Modelling of hydrogen induced pressurization of internal cavities
Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses t...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Sezgin, Jean-Gabriel [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017transfer abstract |
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| Schlagwörter: |
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| Umfang: |
12 |
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| Übergeordnetes Werk: |
Enthalten in: External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs - Dedhia, Kavita ELSEVIER, 2018, official journal of the International Association for Hydrogen Energy, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:42 ; year:2017 ; number:22 ; day:1 ; month:06 ; pages:15403-15414 ; extent:12 |
| Links: |
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| DOI / URN: |
10.1016/j.ijhydene.2017.04.106 |
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| 520 | |a Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. | ||
| 520 | |a Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. | ||
| 650 | 7 | |a Abel–Noble EOS |2 Elsevier | |
| 650 | 7 | |a Internal cavity |2 Elsevier | |
| 650 | 7 | |a Hydrogen diffusion and solubility |2 Elsevier | |
| 650 | 7 | |a Real gas equation of state |2 Elsevier | |
| 650 | 7 | |a 16MND5 steel |2 Elsevier | |
| 650 | 7 | |a Hydrogen fugacity |2 Elsevier | |
| 700 | 1 | |a Bosch, Cédric |4 oth | |
| 700 | 1 | |a Montouchet, Aurore |4 oth | |
| 700 | 1 | |a Perrin, Gilles |4 oth | |
| 700 | 1 | |a Wolski, Krzysztof |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Dedhia, Kavita ELSEVIER |t External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs |d 2018 |d official journal of the International Association for Hydrogen Energy |g New York, NY [u.a.] |w (DE-627)ELV000127019 |
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10.1016/j.ijhydene.2017.04.106 doi GBV00000000000770.pica (DE-627)ELV01507997X (ELSEVIER)S0360-3199(17)31495-7 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Sezgin, Jean-Gabriel verfasserin aut Modelling of hydrogen induced pressurization of internal cavities 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Abel–Noble EOS Elsevier Internal cavity Elsevier Hydrogen diffusion and solubility Elsevier Real gas equation of state Elsevier 16MND5 steel Elsevier Hydrogen fugacity Elsevier Bosch, Cédric oth Montouchet, Aurore oth Perrin, Gilles oth Wolski, Krzysztof oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:42 year:2017 number:22 day:1 month:06 pages:15403-15414 extent:12 https://doi.org/10.1016/j.ijhydene.2017.04.106 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 42 2017 22 1 0601 15403-15414 12 |
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10.1016/j.ijhydene.2017.04.106 doi GBV00000000000770.pica (DE-627)ELV01507997X (ELSEVIER)S0360-3199(17)31495-7 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Sezgin, Jean-Gabriel verfasserin aut Modelling of hydrogen induced pressurization of internal cavities 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Abel–Noble EOS Elsevier Internal cavity Elsevier Hydrogen diffusion and solubility Elsevier Real gas equation of state Elsevier 16MND5 steel Elsevier Hydrogen fugacity Elsevier Bosch, Cédric oth Montouchet, Aurore oth Perrin, Gilles oth Wolski, Krzysztof oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:42 year:2017 number:22 day:1 month:06 pages:15403-15414 extent:12 https://doi.org/10.1016/j.ijhydene.2017.04.106 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 42 2017 22 1 0601 15403-15414 12 |
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10.1016/j.ijhydene.2017.04.106 doi GBV00000000000770.pica (DE-627)ELV01507997X (ELSEVIER)S0360-3199(17)31495-7 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Sezgin, Jean-Gabriel verfasserin aut Modelling of hydrogen induced pressurization of internal cavities 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Abel–Noble EOS Elsevier Internal cavity Elsevier Hydrogen diffusion and solubility Elsevier Real gas equation of state Elsevier 16MND5 steel Elsevier Hydrogen fugacity Elsevier Bosch, Cédric oth Montouchet, Aurore oth Perrin, Gilles oth Wolski, Krzysztof oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:42 year:2017 number:22 day:1 month:06 pages:15403-15414 extent:12 https://doi.org/10.1016/j.ijhydene.2017.04.106 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 42 2017 22 1 0601 15403-15414 12 |
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10.1016/j.ijhydene.2017.04.106 doi GBV00000000000770.pica (DE-627)ELV01507997X (ELSEVIER)S0360-3199(17)31495-7 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Sezgin, Jean-Gabriel verfasserin aut Modelling of hydrogen induced pressurization of internal cavities 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Abel–Noble EOS Elsevier Internal cavity Elsevier Hydrogen diffusion and solubility Elsevier Real gas equation of state Elsevier 16MND5 steel Elsevier Hydrogen fugacity Elsevier Bosch, Cédric oth Montouchet, Aurore oth Perrin, Gilles oth Wolski, Krzysztof oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:42 year:2017 number:22 day:1 month:06 pages:15403-15414 extent:12 https://doi.org/10.1016/j.ijhydene.2017.04.106 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 42 2017 22 1 0601 15403-15414 12 |
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10.1016/j.ijhydene.2017.04.106 doi GBV00000000000770.pica (DE-627)ELV01507997X (ELSEVIER)S0360-3199(17)31495-7 DE-627 ger DE-627 rakwb eng 610 VZ 44.94 bkl Sezgin, Jean-Gabriel verfasserin aut Modelling of hydrogen induced pressurization of internal cavities 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. Abel–Noble EOS Elsevier Internal cavity Elsevier Hydrogen diffusion and solubility Elsevier Real gas equation of state Elsevier 16MND5 steel Elsevier Hydrogen fugacity Elsevier Bosch, Cédric oth Montouchet, Aurore oth Perrin, Gilles oth Wolski, Krzysztof oth Enthalten in Elsevier Dedhia, Kavita ELSEVIER External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs 2018 official journal of the International Association for Hydrogen Energy New York, NY [u.a.] (DE-627)ELV000127019 volume:42 year:2017 number:22 day:1 month:06 pages:15403-15414 extent:12 https://doi.org/10.1016/j.ijhydene.2017.04.106 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 42 2017 22 1 0601 15403-15414 12 |
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English |
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Enthalten in External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs New York, NY [u.a.] volume:42 year:2017 number:22 day:1 month:06 pages:15403-15414 extent:12 |
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Enthalten in External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs New York, NY [u.a.] volume:42 year:2017 number:22 day:1 month:06 pages:15403-15414 extent:12 |
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External auditory canal: Inferior, posterior-inferior, and anterior canal wall overhangs |
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A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. 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modelling of hydrogen induced pressurization of internal cavities |
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Modelling of hydrogen induced pressurization of internal cavities |
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Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. |
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Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. |
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Internal cavities can constitute a crack initiation site especially if filled with hydrogen at high pressure. A new refined equation of state based on recent NIST database has been introduced in order to model the equilibrium pressure. It is based on a thermodynamic definition of fugacity and uses the NIST data relating hydrogen density and pressure to define a new fugacity pressure quadratic dependence. The resulting Equation Of State (EOS) is compared to the standard Abel–Noble EOS and it is shown that for a given fugacity, imposed by a Sievert's law, the corresponding pressure is significantly higher. This new refined EOS was introduced into a previously developed numerical model of hydrogen diffusion and desorption and applied to evaluate the kinetics of pressure build-up within a cavity and its equilibrium pressure. It has been shown that the kinetics of pressure build-up at room temperature, which reaches values close to equilibrium in some hundreds of hours, is compatible with the industrial quality control procedures. The calculated pressures are in the range 4500–8650 bars depending on hydrogen solubility, which differs between the matrix and the segregation bands, and tend to equilibrium values obtained from mass balance approach. |
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