A novel dopamine sensor based on Mo doped reduced graphene oxide/polyimide composite membrane
A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic act...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Jia, Lingpu [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016transfer abstract |
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| Schlagwörter: |
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| Umfang: |
8 |
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| Übergeordnetes Werk: |
Enthalten in: Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners - Jacobs, Jacquelyn A. ELSEVIER, 2017, JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics, Lausanne |
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| Übergeordnetes Werk: |
volume:685 ; year:2016 ; day:15 ; month:11 ; pages:167-174 ; extent:8 |
| Links: |
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| DOI / URN: |
10.1016/j.jallcom.2016.05.239 |
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ELV014288109 |
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| 245 | 1 | 0 | |a A novel dopamine sensor based on Mo doped reduced graphene oxide/polyimide composite membrane |
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| 520 | |a A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. | ||
| 520 | |a A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. | ||
| 650 | 7 | |a Dopamine |2 Elsevier | |
| 650 | 7 | |a Graphene oxide/polyimide |2 Elsevier | |
| 650 | 7 | |a MoO2 |2 Elsevier | |
| 650 | 7 | |a Selective detection |2 Elsevier | |
| 700 | 1 | |a Zhou, Yaxin |4 oth | |
| 700 | 1 | |a Jiang, Yimin |4 oth | |
| 700 | 1 | |a Zhang, Aihua |4 oth | |
| 700 | 1 | |a Li, Xin |4 oth | |
| 700 | 1 | |a Wang, Chunming |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Jacobs, Jacquelyn A. ELSEVIER |t Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners |d 2017 |d JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics |g Lausanne |w (DE-627)ELV001115774 |
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10.1016/j.jallcom.2016.05.239 doi GBVA2016015000016.pica (DE-627)ELV014288109 (ELSEVIER)S0925-8388(16)31588-2 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Jia, Lingpu verfasserin aut A novel dopamine sensor based on Mo doped reduced graphene oxide/polyimide composite membrane 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. Dopamine Elsevier Graphene oxide/polyimide Elsevier MoO2 Elsevier Selective detection Elsevier Zhou, Yaxin oth Jiang, Yimin oth Zhang, Aihua oth Li, Xin oth Wang, Chunming oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:685 year:2016 day:15 month:11 pages:167-174 extent:8 https://doi.org/10.1016/j.jallcom.2016.05.239 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 685 2016 15 1115 167-174 8 045F 670 |
| spelling |
10.1016/j.jallcom.2016.05.239 doi GBVA2016015000016.pica (DE-627)ELV014288109 (ELSEVIER)S0925-8388(16)31588-2 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Jia, Lingpu verfasserin aut A novel dopamine sensor based on Mo doped reduced graphene oxide/polyimide composite membrane 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. Dopamine Elsevier Graphene oxide/polyimide Elsevier MoO2 Elsevier Selective detection Elsevier Zhou, Yaxin oth Jiang, Yimin oth Zhang, Aihua oth Li, Xin oth Wang, Chunming oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:685 year:2016 day:15 month:11 pages:167-174 extent:8 https://doi.org/10.1016/j.jallcom.2016.05.239 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 685 2016 15 1115 167-174 8 045F 670 |
| allfields_unstemmed |
10.1016/j.jallcom.2016.05.239 doi GBVA2016015000016.pica (DE-627)ELV014288109 (ELSEVIER)S0925-8388(16)31588-2 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Jia, Lingpu verfasserin aut A novel dopamine sensor based on Mo doped reduced graphene oxide/polyimide composite membrane 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. Dopamine Elsevier Graphene oxide/polyimide Elsevier MoO2 Elsevier Selective detection Elsevier Zhou, Yaxin oth Jiang, Yimin oth Zhang, Aihua oth Li, Xin oth Wang, Chunming oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:685 year:2016 day:15 month:11 pages:167-174 extent:8 https://doi.org/10.1016/j.jallcom.2016.05.239 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 685 2016 15 1115 167-174 8 045F 670 |
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10.1016/j.jallcom.2016.05.239 doi GBVA2016015000016.pica (DE-627)ELV014288109 (ELSEVIER)S0925-8388(16)31588-2 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Jia, Lingpu verfasserin aut A novel dopamine sensor based on Mo doped reduced graphene oxide/polyimide composite membrane 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. Dopamine Elsevier Graphene oxide/polyimide Elsevier MoO2 Elsevier Selective detection Elsevier Zhou, Yaxin oth Jiang, Yimin oth Zhang, Aihua oth Li, Xin oth Wang, Chunming oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:685 year:2016 day:15 month:11 pages:167-174 extent:8 https://doi.org/10.1016/j.jallcom.2016.05.239 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 685 2016 15 1115 167-174 8 045F 670 |
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10.1016/j.jallcom.2016.05.239 doi GBVA2016015000016.pica (DE-627)ELV014288109 (ELSEVIER)S0925-8388(16)31588-2 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Jia, Lingpu verfasserin aut A novel dopamine sensor based on Mo doped reduced graphene oxide/polyimide composite membrane 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. Dopamine Elsevier Graphene oxide/polyimide Elsevier MoO2 Elsevier Selective detection Elsevier Zhou, Yaxin oth Jiang, Yimin oth Zhang, Aihua oth Li, Xin oth Wang, Chunming oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:685 year:2016 day:15 month:11 pages:167-174 extent:8 https://doi.org/10.1016/j.jallcom.2016.05.239 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 685 2016 15 1115 167-174 8 045F 670 |
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Enthalten in Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners Lausanne volume:685 year:2016 day:15 month:11 pages:167-174 extent:8 |
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Enthalten in Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners Lausanne volume:685 year:2016 day:15 month:11 pages:167-174 extent:8 |
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Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners |
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In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. 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A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. |
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A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. |
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A novel Mo doped reduced graphene oxide/polyimide (Mo-rGO/PI) composite membrane sensor for dopamine (DA) has been successfully prepared by a simple and effective method. In this work, the rGO was doped into PI to prepare polymer composite membrane. Although rGO has a certain degree of catalytic activity for DA, more important is Mo doped rGO/PI film can enhance its electrocatalytic activity towards the oxidation of DA, and so far there is almost no report that MoO2 can catalyze DA. In order to find the best film, different doped ratios of Mo powder are further investigated, and the combined characterization by X-ray photoelectron spectra and energy-dispersive X-ray spectroscopy indicate that Mo exist in rGO/PI film in the form of MoO2. Under optimal conditions, the Mo doped rGO/PI film exhibits excellent catalytic activity to DA, with a linear response throughout the concentration range from 0.1 to 2000 μM, it also shows long-term stability and good reproducibility, and performs well for detection of DA in human blood serums and injection. These results suggest that the novel Mo-rGO/PI film is a promising candidate for the accurate and reliable detection of DA signals in biological samples. |
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