ECTFE hybrid porous membrane with hierarchical micro/nano-structural surface for efficient oil/water separation
Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (D...
Ausführliche Beschreibung
Autor*in: |
Pan, Jian [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2017transfer abstract |
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Schlagwörter: |
Superhydrophobic-superoleophilic |
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Umfang: |
8 |
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Übergeordnetes Werk: |
Enthalten in: Steering charge kinetics in W - Yue, Xin-Zheng ELSEVIER, 2019, the official journal of the North American Membrane Society, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:524 ; year:2017 ; day:15 ; month:02 ; pages:623-630 ; extent:8 |
Links: |
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DOI / URN: |
10.1016/j.memsci.2016.11.012 |
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ELV015107892 |
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520 | |a Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. | ||
520 | |a Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. | ||
650 | 7 | |a Superhydrophobic-superoleophilic |2 Elsevier | |
650 | 7 | |a Thermally induced phase separation |2 Elsevier | |
650 | 7 | |a Micro/nano-structural surface |2 Elsevier | |
650 | 7 | |a Oil/water emulsion separation |2 Elsevier | |
650 | 7 | |a ECTFE |2 Elsevier | |
700 | 1 | |a Xiao, Changfa |4 oth | |
700 | 1 | |a Huang, Qinglin |4 oth | |
700 | 1 | |a Liu, Hailiang |4 oth | |
700 | 1 | |a Zhang, Tai |4 oth | |
773 | 0 | 8 | |i Enthalten in |n Elsevier |a Yue, Xin-Zheng ELSEVIER |t Steering charge kinetics in W |d 2019 |d the official journal of the North American Membrane Society |g New York, NY [u.a.] |w (DE-627)ELV002478420 |
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10.1016/j.memsci.2016.11.012 doi GBV00000000000053A.pica (DE-627)ELV015107892 (ELSEVIER)S0376-7388(16)30765-7 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Pan, Jian verfasserin aut ECTFE hybrid porous membrane with hierarchical micro/nano-structural surface for efficient oil/water separation 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic Elsevier Thermally induced phase separation Elsevier Micro/nano-structural surface Elsevier Oil/water emulsion separation Elsevier ECTFE Elsevier Xiao, Changfa oth Huang, Qinglin oth Liu, Hailiang oth Zhang, Tai oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:524 year:2017 day:15 month:02 pages:623-630 extent:8 https://doi.org/10.1016/j.memsci.2016.11.012 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 524 2017 15 0215 623-630 8 045F 570 |
spelling |
10.1016/j.memsci.2016.11.012 doi GBV00000000000053A.pica (DE-627)ELV015107892 (ELSEVIER)S0376-7388(16)30765-7 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Pan, Jian verfasserin aut ECTFE hybrid porous membrane with hierarchical micro/nano-structural surface for efficient oil/water separation 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic Elsevier Thermally induced phase separation Elsevier Micro/nano-structural surface Elsevier Oil/water emulsion separation Elsevier ECTFE Elsevier Xiao, Changfa oth Huang, Qinglin oth Liu, Hailiang oth Zhang, Tai oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:524 year:2017 day:15 month:02 pages:623-630 extent:8 https://doi.org/10.1016/j.memsci.2016.11.012 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 524 2017 15 0215 623-630 8 045F 570 |
allfields_unstemmed |
10.1016/j.memsci.2016.11.012 doi GBV00000000000053A.pica (DE-627)ELV015107892 (ELSEVIER)S0376-7388(16)30765-7 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Pan, Jian verfasserin aut ECTFE hybrid porous membrane with hierarchical micro/nano-structural surface for efficient oil/water separation 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic Elsevier Thermally induced phase separation Elsevier Micro/nano-structural surface Elsevier Oil/water emulsion separation Elsevier ECTFE Elsevier Xiao, Changfa oth Huang, Qinglin oth Liu, Hailiang oth Zhang, Tai oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:524 year:2017 day:15 month:02 pages:623-630 extent:8 https://doi.org/10.1016/j.memsci.2016.11.012 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 524 2017 15 0215 623-630 8 045F 570 |
allfieldsGer |
10.1016/j.memsci.2016.11.012 doi GBV00000000000053A.pica (DE-627)ELV015107892 (ELSEVIER)S0376-7388(16)30765-7 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Pan, Jian verfasserin aut ECTFE hybrid porous membrane with hierarchical micro/nano-structural surface for efficient oil/water separation 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic Elsevier Thermally induced phase separation Elsevier Micro/nano-structural surface Elsevier Oil/water emulsion separation Elsevier ECTFE Elsevier Xiao, Changfa oth Huang, Qinglin oth Liu, Hailiang oth Zhang, Tai oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:524 year:2017 day:15 month:02 pages:623-630 extent:8 https://doi.org/10.1016/j.memsci.2016.11.012 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 524 2017 15 0215 623-630 8 045F 570 |
allfieldsSound |
10.1016/j.memsci.2016.11.012 doi GBV00000000000053A.pica (DE-627)ELV015107892 (ELSEVIER)S0376-7388(16)30765-7 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Pan, Jian verfasserin aut ECTFE hybrid porous membrane with hierarchical micro/nano-structural surface for efficient oil/water separation 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. Superhydrophobic-superoleophilic Elsevier Thermally induced phase separation Elsevier Micro/nano-structural surface Elsevier Oil/water emulsion separation Elsevier ECTFE Elsevier Xiao, Changfa oth Huang, Qinglin oth Liu, Hailiang oth Zhang, Tai oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:524 year:2017 day:15 month:02 pages:623-630 extent:8 https://doi.org/10.1016/j.memsci.2016.11.012 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 524 2017 15 0215 623-630 8 045F 570 |
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Enthalten in Steering charge kinetics in W New York, NY [u.a.] volume:524 year:2017 day:15 month:02 pages:623-630 extent:8 |
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ddc 570 ddc 540 bkl 35.17 bkl 58.50 bkl 43.12 Elsevier Superhydrophobic-superoleophilic Elsevier Thermally induced phase separation Elsevier Micro/nano-structural surface Elsevier Oil/water emulsion separation Elsevier ECTFE |
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ECTFE hybrid porous membrane with hierarchical micro/nano-structural surface for efficient oil/water separation |
abstract |
Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. |
abstractGer |
Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. |
abstract_unstemmed |
Superhydrophobic-superoleophilic poly(ethylene chlorotrifluoroethylene) (ECTFE)-SiO2 hybrid porous membrane with hierarchical micro/nano-structural surface was successfully fabricated via thermally induced phase separation (TIPS) method using bis(2-ethylhexyl) adipate (DEHA) and diethyl phthalate (DEP) as binary diluent, hydrophobic SiO2 as the additive. The effect of SiO2 content on the morphology, pore size distribution, wettability and mechanical properties of prepared membrane was characterized by scanning electron microscope, automatic mercury porosimeter, contact angle goniometer and tensile testing instrument, respectively. The results showed that, the prepared hybrid membrane surface evolved into superoleophilic and superhydrophobic when the SiO2 content was 4wt%. The separation experiments for different kinds of surfactant-free and surfactant-stabilized water-in-oil emulsions indicated that prepared superhydrophobic-superoleophilic membrane had high oil/water separation efficiency. The antifouling performance of the membrane was also studied for reuse many times in various pH conditions. This study provided a novel material and a facile method to fabricate superhydrophobic-superoleophilic membrane. |
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title_short |
ECTFE hybrid porous membrane with hierarchical micro/nano-structural surface for efficient oil/water separation |
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https://doi.org/10.1016/j.memsci.2016.11.012 |
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