Electrochemical conversion of dinitrogen to ammonia induced by a metal complex–supported ionic liquid
Electrochemical synthesis of NH3 from dinitrogen and protons from water by using Cp2TiCl2 supported in a hydrophobic ionic liquid, 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate ([C9H20N]+[(C2F5)3PF3]−), was achieved in a solid polymer electrolyte (SPE) cell under ambient con...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Katayama, Akira [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Umfang: |
5 |
|---|
| Übergeordnetes Werk: |
Enthalten in: A multi-objective model to configure an electronic reverse logistics network and third party selection - Tosarkani, Babak Mohamadpour ELSEVIER, 2018, Amsterdam [u.a.] |
|---|---|
| Übergeordnetes Werk: |
volume:67 ; year:2016 ; pages:6-10 ; extent:5 |
| Links: |
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| DOI / URN: |
10.1016/j.elecom.2016.03.001 |
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Electrochemical conversion of dinitrogen to ammonia induced by a metal complex–supported ionic liquid |
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Electrochemical synthesis of NH3 from dinitrogen and protons from water by using Cp2TiCl2 supported in a hydrophobic ionic liquid, 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate ([C9H20N]+[(C2F5)3PF3]−), was achieved in a solid polymer electrolyte (SPE) cell under ambient conditions. The yield of NH3 per Cp2TiCl2 and current efficiency are 27% and 0.2%, respectively, which are improved in comparison with those reported previously. |
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Electrochemical synthesis of NH3 from dinitrogen and protons from water by using Cp2TiCl2 supported in a hydrophobic ionic liquid, 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate ([C9H20N]+[(C2F5)3PF3]−), was achieved in a solid polymer electrolyte (SPE) cell under ambient conditions. The yield of NH3 per Cp2TiCl2 and current efficiency are 27% and 0.2%, respectively, which are improved in comparison with those reported previously. |
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Electrochemical synthesis of NH3 from dinitrogen and protons from water by using Cp2TiCl2 supported in a hydrophobic ionic liquid, 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate ([C9H20N]+[(C2F5)3PF3]−), was achieved in a solid polymer electrolyte (SPE) cell under ambient conditions. The yield of NH3 per Cp2TiCl2 and current efficiency are 27% and 0.2%, respectively, which are improved in comparison with those reported previously. |
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