Preparation and characterization of cBN-based composites from cBN-Ti3AlC2 mixtures
Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then forme...
Ausführliche Beschreibung
Autor*in: |
Yang, Limin [verfasserIn] |
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Englisch |
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2016transfer abstract |
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Enthalten in: Sodium atom beam collisions with the liquid glycerol surface: Mass effects of deuteration - Wiens, Justin P. ELSEVIER, 2019, advancing the science and technology of diamond, diamond-like carbon, silicon carbides and Group 3 nitride materials, Amsterdam [u.a.] |
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volume:66 ; year:2016 ; pages:183-187 ; extent:5 |
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DOI / URN: |
10.1016/j.diamond.2016.05.003 |
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ELV019567901 |
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520 | |a Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. | ||
520 | |a Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. | ||
700 | 1 | |a Gong, Jianhong |4 oth | |
700 | 1 | |a Yue, Zhenming |4 oth | |
700 | 1 | |a Chu, Xingrong |4 oth | |
773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Wiens, Justin P. ELSEVIER |t Sodium atom beam collisions with the liquid glycerol surface: Mass effects of deuteration |d 2019 |d advancing the science and technology of diamond, diamond-like carbon, silicon carbides and Group 3 nitride materials |g Amsterdam [u.a.] |w (DE-627)ELV002660938 |
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10.1016/j.diamond.2016.05.003 doi GBV00000000000157A.pica (DE-627)ELV019567901 (ELSEVIER)S0925-9635(16)30124-8 DE-627 ger DE-627 rakwb eng 550 670 550 DE-600 670 DE-600 540 VZ 35.10 bkl Yang, Limin verfasserin aut Preparation and characterization of cBN-based composites from cBN-Ti3AlC2 mixtures 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Gong, Jianhong oth Yue, Zhenming oth Chu, Xingrong oth Enthalten in Elsevier Science Wiens, Justin P. ELSEVIER Sodium atom beam collisions with the liquid glycerol surface: Mass effects of deuteration 2019 advancing the science and technology of diamond, diamond-like carbon, silicon carbides and Group 3 nitride materials Amsterdam [u.a.] (DE-627)ELV002660938 volume:66 year:2016 pages:183-187 extent:5 https://doi.org/10.1016/j.diamond.2016.05.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 66 2016 183-187 5 045F 550 |
spelling |
10.1016/j.diamond.2016.05.003 doi GBV00000000000157A.pica (DE-627)ELV019567901 (ELSEVIER)S0925-9635(16)30124-8 DE-627 ger DE-627 rakwb eng 550 670 550 DE-600 670 DE-600 540 VZ 35.10 bkl Yang, Limin verfasserin aut Preparation and characterization of cBN-based composites from cBN-Ti3AlC2 mixtures 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Gong, Jianhong oth Yue, Zhenming oth Chu, Xingrong oth Enthalten in Elsevier Science Wiens, Justin P. ELSEVIER Sodium atom beam collisions with the liquid glycerol surface: Mass effects of deuteration 2019 advancing the science and technology of diamond, diamond-like carbon, silicon carbides and Group 3 nitride materials Amsterdam [u.a.] (DE-627)ELV002660938 volume:66 year:2016 pages:183-187 extent:5 https://doi.org/10.1016/j.diamond.2016.05.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 66 2016 183-187 5 045F 550 |
allfields_unstemmed |
10.1016/j.diamond.2016.05.003 doi GBV00000000000157A.pica (DE-627)ELV019567901 (ELSEVIER)S0925-9635(16)30124-8 DE-627 ger DE-627 rakwb eng 550 670 550 DE-600 670 DE-600 540 VZ 35.10 bkl Yang, Limin verfasserin aut Preparation and characterization of cBN-based composites from cBN-Ti3AlC2 mixtures 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Gong, Jianhong oth Yue, Zhenming oth Chu, Xingrong oth Enthalten in Elsevier Science Wiens, Justin P. ELSEVIER Sodium atom beam collisions with the liquid glycerol surface: Mass effects of deuteration 2019 advancing the science and technology of diamond, diamond-like carbon, silicon carbides and Group 3 nitride materials Amsterdam [u.a.] (DE-627)ELV002660938 volume:66 year:2016 pages:183-187 extent:5 https://doi.org/10.1016/j.diamond.2016.05.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 66 2016 183-187 5 045F 550 |
allfieldsGer |
10.1016/j.diamond.2016.05.003 doi GBV00000000000157A.pica (DE-627)ELV019567901 (ELSEVIER)S0925-9635(16)30124-8 DE-627 ger DE-627 rakwb eng 550 670 550 DE-600 670 DE-600 540 VZ 35.10 bkl Yang, Limin verfasserin aut Preparation and characterization of cBN-based composites from cBN-Ti3AlC2 mixtures 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Gong, Jianhong oth Yue, Zhenming oth Chu, Xingrong oth Enthalten in Elsevier Science Wiens, Justin P. ELSEVIER Sodium atom beam collisions with the liquid glycerol surface: Mass effects of deuteration 2019 advancing the science and technology of diamond, diamond-like carbon, silicon carbides and Group 3 nitride materials Amsterdam [u.a.] (DE-627)ELV002660938 volume:66 year:2016 pages:183-187 extent:5 https://doi.org/10.1016/j.diamond.2016.05.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 66 2016 183-187 5 045F 550 |
allfieldsSound |
10.1016/j.diamond.2016.05.003 doi GBV00000000000157A.pica (DE-627)ELV019567901 (ELSEVIER)S0925-9635(16)30124-8 DE-627 ger DE-627 rakwb eng 550 670 550 DE-600 670 DE-600 540 VZ 35.10 bkl Yang, Limin verfasserin aut Preparation and characterization of cBN-based composites from cBN-Ti3AlC2 mixtures 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. Gong, Jianhong oth Yue, Zhenming oth Chu, Xingrong oth Enthalten in Elsevier Science Wiens, Justin P. ELSEVIER Sodium atom beam collisions with the liquid glycerol surface: Mass effects of deuteration 2019 advancing the science and technology of diamond, diamond-like carbon, silicon carbides and Group 3 nitride materials Amsterdam [u.a.] (DE-627)ELV002660938 volume:66 year:2016 pages:183-187 extent:5 https://doi.org/10.1016/j.diamond.2016.05.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.10 Physikalische Chemie: Allgemeines VZ AR 66 2016 183-187 5 045F 550 |
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Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gong, Jianhong</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yue, Zhenming</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chu, Xingrong</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="n">Elsevier Science</subfield><subfield code="a">Wiens, Justin P. 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preparation and characterization of cbn-based composites from cbn-ti3alc2 mixtures |
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Preparation and characterization of cBN-based composites from cBN-Ti3AlC2 mixtures |
abstract |
Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. |
abstractGer |
Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. |
abstract_unstemmed |
Cubic boron nitride (cBN)-based composites were prepared at ~5.5GPa and ~1350°C with different mass ratios of cBN-Ti3AlC2 mixtures as starting materials. Ti3AlC2 decomposed and reacted with cBN during high pressure and high temperature (HPHT) sintering. TiC, TiC0.7N0.3, TiB2, and AlN were then formed. The bending and compressive strengths of cBN-based composites first increased and then decreased when the Ti3AlC2 content increased from 5wt.% to 40wt.%; hardness was determined by both the compactness and binder content. cBN-based composites sintered with 20wt.% Ti3AlC2 possessed the highest bending strength (422.45MPa), compressive strength (3969.14MPa), and hardness (3381.58HV); they also had the most compact microstructure. The initial oxygenation temperature of the cBN-based composites sintered with 20wt.% Ti3AlC2 was about 850°C. After isothermal oxidation at 1200°C for 1200s, titanium and aluminum oxides formed on the surface with pores and cracks. The isothermal oxidation process of the cBN-based composites could be described by a parabolic law. |
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title_short |
Preparation and characterization of cBN-based composites from cBN-Ti3AlC2 mixtures |
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https://doi.org/10.1016/j.diamond.2016.05.003 |
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