Iron fluoride microspheres by titanium dioxide surface modification as high capacity cathode of Li-ion batteries
The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning elect...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Rui [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017transfer abstract |
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| Schlagwörter: |
Spherical FeF3·0.33H2O particles |
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| Umfang: |
10 |
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| Übergeordnetes Werk: |
Enthalten in: Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners - Jacobs, Jacquelyn A. ELSEVIER, 2017, JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics, Lausanne |
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| Übergeordnetes Werk: |
volume:719 ; year:2017 ; day:30 ; month:09 ; pages:331-340 ; extent:10 |
| Links: |
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| DOI / URN: |
10.1016/j.jallcom.2017.05.185 |
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ELV015300765 |
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| 520 | |a The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. | ||
| 520 | |a The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. | ||
| 650 | 7 | |a Cycling stability |2 Elsevier | |
| 650 | 7 | |a Spherical FeF3·0.33H2O particles |2 Elsevier | |
| 650 | 7 | |a Modification of nanosized TiO2- coating |2 Elsevier | |
| 650 | 7 | |a Li-ion batteries |2 Elsevier | |
| 700 | 1 | |a Wang, Xianyou |4 oth | |
| 700 | 1 | |a Wei, Shuangying |4 oth | |
| 700 | 1 | |a Wang, Xuan |4 oth | |
| 700 | 1 | |a Liu, Min |4 oth | |
| 700 | 1 | |a Hu, Hai |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Jacobs, Jacquelyn A. ELSEVIER |t Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners |d 2017 |d JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics |g Lausanne |w (DE-627)ELV001115774 |
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10.1016/j.jallcom.2017.05.185 doi GBV00000000000097A.pica (DE-627)ELV015300765 (ELSEVIER)S0925-8388(17)31802-9 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Zhang, Rui verfasserin aut Iron fluoride microspheres by titanium dioxide surface modification as high capacity cathode of Li-ion batteries 2017transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. Cycling stability Elsevier Spherical FeF3·0.33H2O particles Elsevier Modification of nanosized TiO2- coating Elsevier Li-ion batteries Elsevier Wang, Xianyou oth Wei, Shuangying oth Wang, Xuan oth Liu, Min oth Hu, Hai oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:719 year:2017 day:30 month:09 pages:331-340 extent:10 https://doi.org/10.1016/j.jallcom.2017.05.185 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 719 2017 30 0930 331-340 10 045F 670 |
| spelling |
10.1016/j.jallcom.2017.05.185 doi GBV00000000000097A.pica (DE-627)ELV015300765 (ELSEVIER)S0925-8388(17)31802-9 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Zhang, Rui verfasserin aut Iron fluoride microspheres by titanium dioxide surface modification as high capacity cathode of Li-ion batteries 2017transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. Cycling stability Elsevier Spherical FeF3·0.33H2O particles Elsevier Modification of nanosized TiO2- coating Elsevier Li-ion batteries Elsevier Wang, Xianyou oth Wei, Shuangying oth Wang, Xuan oth Liu, Min oth Hu, Hai oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:719 year:2017 day:30 month:09 pages:331-340 extent:10 https://doi.org/10.1016/j.jallcom.2017.05.185 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 719 2017 30 0930 331-340 10 045F 670 |
| allfields_unstemmed |
10.1016/j.jallcom.2017.05.185 doi GBV00000000000097A.pica (DE-627)ELV015300765 (ELSEVIER)S0925-8388(17)31802-9 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Zhang, Rui verfasserin aut Iron fluoride microspheres by titanium dioxide surface modification as high capacity cathode of Li-ion batteries 2017transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. Cycling stability Elsevier Spherical FeF3·0.33H2O particles Elsevier Modification of nanosized TiO2- coating Elsevier Li-ion batteries Elsevier Wang, Xianyou oth Wei, Shuangying oth Wang, Xuan oth Liu, Min oth Hu, Hai oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:719 year:2017 day:30 month:09 pages:331-340 extent:10 https://doi.org/10.1016/j.jallcom.2017.05.185 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 719 2017 30 0930 331-340 10 045F 670 |
| allfieldsGer |
10.1016/j.jallcom.2017.05.185 doi GBV00000000000097A.pica (DE-627)ELV015300765 (ELSEVIER)S0925-8388(17)31802-9 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Zhang, Rui verfasserin aut Iron fluoride microspheres by titanium dioxide surface modification as high capacity cathode of Li-ion batteries 2017transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. Cycling stability Elsevier Spherical FeF3·0.33H2O particles Elsevier Modification of nanosized TiO2- coating Elsevier Li-ion batteries Elsevier Wang, Xianyou oth Wei, Shuangying oth Wang, Xuan oth Liu, Min oth Hu, Hai oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:719 year:2017 day:30 month:09 pages:331-340 extent:10 https://doi.org/10.1016/j.jallcom.2017.05.185 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 719 2017 30 0930 331-340 10 045F 670 |
| allfieldsSound |
10.1016/j.jallcom.2017.05.185 doi GBV00000000000097A.pica (DE-627)ELV015300765 (ELSEVIER)S0925-8388(17)31802-9 DE-627 ger DE-627 rakwb eng 670 540 670 DE-600 540 DE-600 630 VZ Zhang, Rui verfasserin aut Iron fluoride microspheres by titanium dioxide surface modification as high capacity cathode of Li-ion batteries 2017transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. Cycling stability Elsevier Spherical FeF3·0.33H2O particles Elsevier Modification of nanosized TiO2- coating Elsevier Li-ion batteries Elsevier Wang, Xianyou oth Wei, Shuangying oth Wang, Xuan oth Liu, Min oth Hu, Hai oth Enthalten in Elsevier Jacobs, Jacquelyn A. ELSEVIER Factors associated with canine resource guarding behaviour in the presence of people: A cross-sectional survey of dog owners 2017 JAL : an interdisciplinary journal of materials science and solid-state chemistry and physics Lausanne (DE-627)ELV001115774 volume:719 year:2017 day:30 month:09 pages:331-340 extent:10 https://doi.org/10.1016/j.jallcom.2017.05.185 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA AR 719 2017 30 0930 331-340 10 045F 670 |
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Iron fluoride microspheres by titanium dioxide surface modification as high capacity cathode of Li-ion batteries |
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The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. |
| abstractGer |
The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. |
| abstract_unstemmed |
The spherical FeF3·0.33H2O cathode material is successfully modified with a TiO2 coating via a simple solvothermal method. The effects of nanosized TiO2 coating on the morphology structure, and electrochemical performance of spherical FeF3·0.33H2O cathode material are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical test, respectively. The results demonstrate that FeF3·0.33H2O sample is spherical morphology with the average particle size of about 1.0 μm and good dispersity, as well as the nanosized TiO2 layer is uniformly coated on the surface of the FeF3·0.33H2O spheres. Besides, the nanosized TiO2-coated FeF3·0.33H2O sample exhibits a high initial discharge capacity of 654 mAh g−1 and the corresponding charge capacity of 522 mAh g−1 at 0.1 C between 1.5 V and 4.5 V. Especially, the nanosized TiO2-coated FeF3·0.33H2O sample still possesses good cycling stability of 264 mAh g−1 after 200 cycles at 0.2 C. Thus, the modification of spherical FeF3·0.33H2O with nanosized TiO2 layer will be a promising strategy for improving cycle life and structure stability, and promoting its wide application in high performance LIBs. |
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