Interdiffusion and phase separation upon curing in thermoset-thermoplastic interphases unravelled by the characterization of partially cured systems
The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion p...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Voleppe, Quentin [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016transfer abstract |
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| Schlagwörter: |
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| Umfang: |
8 |
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| Übergeordnetes Werk: |
Enthalten in: Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study - Fitzgerald, Emily ELSEVIER, 2020, the international journal for the science and technology of polymers, Oxford |
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| Übergeordnetes Werk: |
volume:106 ; year:2016 ; day:5 ; month:12 ; pages:120-127 ; extent:8 |
| Links: |
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| DOI / URN: |
10.1016/j.polymer.2016.09.066 |
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| 520 | |a The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. | ||
| 520 | |a The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. | ||
| 650 | 7 | |a Thermoset/thermoplastic interphases |2 Elsevier | |
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10.1016/j.polymer.2016.09.066 doi GBVA2016023000001.pica (DE-627)ELV024909254 (ELSEVIER)S0032-3861(16)30865-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.63 bkl 44.69 bkl Voleppe, Quentin verfasserin aut Interdiffusion and phase separation upon curing in thermoset-thermoplastic interphases unravelled by the characterization of partially cured systems 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. Thermoset/thermoplastic interphases Elsevier Concentration profiles Elsevier Partial curing Elsevier Pardoen, Thomas oth Bailly, Christian oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:106 year:2016 day:5 month:12 pages:120-127 extent:8 https://doi.org/10.1016/j.polymer.2016.09.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 106 2016 5 1205 120-127 8 045F 540 |
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10.1016/j.polymer.2016.09.066 doi GBVA2016023000001.pica (DE-627)ELV024909254 (ELSEVIER)S0032-3861(16)30865-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.63 bkl 44.69 bkl Voleppe, Quentin verfasserin aut Interdiffusion and phase separation upon curing in thermoset-thermoplastic interphases unravelled by the characterization of partially cured systems 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. Thermoset/thermoplastic interphases Elsevier Concentration profiles Elsevier Partial curing Elsevier Pardoen, Thomas oth Bailly, Christian oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:106 year:2016 day:5 month:12 pages:120-127 extent:8 https://doi.org/10.1016/j.polymer.2016.09.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 106 2016 5 1205 120-127 8 045F 540 |
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10.1016/j.polymer.2016.09.066 doi GBVA2016023000001.pica (DE-627)ELV024909254 (ELSEVIER)S0032-3861(16)30865-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.63 bkl 44.69 bkl Voleppe, Quentin verfasserin aut Interdiffusion and phase separation upon curing in thermoset-thermoplastic interphases unravelled by the characterization of partially cured systems 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. Thermoset/thermoplastic interphases Elsevier Concentration profiles Elsevier Partial curing Elsevier Pardoen, Thomas oth Bailly, Christian oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:106 year:2016 day:5 month:12 pages:120-127 extent:8 https://doi.org/10.1016/j.polymer.2016.09.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 106 2016 5 1205 120-127 8 045F 540 |
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10.1016/j.polymer.2016.09.066 doi GBVA2016023000001.pica (DE-627)ELV024909254 (ELSEVIER)S0032-3861(16)30865-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.63 bkl 44.69 bkl Voleppe, Quentin verfasserin aut Interdiffusion and phase separation upon curing in thermoset-thermoplastic interphases unravelled by the characterization of partially cured systems 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. Thermoset/thermoplastic interphases Elsevier Concentration profiles Elsevier Partial curing Elsevier Pardoen, Thomas oth Bailly, Christian oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:106 year:2016 day:5 month:12 pages:120-127 extent:8 https://doi.org/10.1016/j.polymer.2016.09.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 106 2016 5 1205 120-127 8 045F 540 |
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10.1016/j.polymer.2016.09.066 doi GBVA2016023000001.pica (DE-627)ELV024909254 (ELSEVIER)S0032-3861(16)30865-5 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.63 bkl 44.69 bkl Voleppe, Quentin verfasserin aut Interdiffusion and phase separation upon curing in thermoset-thermoplastic interphases unravelled by the characterization of partially cured systems 2016transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. Thermoset/thermoplastic interphases Elsevier Concentration profiles Elsevier Partial curing Elsevier Pardoen, Thomas oth Bailly, Christian oth Enthalten in Elsevier Science Fitzgerald, Emily ELSEVIER Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study 2020 the international journal for the science and technology of polymers Oxford (DE-627)ELV005093368 volume:106 year:2016 day:5 month:12 pages:120-127 extent:8 https://doi.org/10.1016/j.polymer.2016.09.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.63 Krankenpflege VZ 44.69 Intensivmedizin VZ AR 106 2016 5 1205 120-127 8 045F 540 |
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Enthalten in Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study Oxford volume:106 year:2016 day:5 month:12 pages:120-127 extent:8 |
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Enthalten in Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study Oxford volume:106 year:2016 day:5 month:12 pages:120-127 extent:8 |
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Functional outcomes at 12 months for patients with traumatic brain injury, intracerebral haemorrhage and subarachnoid haemorrhage treated in an Australian neurocritical care unit: A prospective cohort study |
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Interdiffusion and phase separation upon curing in thermoset-thermoplastic interphases unravelled by the characterization of partially cured systems |
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The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. |
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The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. |
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The evolution upon curing of interdiffusion as well as phase separation is characterized at the interphase between a high Tg poly(ether sulfone) thermoplastic (TP) and a high density thermosetting network (TS), both components being initially miscible. We show that the late stages of the diffusion process overlap with the early stages of phase separation, which is contrary to the expectations from the current state of the art. The penetration depth of the TS into the TP is found to increase with decreasing gelation time within the investigated operating window. This is due to the stronger thermal activation of diffusion over reaction at the early stages of curing. A chemometric model is developed based on Raman spectroscopy data in order to further analyze these results. The predictions of the model are compared with the profiles generated by image analysis carried on microtomed sections of fully cured interphases. The concentration profiles of partially cured interphases are predicted as well and used to correlate the degree of curing of the TS with the front velocity for each profile. |
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