Sr3GdLi(PO4)3F:Eu2+, Mn2+: A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs
A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV)...
Ausführliche Beschreibung
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Lv, Yang [verfasserIn] |
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Englisch |
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2017transfer abstract |
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Übergeordnetes Werk: |
Enthalten in: Soil and water bioengineering: Practice and research needs for reconciling natural hazard control and ecological restoration - Rey, F. ELSEVIER, 2018, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:43 ; year:2017 ; number:12 ; day:15 ; month:08 ; pages:8824-8830 ; extent:7 |
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DOI / URN: |
10.1016/j.ceramint.2017.04.015 |
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ELV014997800 |
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520 | |a A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. | ||
520 | |a A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. | ||
650 | 7 | |a w-LEDs |2 Elsevier | |
650 | 7 | |a Luminescence |2 Elsevier | |
650 | 7 | |a Energy transfer |2 Elsevier | |
650 | 7 | |a Phosphor |2 Elsevier | |
700 | 1 | |a Jin, Yahong |4 oth | |
700 | 1 | |a Zhang, Shaoan |4 oth | |
700 | 1 | |a Wang, Chuanlong |4 oth | |
700 | 1 | |a Ju, Guifang |4 oth | |
700 | 1 | |a Xue, Feihong |4 oth | |
700 | 1 | |a He, Miao |4 oth | |
700 | 1 | |a Hu, Yihua |4 oth | |
773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Rey, F. ELSEVIER |t Soil and water bioengineering: Practice and research needs for reconciling natural hazard control and ecological restoration |d 2018 |g Amsterdam [u.a.] |w (DE-627)ELV000899798 |
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10.1016/j.ceramint.2017.04.015 doi GBV00000000000078A.pica (DE-627)ELV014997800 (ELSEVIER)S0272-8842(17)30604-1 DE-627 ger DE-627 rakwb eng 670 670 DE-600 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Lv, Yang verfasserin aut Sr3GdLi(PO4)3F:Eu2+, Mn2+: A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. w-LEDs Elsevier Luminescence Elsevier Energy transfer Elsevier Phosphor Elsevier Jin, Yahong oth Zhang, Shaoan oth Wang, Chuanlong oth Ju, Guifang oth Xue, Feihong oth He, Miao oth Hu, Yihua oth Enthalten in Elsevier Science Rey, F. ELSEVIER Soil and water bioengineering: Practice and research needs for reconciling natural hazard control and ecological restoration 2018 Amsterdam [u.a.] (DE-627)ELV000899798 volume:43 year:2017 number:12 day:15 month:08 pages:8824-8830 extent:7 https://doi.org/10.1016/j.ceramint.2017.04.015 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 43 2017 12 15 0815 8824-8830 7 045F 670 |
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10.1016/j.ceramint.2017.04.015 doi GBV00000000000078A.pica (DE-627)ELV014997800 (ELSEVIER)S0272-8842(17)30604-1 DE-627 ger DE-627 rakwb eng 670 670 DE-600 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Lv, Yang verfasserin aut Sr3GdLi(PO4)3F:Eu2+, Mn2+: A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. w-LEDs Elsevier Luminescence Elsevier Energy transfer Elsevier Phosphor Elsevier Jin, Yahong oth Zhang, Shaoan oth Wang, Chuanlong oth Ju, Guifang oth Xue, Feihong oth He, Miao oth Hu, Yihua oth Enthalten in Elsevier Science Rey, F. ELSEVIER Soil and water bioengineering: Practice and research needs for reconciling natural hazard control and ecological restoration 2018 Amsterdam [u.a.] (DE-627)ELV000899798 volume:43 year:2017 number:12 day:15 month:08 pages:8824-8830 extent:7 https://doi.org/10.1016/j.ceramint.2017.04.015 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 43 2017 12 15 0815 8824-8830 7 045F 670 |
allfields_unstemmed |
10.1016/j.ceramint.2017.04.015 doi GBV00000000000078A.pica (DE-627)ELV014997800 (ELSEVIER)S0272-8842(17)30604-1 DE-627 ger DE-627 rakwb eng 670 670 DE-600 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Lv, Yang verfasserin aut Sr3GdLi(PO4)3F:Eu2+, Mn2+: A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. w-LEDs Elsevier Luminescence Elsevier Energy transfer Elsevier Phosphor Elsevier Jin, Yahong oth Zhang, Shaoan oth Wang, Chuanlong oth Ju, Guifang oth Xue, Feihong oth He, Miao oth Hu, Yihua oth Enthalten in Elsevier Science Rey, F. ELSEVIER Soil and water bioengineering: Practice and research needs for reconciling natural hazard control and ecological restoration 2018 Amsterdam [u.a.] (DE-627)ELV000899798 volume:43 year:2017 number:12 day:15 month:08 pages:8824-8830 extent:7 https://doi.org/10.1016/j.ceramint.2017.04.015 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 43 2017 12 15 0815 8824-8830 7 045F 670 |
allfieldsGer |
10.1016/j.ceramint.2017.04.015 doi GBV00000000000078A.pica (DE-627)ELV014997800 (ELSEVIER)S0272-8842(17)30604-1 DE-627 ger DE-627 rakwb eng 670 670 DE-600 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Lv, Yang verfasserin aut Sr3GdLi(PO4)3F:Eu2+, Mn2+: A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. w-LEDs Elsevier Luminescence Elsevier Energy transfer Elsevier Phosphor Elsevier Jin, Yahong oth Zhang, Shaoan oth Wang, Chuanlong oth Ju, Guifang oth Xue, Feihong oth He, Miao oth Hu, Yihua oth Enthalten in Elsevier Science Rey, F. ELSEVIER Soil and water bioengineering: Practice and research needs for reconciling natural hazard control and ecological restoration 2018 Amsterdam [u.a.] (DE-627)ELV000899798 volume:43 year:2017 number:12 day:15 month:08 pages:8824-8830 extent:7 https://doi.org/10.1016/j.ceramint.2017.04.015 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 43 2017 12 15 0815 8824-8830 7 045F 670 |
allfieldsSound |
10.1016/j.ceramint.2017.04.015 doi GBV00000000000078A.pica (DE-627)ELV014997800 (ELSEVIER)S0272-8842(17)30604-1 DE-627 ger DE-627 rakwb eng 670 670 DE-600 333.7 610 VZ 43.12 bkl 43.13 bkl 44.13 bkl Lv, Yang verfasserin aut Sr3GdLi(PO4)3F:Eu2+, Mn2+: A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. w-LEDs Elsevier Luminescence Elsevier Energy transfer Elsevier Phosphor Elsevier Jin, Yahong oth Zhang, Shaoan oth Wang, Chuanlong oth Ju, Guifang oth Xue, Feihong oth He, Miao oth Hu, Yihua oth Enthalten in Elsevier Science Rey, F. ELSEVIER Soil and water bioengineering: Practice and research needs for reconciling natural hazard control and ecological restoration 2018 Amsterdam [u.a.] (DE-627)ELV000899798 volume:43 year:2017 number:12 day:15 month:08 pages:8824-8830 extent:7 https://doi.org/10.1016/j.ceramint.2017.04.015 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO 43.12 Umweltchemie VZ 43.13 Umwelttoxikologie VZ 44.13 Medizinische Ökologie VZ AR 43 2017 12 15 0815 8824-8830 7 045F 670 |
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Sr3GdLi(PO4)3F:Eu2+, Mn2+: A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs |
abstract |
A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. |
abstractGer |
A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. |
abstract_unstemmed |
A series of Eu2+ and Mn2+ co-doping Sr3GdLi(PO4)3F phosphors have been synthesized through high temperature solid state reaction. Eu2+ single doped Sr3GdLi(PO4)3F phosphors have an efficient excitation in the range of 230–430nm, which is in good agreement with the commercial near-ultraviolet (n-UV) LED chips, and gives intense blue emission centering at 445nm. The critical distance of the Eu2+ ions in Sr3GdLi(PO4)3F is computed and demonstrated that the concentration quenching mechanism of Eu2+ is mostly caused by the dipole-dipole interaction. By co-doping Eu2+ and Mn2+ ions in the Sr3GdLi(PO4)3F host, the energy transfer from Eu2+ to Mn2+ that can be discovered. With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. This study infers that the obtained Sr3GdLi(PO4)3F:Eu2+, Mn2+ phosphors may be a potential candidate for n-UV LEDs. |
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Sr3GdLi(PO4)3F:Eu2+, Mn2+: A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs |
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With the increase of Mn2+ content, emission color can be adjusted from blue to white under excitation of 380nm, corresponding to chromatic coordinates change from (0.189, 0.108) to (0.319, 0.277). The energy transfer from Eu2+ to Mn2+ ions is proven to be a dipole-dipole mechanism on the basis of the experimental results and analysis of photoluminescence spectra and decay curves. 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