Float zone growth and spectral properties of Cr,Nd:CaYAlO4 single crystals
Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same gr...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ueda, Aki [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014transfer abstract |
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| Schlagwörter: |
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| Umfang: |
5 |
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| Übergeordnetes Werk: |
Enthalten in: The mental health of doctor-shoppers: Experience from a patient-led fee-for-service primary care setting - 2011, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:404 ; year:2014 ; day:15 ; month:10 ; pages:152-156 ; extent:5 |
| Links: |
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| DOI / URN: |
10.1016/j.jcrysgro.2014.07.027 |
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| 245 | 1 | 0 | |a Float zone growth and spectral properties of Cr,Nd:CaYAlO4 single crystals |
| 264 | 1 | |c 2014transfer abstract | |
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| 520 | |a Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. | ||
| 520 | |a Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. | ||
| 650 | 7 | |a B3. Solid state lasers |2 Elsevier | |
| 650 | 7 | |a A2. Floating zone technique |2 Elsevier | |
| 650 | 7 | |a B1. Aluminates |2 Elsevier | |
| 650 | 7 | |a A1. Defects |2 Elsevier | |
| 700 | 1 | |a Higuchi, Mikio |4 oth | |
| 700 | 1 | |a Yamada, Daiki |4 oth | |
| 700 | 1 | |a Namiki, Sho |4 oth | |
| 700 | 1 | |a Ogawa, Takayo |4 oth | |
| 700 | 1 | |a Wada, Satoshi |4 oth | |
| 700 | 1 | |a Tadanaga, Kiyoharu |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |t The mental health of doctor-shoppers: Experience from a patient-led fee-for-service primary care setting |d 2011 |g Amsterdam [u.a.] |w (DE-627)ELV010662650 |
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10.1016/j.jcrysgro.2014.07.027 doi GBVA2014022000016.pica (DE-627)ELV02317160X (ELSEVIER)S0022-0248(14)00529-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 570 540 VZ Ueda, Aki verfasserin aut Float zone growth and spectral properties of Cr,Nd:CaYAlO4 single crystals 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. B3. Solid state lasers Elsevier A2. Floating zone technique Elsevier B1. Aluminates Elsevier A1. Defects Elsevier Higuchi, Mikio oth Yamada, Daiki oth Namiki, Sho oth Ogawa, Takayo oth Wada, Satoshi oth Tadanaga, Kiyoharu oth Enthalten in Elsevier The mental health of doctor-shoppers: Experience from a patient-led fee-for-service primary care setting 2011 Amsterdam [u.a.] (DE-627)ELV010662650 volume:404 year:2014 day:15 month:10 pages:152-156 extent:5 https://doi.org/10.1016/j.jcrysgro.2014.07.027 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_22 GBV_ILN_40 GBV_ILN_105 AR 404 2014 15 1015 152-156 5 045F 540 |
| spelling |
10.1016/j.jcrysgro.2014.07.027 doi GBVA2014022000016.pica (DE-627)ELV02317160X (ELSEVIER)S0022-0248(14)00529-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 570 540 VZ Ueda, Aki verfasserin aut Float zone growth and spectral properties of Cr,Nd:CaYAlO4 single crystals 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. B3. Solid state lasers Elsevier A2. Floating zone technique Elsevier B1. Aluminates Elsevier A1. Defects Elsevier Higuchi, Mikio oth Yamada, Daiki oth Namiki, Sho oth Ogawa, Takayo oth Wada, Satoshi oth Tadanaga, Kiyoharu oth Enthalten in Elsevier The mental health of doctor-shoppers: Experience from a patient-led fee-for-service primary care setting 2011 Amsterdam [u.a.] (DE-627)ELV010662650 volume:404 year:2014 day:15 month:10 pages:152-156 extent:5 https://doi.org/10.1016/j.jcrysgro.2014.07.027 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_22 GBV_ILN_40 GBV_ILN_105 AR 404 2014 15 1015 152-156 5 045F 540 |
| allfields_unstemmed |
10.1016/j.jcrysgro.2014.07.027 doi GBVA2014022000016.pica (DE-627)ELV02317160X (ELSEVIER)S0022-0248(14)00529-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 570 540 VZ Ueda, Aki verfasserin aut Float zone growth and spectral properties of Cr,Nd:CaYAlO4 single crystals 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. B3. Solid state lasers Elsevier A2. Floating zone technique Elsevier B1. Aluminates Elsevier A1. Defects Elsevier Higuchi, Mikio oth Yamada, Daiki oth Namiki, Sho oth Ogawa, Takayo oth Wada, Satoshi oth Tadanaga, Kiyoharu oth Enthalten in Elsevier The mental health of doctor-shoppers: Experience from a patient-led fee-for-service primary care setting 2011 Amsterdam [u.a.] (DE-627)ELV010662650 volume:404 year:2014 day:15 month:10 pages:152-156 extent:5 https://doi.org/10.1016/j.jcrysgro.2014.07.027 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_22 GBV_ILN_40 GBV_ILN_105 AR 404 2014 15 1015 152-156 5 045F 540 |
| allfieldsGer |
10.1016/j.jcrysgro.2014.07.027 doi GBVA2014022000016.pica (DE-627)ELV02317160X (ELSEVIER)S0022-0248(14)00529-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 570 540 VZ Ueda, Aki verfasserin aut Float zone growth and spectral properties of Cr,Nd:CaYAlO4 single crystals 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. B3. Solid state lasers Elsevier A2. Floating zone technique Elsevier B1. Aluminates Elsevier A1. Defects Elsevier Higuchi, Mikio oth Yamada, Daiki oth Namiki, Sho oth Ogawa, Takayo oth Wada, Satoshi oth Tadanaga, Kiyoharu oth Enthalten in Elsevier The mental health of doctor-shoppers: Experience from a patient-led fee-for-service primary care setting 2011 Amsterdam [u.a.] (DE-627)ELV010662650 volume:404 year:2014 day:15 month:10 pages:152-156 extent:5 https://doi.org/10.1016/j.jcrysgro.2014.07.027 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_22 GBV_ILN_40 GBV_ILN_105 AR 404 2014 15 1015 152-156 5 045F 540 |
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10.1016/j.jcrysgro.2014.07.027 doi GBVA2014022000016.pica (DE-627)ELV02317160X (ELSEVIER)S0022-0248(14)00529-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 570 540 VZ Ueda, Aki verfasserin aut Float zone growth and spectral properties of Cr,Nd:CaYAlO4 single crystals 2014transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. B3. Solid state lasers Elsevier A2. Floating zone technique Elsevier B1. Aluminates Elsevier A1. Defects Elsevier Higuchi, Mikio oth Yamada, Daiki oth Namiki, Sho oth Ogawa, Takayo oth Wada, Satoshi oth Tadanaga, Kiyoharu oth Enthalten in Elsevier The mental health of doctor-shoppers: Experience from a patient-led fee-for-service primary care setting 2011 Amsterdam [u.a.] (DE-627)ELV010662650 volume:404 year:2014 day:15 month:10 pages:152-156 extent:5 https://doi.org/10.1016/j.jcrysgro.2014.07.027 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_22 GBV_ILN_40 GBV_ILN_105 AR 404 2014 15 1015 152-156 5 045F 540 |
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Enthalten in The mental health of doctor-shoppers: Experience from a patient-led fee-for-service primary care setting Amsterdam [u.a.] volume:404 year:2014 day:15 month:10 pages:152-156 extent:5 |
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The mental health of doctor-shoppers: Experience from a patient-led fee-for-service primary care setting |
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Ueda, Aki @@aut@@ Higuchi, Mikio @@oth@@ Yamada, Daiki @@oth@@ Namiki, Sho @@oth@@ Ogawa, Takayo @@oth@@ Wada, Satoshi @@oth@@ Tadanaga, Kiyoharu @@oth@@ |
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float zone growth and spectral properties of cr,nd:cayalo4 single crystals |
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Float zone growth and spectral properties of Cr,Nd:CaYAlO4 single crystals |
| abstract |
Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. |
| abstractGer |
Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. |
| abstract_unstemmed |
Cr,Nd:CaYAlO4 single crystals were grown by the floating zone method and their spectroscopic properties were investigated. Many voids were observed in the crystals grown with a stoichiometric feed rod even at a relatively low growth rate of 2.5mm/h, while a void-free crystal was grown at the same growth rate using a feed rod the composition of which was Y-rich to Ca. These results indicate that voids were attributable to constitutional supercooling due to the segregation of main constituents caused by the difference in congruent and stoichiometric compositions. The as-grown crystals were deep red and showed strong absorption in the wavelength region of 320–600nm. The absorption cross section for σ-polarization at 430nm, where Cr,Nd:YAG has the maximum absorption, is about 1160×10−20 cm2, which is 165 times as large as that of Cr,Nd:YAG. By pumping at 400nm, which is a part of the absorption band of Cr3+, Cr,Nd:CaYAlO4 showed fluorescence bands around 900nm and 1080nm by Nd3+ indicating energy transfer from Cr3+ to Nd3+ in the crystal. Cr,Nd:CaYAlO4 single crystals are therefore one of the promising gain media for solar-pumped solid state laser systems. |
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