Sulfadiazine/dimethylsulfadiazine transition metal complexes: Synthesis, crystal structures and magnetic properties
Four divalent transition metal complexes (Cu, Ni or Co) of sulfadiazine (Hsulf) or dimethylsulfadiazine (Hdmsulf) with polynuclear Cu2, Ni4, Co4 and two-dimensional structures were synthesized by controlling the different metal ions, ligands and solvents. Ferromagnetic interaction between the MeO−-b...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Shi, Wen-Bo [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Schlagwörter: |
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| Umfang: |
8 |
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| Übergeordnetes Werk: |
Enthalten in: Resilience resources in low-income Black, Latino, and White fathers - Wilson, Dawn K. ELSEVIER, 2021, the international journal for inorganic and organometallic chemistry, Amsterdam [u.a.] |
|---|---|
| Übergeordnetes Werk: |
volume:99 ; year:2015 ; day:15 ; month:10 ; pages:252-259 ; extent:8 |
| Links: |
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| DOI / URN: |
10.1016/j.poly.2015.08.028 |
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Four divalent transition metal complexes (Cu, Ni or Co) of sulfadiazine (Hsulf) or dimethylsulfadiazine (Hdmsulf) with polynuclear Cu2, Ni4, Co4 and two-dimensional structures were synthesized by controlling the different metal ions, ligands and solvents. Ferromagnetic interaction between the MeO−-bridged CoII ions was observed, while the pyrimidine bridges transmit antiferromagnetic coupling between CuII or NiII ions. |
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Four divalent transition metal complexes (Cu, Ni or Co) of sulfadiazine (Hsulf) or dimethylsulfadiazine (Hdmsulf) with polynuclear Cu2, Ni4, Co4 and two-dimensional structures were synthesized by controlling the different metal ions, ligands and solvents. Ferromagnetic interaction between the MeO−-bridged CoII ions was observed, while the pyrimidine bridges transmit antiferromagnetic coupling between CuII or NiII ions. |
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Four divalent transition metal complexes (Cu, Ni or Co) of sulfadiazine (Hsulf) or dimethylsulfadiazine (Hdmsulf) with polynuclear Cu2, Ni4, Co4 and two-dimensional structures were synthesized by controlling the different metal ions, ligands and solvents. Ferromagnetic interaction between the MeO−-bridged CoII ions was observed, while the pyrimidine bridges transmit antiferromagnetic coupling between CuII or NiII ions. |
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