Experimental study on the pseudobinary H2O+NaAlSi3O8 at 600–800°C and 0.3–2.4GPa
The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder app...
Ausführliche Beschreibung
Autor*in: |
Schmidt, Christian [verfasserIn] |
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Sprache: |
Englisch |
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2014transfer abstract |
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Umfang: |
8 |
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Übergeordnetes Werk: |
Enthalten in: An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan - Miyata, Hugo Hissashi ELSEVIER, 2022, (including Isotope geoscience) : official journal of the European Association for Geochemistry, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:388 ; year:2014 ; day:21 ; month:11 ; pages:40-47 ; extent:8 |
Links: |
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DOI / URN: |
10.1016/j.chemgeo.2014.09.005 |
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ELV02301234X |
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520 | |a The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. | ||
520 | |a The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. | ||
700 | 1 | |a Wohlers, Anke |4 oth | |
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700 | 1 | |a Watenphul, Anke |4 oth | |
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10.1016/j.chemgeo.2014.09.005 doi GBVA2014020000007.pica (DE-627)ELV02301234X (ELSEVIER)S0009-2541(14)00422-7 DE-627 ger DE-627 rakwb eng 550 550 DE-600 004 VZ 85.35 bkl 54.80 bkl Schmidt, Christian verfasserin aut Experimental study on the pseudobinary H2O+NaAlSi3O8 at 600–800°C and 0.3–2.4GPa 2014transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. Wohlers, Anke oth Marquardt, Katharina oth Watenphul, Anke oth Enthalten in Elsevier Miyata, Hugo Hissashi ELSEVIER An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan 2022 (including Isotope geoscience) : official journal of the European Association for Geochemistry New York, NY [u.a.] (DE-627)ELV008354693 volume:388 year:2014 day:21 month:11 pages:40-47 extent:8 https://doi.org/10.1016/j.chemgeo.2014.09.005 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 388 2014 21 1121 40-47 8 045F 550 |
spelling |
10.1016/j.chemgeo.2014.09.005 doi GBVA2014020000007.pica (DE-627)ELV02301234X (ELSEVIER)S0009-2541(14)00422-7 DE-627 ger DE-627 rakwb eng 550 550 DE-600 004 VZ 85.35 bkl 54.80 bkl Schmidt, Christian verfasserin aut Experimental study on the pseudobinary H2O+NaAlSi3O8 at 600–800°C and 0.3–2.4GPa 2014transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. Wohlers, Anke oth Marquardt, Katharina oth Watenphul, Anke oth Enthalten in Elsevier Miyata, Hugo Hissashi ELSEVIER An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan 2022 (including Isotope geoscience) : official journal of the European Association for Geochemistry New York, NY [u.a.] (DE-627)ELV008354693 volume:388 year:2014 day:21 month:11 pages:40-47 extent:8 https://doi.org/10.1016/j.chemgeo.2014.09.005 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 388 2014 21 1121 40-47 8 045F 550 |
allfields_unstemmed |
10.1016/j.chemgeo.2014.09.005 doi GBVA2014020000007.pica (DE-627)ELV02301234X (ELSEVIER)S0009-2541(14)00422-7 DE-627 ger DE-627 rakwb eng 550 550 DE-600 004 VZ 85.35 bkl 54.80 bkl Schmidt, Christian verfasserin aut Experimental study on the pseudobinary H2O+NaAlSi3O8 at 600–800°C and 0.3–2.4GPa 2014transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. Wohlers, Anke oth Marquardt, Katharina oth Watenphul, Anke oth Enthalten in Elsevier Miyata, Hugo Hissashi ELSEVIER An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan 2022 (including Isotope geoscience) : official journal of the European Association for Geochemistry New York, NY [u.a.] (DE-627)ELV008354693 volume:388 year:2014 day:21 month:11 pages:40-47 extent:8 https://doi.org/10.1016/j.chemgeo.2014.09.005 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 388 2014 21 1121 40-47 8 045F 550 |
allfieldsGer |
10.1016/j.chemgeo.2014.09.005 doi GBVA2014020000007.pica (DE-627)ELV02301234X (ELSEVIER)S0009-2541(14)00422-7 DE-627 ger DE-627 rakwb eng 550 550 DE-600 004 VZ 85.35 bkl 54.80 bkl Schmidt, Christian verfasserin aut Experimental study on the pseudobinary H2O+NaAlSi3O8 at 600–800°C and 0.3–2.4GPa 2014transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. Wohlers, Anke oth Marquardt, Katharina oth Watenphul, Anke oth Enthalten in Elsevier Miyata, Hugo Hissashi ELSEVIER An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan 2022 (including Isotope geoscience) : official journal of the European Association for Geochemistry New York, NY [u.a.] (DE-627)ELV008354693 volume:388 year:2014 day:21 month:11 pages:40-47 extent:8 https://doi.org/10.1016/j.chemgeo.2014.09.005 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 388 2014 21 1121 40-47 8 045F 550 |
allfieldsSound |
10.1016/j.chemgeo.2014.09.005 doi GBVA2014020000007.pica (DE-627)ELV02301234X (ELSEVIER)S0009-2541(14)00422-7 DE-627 ger DE-627 rakwb eng 550 550 DE-600 004 VZ 85.35 bkl 54.80 bkl Schmidt, Christian verfasserin aut Experimental study on the pseudobinary H2O+NaAlSi3O8 at 600–800°C and 0.3–2.4GPa 2014transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. Wohlers, Anke oth Marquardt, Katharina oth Watenphul, Anke oth Enthalten in Elsevier Miyata, Hugo Hissashi ELSEVIER An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan 2022 (including Isotope geoscience) : official journal of the European Association for Geochemistry New York, NY [u.a.] (DE-627)ELV008354693 volume:388 year:2014 day:21 month:11 pages:40-47 extent:8 https://doi.org/10.1016/j.chemgeo.2014.09.005 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 388 2014 21 1121 40-47 8 045F 550 |
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English |
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Enthalten in An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan New York, NY [u.a.] volume:388 year:2014 day:21 month:11 pages:40-47 extent:8 |
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Enthalten in An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan New York, NY [u.a.] volume:388 year:2014 day:21 month:11 pages:40-47 extent:8 |
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An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan |
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Schmidt, Christian @@aut@@ Wohlers, Anke @@oth@@ Marquardt, Katharina @@oth@@ Watenphul, Anke @@oth@@ |
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We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. 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Experimental study on the pseudobinary H2O+NaAlSi3O8 at 600–800°C and 0.3–2.4GPa |
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An iterated greedy algorithm for distributed blocking flow shop with setup times and maintenance operations to minimize makespan |
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experimental study on the pseudobinary h2o+naalsi3o8 at 600–800°c and 0.3–2.4gpa |
title_auth |
Experimental study on the pseudobinary H2O+NaAlSi3O8 at 600–800°C and 0.3–2.4GPa |
abstract |
The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. |
abstractGer |
The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. |
abstract_unstemmed |
The pseudobinary H2O+NaAlSi3O8 was studied at compositions between 35 and 66 mass% NaAlSi3O8, at temperatures between 600 and 804°C, and at pressures ranging from 0.3 to 2.41GPa using a hydrothermal diamond-anvil cell (HDAC), cold-seal hydrothermal pressure vessels (CSPVs), and a piston-cylinder apparatus (PC). We propose a revised pseudosection for bulk compositions near 40 mass% NaAlSi3O8, the critical composition at 750°C obtained from the HDAC experiments. The corresponding critical pressure was 1.56GPa, as determined directly using zircon as Raman spectroscopic pressure sensor. Pressures at the melt-fluid homogenization temperature and along six isochoric P–T paths obtained from the Raman spectrum of zircon were close to or slightly lower than the pressure calculated from the EoS of H2O based on the vapor dissolution or ice melting temperature, which demonstrates that the effect of albite or NaAlSi3O8 melt dissolution is small. In an experiment up to 700°C and 2.28GPa, no clear evidence was found from optical observation for the hypothetical reappearance of melt-fluid immiscibility at higher pressure. |
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title_short |
Experimental study on the pseudobinary H2O+NaAlSi3O8 at 600–800°C and 0.3–2.4GPa |
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https://doi.org/10.1016/j.chemgeo.2014.09.005 |
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Wohlers, Anke Marquardt, Katharina Watenphul, Anke |
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