Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell
Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the u...
Ausführliche Beschreibung
Autor*in: |
Peng, Zhe [verfasserIn] |
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Sprache: |
Englisch |
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2017transfer abstract |
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12 |
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Übergeordnetes Werk: |
Enthalten in: Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method - Xiao, Hong ELSEVIER, 2013, the international journal on the science and technology of electrochemical energy systems, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:356 ; year:2017 ; day:15 ; month:07 ; pages:200-211 ; extent:12 |
Links: |
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DOI / URN: |
10.1016/j.jpowsour.2017.04.095 |
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Katalog-ID: |
ELV020292155 |
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245 | 1 | 0 | |a Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell |
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520 | |a Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. | ||
520 | |a Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. | ||
650 | 7 | |a Water management |2 Elsevier | |
650 | 7 | |a Aquivion |2 Elsevier | |
650 | 7 | |a Hydration |2 Elsevier | |
650 | 7 | |a Operando Raman spectroscopy |2 Elsevier | |
650 | 7 | |a Nafion |2 Elsevier | |
650 | 7 | |a Proton exchange membrane fuel cell |2 Elsevier | |
700 | 1 | |a Badets, Vasilica |4 oth | |
700 | 1 | |a Huguet, Patrice |4 oth | |
700 | 1 | |a Morin, Arnaud |4 oth | |
700 | 1 | |a Schott, Pascal |4 oth | |
700 | 1 | |a Tran, Thi Bich Hue |4 oth | |
700 | 1 | |a Porozhnyy, Mikhaël |4 oth | |
700 | 1 | |a Nikonenko, Victor |4 oth | |
700 | 1 | |a Deabate, Stefano |4 oth | |
773 | 0 | 8 | |i Enthalten in |n Elsevier |a Xiao, Hong ELSEVIER |t Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method |d 2013 |d the international journal on the science and technology of electrochemical energy systems |g New York, NY [u.a.] |w (DE-627)ELV00098745X |
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10.1016/j.jpowsour.2017.04.095 doi GBV00000000000223A.pica (DE-627)ELV020292155 (ELSEVIER)S0378-7753(17)30599-2 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Peng, Zhe verfasserin aut Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Water management Elsevier Aquivion Elsevier Hydration Elsevier Operando Raman spectroscopy Elsevier Nafion Elsevier Proton exchange membrane fuel cell Elsevier Badets, Vasilica oth Huguet, Patrice oth Morin, Arnaud oth Schott, Pascal oth Tran, Thi Bich Hue oth Porozhnyy, Mikhaël oth Nikonenko, Victor oth Deabate, Stefano oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:356 year:2017 day:15 month:07 pages:200-211 extent:12 https://doi.org/10.1016/j.jpowsour.2017.04.095 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 356 2017 15 0715 200-211 12 045F 620 |
spelling |
10.1016/j.jpowsour.2017.04.095 doi GBV00000000000223A.pica (DE-627)ELV020292155 (ELSEVIER)S0378-7753(17)30599-2 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Peng, Zhe verfasserin aut Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Water management Elsevier Aquivion Elsevier Hydration Elsevier Operando Raman spectroscopy Elsevier Nafion Elsevier Proton exchange membrane fuel cell Elsevier Badets, Vasilica oth Huguet, Patrice oth Morin, Arnaud oth Schott, Pascal oth Tran, Thi Bich Hue oth Porozhnyy, Mikhaël oth Nikonenko, Victor oth Deabate, Stefano oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:356 year:2017 day:15 month:07 pages:200-211 extent:12 https://doi.org/10.1016/j.jpowsour.2017.04.095 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 356 2017 15 0715 200-211 12 045F 620 |
allfields_unstemmed |
10.1016/j.jpowsour.2017.04.095 doi GBV00000000000223A.pica (DE-627)ELV020292155 (ELSEVIER)S0378-7753(17)30599-2 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Peng, Zhe verfasserin aut Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Water management Elsevier Aquivion Elsevier Hydration Elsevier Operando Raman spectroscopy Elsevier Nafion Elsevier Proton exchange membrane fuel cell Elsevier Badets, Vasilica oth Huguet, Patrice oth Morin, Arnaud oth Schott, Pascal oth Tran, Thi Bich Hue oth Porozhnyy, Mikhaël oth Nikonenko, Victor oth Deabate, Stefano oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:356 year:2017 day:15 month:07 pages:200-211 extent:12 https://doi.org/10.1016/j.jpowsour.2017.04.095 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 356 2017 15 0715 200-211 12 045F 620 |
allfieldsGer |
10.1016/j.jpowsour.2017.04.095 doi GBV00000000000223A.pica (DE-627)ELV020292155 (ELSEVIER)S0378-7753(17)30599-2 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Peng, Zhe verfasserin aut Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Water management Elsevier Aquivion Elsevier Hydration Elsevier Operando Raman spectroscopy Elsevier Nafion Elsevier Proton exchange membrane fuel cell Elsevier Badets, Vasilica oth Huguet, Patrice oth Morin, Arnaud oth Schott, Pascal oth Tran, Thi Bich Hue oth Porozhnyy, Mikhaël oth Nikonenko, Victor oth Deabate, Stefano oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:356 year:2017 day:15 month:07 pages:200-211 extent:12 https://doi.org/10.1016/j.jpowsour.2017.04.095 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 356 2017 15 0715 200-211 12 045F 620 |
allfieldsSound |
10.1016/j.jpowsour.2017.04.095 doi GBV00000000000223A.pica (DE-627)ELV020292155 (ELSEVIER)S0378-7753(17)30599-2 DE-627 ger DE-627 rakwb eng 620 620 DE-600 690 VZ 50.92 bkl Peng, Zhe verfasserin aut Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. Water management Elsevier Aquivion Elsevier Hydration Elsevier Operando Raman spectroscopy Elsevier Nafion Elsevier Proton exchange membrane fuel cell Elsevier Badets, Vasilica oth Huguet, Patrice oth Morin, Arnaud oth Schott, Pascal oth Tran, Thi Bich Hue oth Porozhnyy, Mikhaël oth Nikonenko, Victor oth Deabate, Stefano oth Enthalten in Elsevier Xiao, Hong ELSEVIER Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method 2013 the international journal on the science and technology of electrochemical energy systems New York, NY [u.a.] (DE-627)ELV00098745X volume:356 year:2017 day:15 month:07 pages:200-211 extent:12 https://doi.org/10.1016/j.jpowsour.2017.04.095 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.92 Meerestechnik VZ AR 356 2017 15 0715 200-211 12 045F 620 |
language |
English |
source |
Enthalten in Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method New York, NY [u.a.] volume:356 year:2017 day:15 month:07 pages:200-211 extent:12 |
sourceStr |
Enthalten in Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method New York, NY [u.a.] volume:356 year:2017 day:15 month:07 pages:200-211 extent:12 |
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Water management Aquivion Hydration Operando Raman spectroscopy Nafion Proton exchange membrane fuel cell |
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Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method |
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Peng, Zhe @@aut@@ Badets, Vasilica @@oth@@ Huguet, Patrice @@oth@@ Morin, Arnaud @@oth@@ Schott, Pascal @@oth@@ Tran, Thi Bich Hue @@oth@@ Porozhnyy, Mikhaël @@oth@@ Nikonenko, Victor @@oth@@ Deabate, Stefano @@oth@@ |
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Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method |
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Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell |
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Numerical modeling of wave–current forces acting on horizontal cylinder of marine structures by VOF method |
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operando μ-raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell |
title_auth |
Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell |
abstract |
Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. |
abstractGer |
Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. |
abstract_unstemmed |
Operando μ-Raman spectroscopy is used to probe the water distribution across Nafion® and Aquivion™ membranes in the operating fuel cell. The through-plane water concentration profile is obtained with μm resolution at the middle of the active surface, both at the gas distribution channel and at the under-lands areas. Depth-resolved measurements carried out at room temperature show that the water content of both membranes increases with the increase of the feed gas relative humidity and decreases with the increase of stoichiometry. At given relative humidity and stoichiometry conditions, the water content first increases at the fuel cell start-up and, then, decreases progressively with the increase of the current density delivered by the cell. The water loss is due to the concomitant rise of pressure drops and of the cell inner temperature, the latter giving the larger contribution. Pressure drops are related to the increase of the feed gases fluxes while temperature rise is due to increasing ohmic losses and heat from the electrochemical reaction. Compared to Nafion, Aquivion exhibits larger water content, but similar dehydration rate as a function of ohmic losses, and larger water accumulation at the under-lands area compared to channel. |
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Operando μ-Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell |
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Badets, Vasilica Huguet, Patrice Morin, Arnaud Schott, Pascal Tran, Thi Bich Hue Porozhnyy, Mikhaël Nikonenko, Victor Deabate, Stefano |
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Badets, Vasilica Huguet, Patrice Morin, Arnaud Schott, Pascal Tran, Thi Bich Hue Porozhnyy, Mikhaël Nikonenko, Victor Deabate, Stefano |
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