415-424 extent:10 |
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determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: a lixiviation study |
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Determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: A lixiviation study |
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An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. |
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An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. |
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An accurate and sensitive method for the determination of selected EDCs in soil and compost from wastewater treatment plants is developed and validated. Five parabens, six benzophenone-UV filters and the antibacterials triclosan and triclocarban were selected as target analytes. The parameters for ultrasound-assisted extraction were thoroughly optimized. After extraction, the analytes were detected and quantified using ultra-high performance liquid chromatography tandem mass spectrometry. Ethylparaben (ring–13C6 labelled) and deuterated benzophenone (BP-d10) were used as internal standards. The method was validated using matrix–matched calibration and recovery assays with spiked samples. The limits of detection ranged from 0.03 to 0.40ngg−1 and the limits of quantification from 0.1 to 1.0ngg−1, while precision in terms of relative standard deviation was between 9% and 21%. Recovery rates ranged from 83% to 107%. The validated method was applied for the study of the behavior of the selected compounds in agricultural soils treated and un-treated with compost from WWTP. A lixiviation study was developed in both agricultural soil and treated soil and first order kinetic models of their disappearance at different depths are proposed. The application of organic composts in the soil leads to an increase of the disappearance rate of the studied compounds. The lixiviation study also shows the risk of pollution of groundwater aquifers after disposal or waste of these EDCs in agricultural soils is not high. |
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Determination of selected parabens, benzophenones, triclosan and triclocarban in agricultural soils after and before treatment with compost from sewage sludge: A lixiviation study |
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