Glass-like dynamics of new cross-linked polymeric systems: Behavior of the Boson peak
Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter...
Ausführliche Beschreibung
Autor*in: |
Rossi, B. [verfasserIn] |
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Englisch |
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2014transfer abstract |
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5 |
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Enthalten in: Modeling and simulation of large-scale systems: A systematic comparison of modeling paradigms - Schweiger, G. ELSEVIER, 2019, a journal on the chemical, electronic, optical and mechanical properties of glasses, amorphous semiconductors and metals, sol-gel materials, the liquid state of these solids and the processes by which they are formed, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:401 ; year:2014 ; day:1 ; month:10 ; pages:73-77 ; extent:5 |
Links: |
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DOI / URN: |
10.1016/j.jnoncrysol.2014.01.016 |
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520 | |a Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. | ||
520 | |a Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. | ||
700 | 1 | |a Fontana, A. |4 oth | |
700 | 1 | |a Giarola, M. |4 oth | |
700 | 1 | |a Mariotto, G. |4 oth | |
700 | 1 | |a Mele, A. |4 oth | |
700 | 1 | |a Punta, C. |4 oth | |
700 | 1 | |a Melone, L. |4 oth | |
700 | 1 | |a Toraldo, F. |4 oth | |
700 | 1 | |a Trotta, F. |4 oth | |
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10.1016/j.jnoncrysol.2014.01.016 doi GBVA2014022000002.pica (DE-627)ELV023132817 (ELSEVIER)S0022-3093(14)00022-2 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 510 VZ 31.80 bkl 31.76 bkl Rossi, B. verfasserin aut Glass-like dynamics of new cross-linked polymeric systems: Behavior of the Boson peak 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Fontana, A. oth Giarola, M. oth Mariotto, G. oth Mele, A. oth Punta, C. oth Melone, L. oth Toraldo, F. oth Trotta, F. oth Enthalten in Elsevier Science Schweiger, G. ELSEVIER Modeling and simulation of large-scale systems: A systematic comparison of modeling paradigms 2019 a journal on the chemical, electronic, optical and mechanical properties of glasses, amorphous semiconductors and metals, sol-gel materials, the liquid state of these solids and the processes by which they are formed Amsterdam [u.a.] (DE-627)ELV002959275 volume:401 year:2014 day:1 month:10 pages:73-77 extent:5 https://doi.org/10.1016/j.jnoncrysol.2014.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-MAT 31.80 Angewandte Mathematik VZ 31.76 Numerische Mathematik VZ AR 401 2014 1 1001 73-77 5 045F 660 |
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10.1016/j.jnoncrysol.2014.01.016 doi GBVA2014022000002.pica (DE-627)ELV023132817 (ELSEVIER)S0022-3093(14)00022-2 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 510 VZ 31.80 bkl 31.76 bkl Rossi, B. verfasserin aut Glass-like dynamics of new cross-linked polymeric systems: Behavior of the Boson peak 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Fontana, A. oth Giarola, M. oth Mariotto, G. oth Mele, A. oth Punta, C. oth Melone, L. oth Toraldo, F. oth Trotta, F. oth Enthalten in Elsevier Science Schweiger, G. ELSEVIER Modeling and simulation of large-scale systems: A systematic comparison of modeling paradigms 2019 a journal on the chemical, electronic, optical and mechanical properties of glasses, amorphous semiconductors and metals, sol-gel materials, the liquid state of these solids and the processes by which they are formed Amsterdam [u.a.] (DE-627)ELV002959275 volume:401 year:2014 day:1 month:10 pages:73-77 extent:5 https://doi.org/10.1016/j.jnoncrysol.2014.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-MAT 31.80 Angewandte Mathematik VZ 31.76 Numerische Mathematik VZ AR 401 2014 1 1001 73-77 5 045F 660 |
allfields_unstemmed |
10.1016/j.jnoncrysol.2014.01.016 doi GBVA2014022000002.pica (DE-627)ELV023132817 (ELSEVIER)S0022-3093(14)00022-2 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 510 VZ 31.80 bkl 31.76 bkl Rossi, B. verfasserin aut Glass-like dynamics of new cross-linked polymeric systems: Behavior of the Boson peak 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Fontana, A. oth Giarola, M. oth Mariotto, G. oth Mele, A. oth Punta, C. oth Melone, L. oth Toraldo, F. oth Trotta, F. oth Enthalten in Elsevier Science Schweiger, G. ELSEVIER Modeling and simulation of large-scale systems: A systematic comparison of modeling paradigms 2019 a journal on the chemical, electronic, optical and mechanical properties of glasses, amorphous semiconductors and metals, sol-gel materials, the liquid state of these solids and the processes by which they are formed Amsterdam [u.a.] (DE-627)ELV002959275 volume:401 year:2014 day:1 month:10 pages:73-77 extent:5 https://doi.org/10.1016/j.jnoncrysol.2014.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-MAT 31.80 Angewandte Mathematik VZ 31.76 Numerische Mathematik VZ AR 401 2014 1 1001 73-77 5 045F 660 |
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10.1016/j.jnoncrysol.2014.01.016 doi GBVA2014022000002.pica (DE-627)ELV023132817 (ELSEVIER)S0022-3093(14)00022-2 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 510 VZ 31.80 bkl 31.76 bkl Rossi, B. verfasserin aut Glass-like dynamics of new cross-linked polymeric systems: Behavior of the Boson peak 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Fontana, A. oth Giarola, M. oth Mariotto, G. oth Mele, A. oth Punta, C. oth Melone, L. oth Toraldo, F. oth Trotta, F. oth Enthalten in Elsevier Science Schweiger, G. ELSEVIER Modeling and simulation of large-scale systems: A systematic comparison of modeling paradigms 2019 a journal on the chemical, electronic, optical and mechanical properties of glasses, amorphous semiconductors and metals, sol-gel materials, the liquid state of these solids and the processes by which they are formed Amsterdam [u.a.] (DE-627)ELV002959275 volume:401 year:2014 day:1 month:10 pages:73-77 extent:5 https://doi.org/10.1016/j.jnoncrysol.2014.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-MAT 31.80 Angewandte Mathematik VZ 31.76 Numerische Mathematik VZ AR 401 2014 1 1001 73-77 5 045F 660 |
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10.1016/j.jnoncrysol.2014.01.016 doi GBVA2014022000002.pica (DE-627)ELV023132817 (ELSEVIER)S0022-3093(14)00022-2 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 510 VZ 31.80 bkl 31.76 bkl Rossi, B. verfasserin aut Glass-like dynamics of new cross-linked polymeric systems: Behavior of the Boson peak 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. Fontana, A. oth Giarola, M. oth Mariotto, G. oth Mele, A. oth Punta, C. oth Melone, L. oth Toraldo, F. oth Trotta, F. oth Enthalten in Elsevier Science Schweiger, G. ELSEVIER Modeling and simulation of large-scale systems: A systematic comparison of modeling paradigms 2019 a journal on the chemical, electronic, optical and mechanical properties of glasses, amorphous semiconductors and metals, sol-gel materials, the liquid state of these solids and the processes by which they are formed Amsterdam [u.a.] (DE-627)ELV002959275 volume:401 year:2014 day:1 month:10 pages:73-77 extent:5 https://doi.org/10.1016/j.jnoncrysol.2014.01.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-MAT 31.80 Angewandte Mathematik VZ 31.76 Numerische Mathematik VZ AR 401 2014 1 1001 73-77 5 045F 660 |
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glass-like dynamics of new cross-linked polymeric systems: behavior of the boson peak |
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Glass-like dynamics of new cross-linked polymeric systems: Behavior of the Boson peak |
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Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. |
abstractGer |
Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. |
abstract_unstemmed |
Cyclodextrin nanosponges (CDNS) provide a very promising class of cross-linked polymers consisting of cyclodextrins as building blocks and showing a characteristic nanoporous structure capable of effectively encapsulating and carrying a variety of both lipophilic and hydrophilic compounds. Hereafter, we investigate the vibrational dynamics of CDNS in the low-wave number region, with the aim to provide physical descriptors correlated to the elastic properties of this innovative glass-forming material. By means of Raman scattering measurements, we explore the modifications occurring to the boson peak (BP) as a function of the cavity size of the cyclodextrin and the relative amount of the cross-linking agent with respect to the monomer cyclodextrin, which can be varied during the synthesis of the polymer. The shift and intensity variations of the BP are discussed in terms of the modification of the elastic properties of CDNS, and a master curve for the boson peak can therefore be obtained. The experimental approach adopted here is a useful tool for investigating the structural and physicochemical properties of novel nanoporous soft materials of interest for biolife applications. |
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Glass-like dynamics of new cross-linked polymeric systems: Behavior of the Boson peak |
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