Preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium
Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The...
Ausführliche Beschreibung
Autor*in: |
Wang, Xin [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2016transfer abstract |
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Umfang: |
9 |
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Übergeordnetes Werk: |
Enthalten in: Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method - Xiao, Hong ELSEVIER, 2013, the international journal on the science and technology of electrochemical energy systems, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:303 ; year:2016 ; day:30 ; month:01 ; pages:278-286 ; extent:9 |
Links: |
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DOI / URN: |
10.1016/j.jpowsour.2015.11.007 |
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Katalog-ID: |
ELV014163365 |
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520 | |a Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. | ||
520 | |a Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. | ||
650 | 7 | |a Hydrogen peroxide |2 Elsevier | |
650 | 7 | |a Palladium catalyst |2 Elsevier | |
650 | 7 | |a Nanopore |2 Elsevier | |
650 | 7 | |a Electroreduction |2 Elsevier | |
650 | 7 | |a Nanowire arrays |2 Elsevier | |
700 | 1 | |a Ye, Ke |4 oth | |
700 | 1 | |a Gao, Yinyi |4 oth | |
700 | 1 | |a Zhang, Hongyu |4 oth | |
700 | 1 | |a Cheng, Kui |4 oth | |
700 | 1 | |a Xiao, Xue |4 oth | |
700 | 1 | |a Wang, Guiling |4 oth | |
700 | 1 | |a Cao, Dianxue |4 oth | |
773 | 0 | 8 | |i Enthalten in |n Elsevier |a Xiao, Hong ELSEVIER |t Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method |d 2013 |d the international journal on the science and technology of electrochemical energy systems |g New York, NY [u.a.] |w (DE-627)ELV00098745X |
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10.1016/j.jpowsour.2015.11.007 doi GBVA2016013000014.pica (DE-627)ELV014163365 (ELSEVIER)S0378-7753(15)30506-1 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Wang, Xin verfasserin aut Preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Hydrogen peroxide Elsevier Palladium catalyst Elsevier Nanopore Elsevier Electroreduction Elsevier Nanowire arrays Elsevier Ye, Ke oth Gao, Yinyi oth Zhang, Hongyu oth Cheng, Kui oth Xiao, Xue oth Wang, Guiling oth Cao, Dianxue oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:303 year:2016 day:30 month:01 pages:278-286 extent:9 https://doi.org/10.1016/j.jpowsour.2015.11.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 303 2016 30 0130 278-286 9 045F 620 |
spelling |
10.1016/j.jpowsour.2015.11.007 doi GBVA2016013000014.pica (DE-627)ELV014163365 (ELSEVIER)S0378-7753(15)30506-1 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Wang, Xin verfasserin aut Preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Hydrogen peroxide Elsevier Palladium catalyst Elsevier Nanopore Elsevier Electroreduction Elsevier Nanowire arrays Elsevier Ye, Ke oth Gao, Yinyi oth Zhang, Hongyu oth Cheng, Kui oth Xiao, Xue oth Wang, Guiling oth Cao, Dianxue oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:303 year:2016 day:30 month:01 pages:278-286 extent:9 https://doi.org/10.1016/j.jpowsour.2015.11.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 303 2016 30 0130 278-286 9 045F 620 |
allfields_unstemmed |
10.1016/j.jpowsour.2015.11.007 doi GBVA2016013000014.pica (DE-627)ELV014163365 (ELSEVIER)S0378-7753(15)30506-1 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Wang, Xin verfasserin aut Preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Hydrogen peroxide Elsevier Palladium catalyst Elsevier Nanopore Elsevier Electroreduction Elsevier Nanowire arrays Elsevier Ye, Ke oth Gao, Yinyi oth Zhang, Hongyu oth Cheng, Kui oth Xiao, Xue oth Wang, Guiling oth Cao, Dianxue oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:303 year:2016 day:30 month:01 pages:278-286 extent:9 https://doi.org/10.1016/j.jpowsour.2015.11.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 303 2016 30 0130 278-286 9 045F 620 |
allfieldsGer |
10.1016/j.jpowsour.2015.11.007 doi GBVA2016013000014.pica (DE-627)ELV014163365 (ELSEVIER)S0378-7753(15)30506-1 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Wang, Xin verfasserin aut Preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Hydrogen peroxide Elsevier Palladium catalyst Elsevier Nanopore Elsevier Electroreduction Elsevier Nanowire arrays Elsevier Ye, Ke oth Gao, Yinyi oth Zhang, Hongyu oth Cheng, Kui oth Xiao, Xue oth Wang, Guiling oth Cao, Dianxue oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:303 year:2016 day:30 month:01 pages:278-286 extent:9 https://doi.org/10.1016/j.jpowsour.2015.11.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 303 2016 30 0130 278-286 9 045F 620 |
allfieldsSound |
10.1016/j.jpowsour.2015.11.007 doi GBVA2016013000014.pica (DE-627)ELV014163365 (ELSEVIER)S0378-7753(15)30506-1 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Wang, Xin verfasserin aut Preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. Hydrogen peroxide Elsevier Palladium catalyst Elsevier Nanopore Elsevier Electroreduction Elsevier Nanowire arrays Elsevier Ye, Ke oth Gao, Yinyi oth Zhang, Hongyu oth Cheng, Kui oth Xiao, Xue oth Wang, Guiling oth Cao, Dianxue oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:303 year:2016 day:30 month:01 pages:278-286 extent:9 https://doi.org/10.1016/j.jpowsour.2015.11.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 303 2016 30 0130 278-286 9 045F 620 |
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English |
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Enthalten in Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method New York, NY [u.a.] volume:303 year:2016 day:30 month:01 pages:278-286 extent:9 |
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Enthalten in Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method New York, NY [u.a.] volume:303 year:2016 day:30 month:01 pages:278-286 extent:9 |
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Hydrogen peroxide Palladium catalyst Nanopore Electroreduction Nanowire arrays |
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Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method |
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Preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium |
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Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method |
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preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium |
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Preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium |
abstract |
Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. |
abstractGer |
Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. |
abstract_unstemmed |
Nanoporous palladium supported on the carbon coated titanium carbide (CTiC) nanowire arrays (Pd NP/C@TiC) are successfully prepared by a facile chemical vapor deposition of three-dimensional (3D) C@TiC substrate, followed by electrochemical codeposition of Pd–Ni and removal of Ni via dealloying. The structure and morphology of the obtained Pd NP/C@TiC electrodes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) are used to examine the catalytic performances of the electrodes for H2O2 electroreduction in H2SO4 solution. The Pd NP/C@TiC electrode exhibits a largely effective specific surface area owing to its open nanoporous structure allowing the full utilization of Pd surface active sites. At the potential of 0.2 V in 2.0 mol L−1 H2O2 and 2 mol L−1 H2SO4 solutions, the reduction current density reaches 3.47 A mg−1, which is significantly higher than the catalytic activity of H2O2 electroreduction achieved previously with precious metals as catalysts. |
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Preparation of porous palladium nanowire arrays and their catalytic performance for hydrogen peroxide electroreduction in acid medium |
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