Voltammetric resolution of catechol and hydroquinone at eosin Y film modified carbon paste electrode
A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The e...
Ausführliche Beschreibung
Autor*in: |
Ganesh, P.S. [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2016transfer abstract |
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Umfang: |
8 |
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Übergeordnetes Werk: |
Enthalten in: Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects - Moreno-Cabezali, Belen Maria ELSEVIER, 2020, an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:220 ; year:2016 ; pages:208-215 ; extent:8 |
Links: |
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DOI / URN: |
10.1016/j.molliq.2016.04.078 |
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ELV01911110X |
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520 | |a A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. | ||
520 | |a A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. | ||
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10.1016/j.molliq.2016.04.078 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000802.pica (DE-627)ELV01911110X (ELSEVIER)S0167-7322(16)30070-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Ganesh, P.S. verfasserin aut Voltammetric resolution of catechol and hydroquinone at eosin Y film modified carbon paste electrode 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. Swamy, B.E. Kumara oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:220 year:2016 pages:208-215 extent:8 https://doi.org/10.1016/j.molliq.2016.04.078 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 220 2016 208-215 8 |
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10.1016/j.molliq.2016.04.078 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000802.pica (DE-627)ELV01911110X (ELSEVIER)S0167-7322(16)30070-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Ganesh, P.S. verfasserin aut Voltammetric resolution of catechol and hydroquinone at eosin Y film modified carbon paste electrode 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. Swamy, B.E. Kumara oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:220 year:2016 pages:208-215 extent:8 https://doi.org/10.1016/j.molliq.2016.04.078 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 220 2016 208-215 8 |
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10.1016/j.molliq.2016.04.078 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000802.pica (DE-627)ELV01911110X (ELSEVIER)S0167-7322(16)30070-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Ganesh, P.S. verfasserin aut Voltammetric resolution of catechol and hydroquinone at eosin Y film modified carbon paste electrode 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. Swamy, B.E. Kumara oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:220 year:2016 pages:208-215 extent:8 https://doi.org/10.1016/j.molliq.2016.04.078 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 220 2016 208-215 8 |
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10.1016/j.molliq.2016.04.078 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000802.pica (DE-627)ELV01911110X (ELSEVIER)S0167-7322(16)30070-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Ganesh, P.S. verfasserin aut Voltammetric resolution of catechol and hydroquinone at eosin Y film modified carbon paste electrode 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. Swamy, B.E. Kumara oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:220 year:2016 pages:208-215 extent:8 https://doi.org/10.1016/j.molliq.2016.04.078 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 220 2016 208-215 8 |
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10.1016/j.molliq.2016.04.078 doi /cbs_pica/cbs_olc/import_discovery/elsevier/einzuspielen/GBV00000000000802.pica (DE-627)ELV01911110X (ELSEVIER)S0167-7322(16)30070-8 DE-627 ger DE-627 rakwb eng 004 VZ 85.35 bkl 54.80 bkl Ganesh, P.S. verfasserin aut Voltammetric resolution of catechol and hydroquinone at eosin Y film modified carbon paste electrode 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. Swamy, B.E. Kumara oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:220 year:2016 pages:208-215 extent:8 https://doi.org/10.1016/j.molliq.2016.04.078 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 220 2016 208-215 8 |
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voltammetric resolution of catechol and hydroquinone at eosin y film modified carbon paste electrode |
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Voltammetric resolution of catechol and hydroquinone at eosin Y film modified carbon paste electrode |
abstract |
A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. |
abstractGer |
A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. |
abstract_unstemmed |
A sensitive, selective and reproducible electrochemical method was developed for the electroanalysis of catechol (CC) and hydroquinone (HQ) using eosin Y film modified carbon paste electrode (eosin Y/CPE). The modified electrode lowers the over potential and favours the oxidation of CC and HQ. The effect of scan rate and concentration studies reveals that the electrode process is controlled by the adsorption of an analytes. The simultaneous separation of CC and HQ was achieved in a binary mixture by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. The separation of the oxidation peak potentials for CC–HQ was about 0.114V and 0.118V by CV and DPV techniques respectively. This peak differences were large enough to determine CC and HQ individually or simultaneously. The lower limit of detection of CC was 0.27μM and 0.79μM for HQ. The eosin Y/CPE was achieved the voltammetric separation of the dihydroxy benzene isomers in a binary mixture by CV technique; this work provides a simple and easy approach for the modification of the bare carbon paste electrode. |
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Voltammetric resolution of catechol and hydroquinone at eosin Y film modified carbon paste electrode |
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