Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices
The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The appl...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Anizelli, Helder Scapin [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017transfer abstract |
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| Schlagwörter: |
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| Umfang: |
6 |
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| Übergeordnetes Werk: |
Enthalten in: Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands - saleh, Dalia I ELSEVIER, 2022, physics, materials and applications, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:49 ; year:2017 ; pages:129-134 ; extent:6 |
| Links: |
|---|
| DOI / URN: |
10.1016/j.orgel.2017.06.056 |
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| 520 | |a The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. | ||
| 520 | |a The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. | ||
| 650 | 7 | |a Degradation |2 Elsevier | |
| 650 | 7 | |a Solar cells |2 Elsevier | |
| 650 | 7 | |a Perovskite |2 Elsevier | |
| 650 | 7 | |a Stability |2 Elsevier | |
| 650 | 7 | |a Luminescence downshifting |2 Elsevier | |
| 700 | 1 | |a Stoichkov, Vasil |4 oth | |
| 700 | 1 | |a Fernandes, Ricardo Vignoto |4 oth | |
| 700 | 1 | |a Duarte, José Leonil |4 oth | |
| 700 | 1 | |a Laureto, Edson |4 oth | |
| 700 | 1 | |a Kettle, Jeff |4 oth | |
| 700 | 1 | |a Visoly-Fisher, Iris |4 oth | |
| 700 | 1 | |a Katz, Eugene A. |4 oth | |
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10.1016/j.orgel.2017.06.056 doi GBV00000000000385.pica (DE-627)ELV025130803 (ELSEVIER)S1566-1199(17)30313-0 DE-627 ger DE-627 rakwb eng 540 VZ 35.00 bkl Anizelli, Helder Scapin verfasserin aut Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. Degradation Elsevier Solar cells Elsevier Perovskite Elsevier Stability Elsevier Luminescence downshifting Elsevier Stoichkov, Vasil oth Fernandes, Ricardo Vignoto oth Duarte, José Leonil oth Laureto, Edson oth Kettle, Jeff oth Visoly-Fisher, Iris oth Katz, Eugene A. oth Enthalten in Elsevier Science saleh, Dalia I ELSEVIER Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands 2022 physics, materials and applications Amsterdam [u.a.] (DE-627)ELV007843747 volume:49 year:2017 pages:129-134 extent:6 https://doi.org/10.1016/j.orgel.2017.06.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.00 Chemie: Allgemeines VZ AR 49 2017 129-134 6 |
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10.1016/j.orgel.2017.06.056 doi GBV00000000000385.pica (DE-627)ELV025130803 (ELSEVIER)S1566-1199(17)30313-0 DE-627 ger DE-627 rakwb eng 540 VZ 35.00 bkl Anizelli, Helder Scapin verfasserin aut Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. Degradation Elsevier Solar cells Elsevier Perovskite Elsevier Stability Elsevier Luminescence downshifting Elsevier Stoichkov, Vasil oth Fernandes, Ricardo Vignoto oth Duarte, José Leonil oth Laureto, Edson oth Kettle, Jeff oth Visoly-Fisher, Iris oth Katz, Eugene A. oth Enthalten in Elsevier Science saleh, Dalia I ELSEVIER Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands 2022 physics, materials and applications Amsterdam [u.a.] (DE-627)ELV007843747 volume:49 year:2017 pages:129-134 extent:6 https://doi.org/10.1016/j.orgel.2017.06.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.00 Chemie: Allgemeines VZ AR 49 2017 129-134 6 |
| allfields_unstemmed |
10.1016/j.orgel.2017.06.056 doi GBV00000000000385.pica (DE-627)ELV025130803 (ELSEVIER)S1566-1199(17)30313-0 DE-627 ger DE-627 rakwb eng 540 VZ 35.00 bkl Anizelli, Helder Scapin verfasserin aut Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. Degradation Elsevier Solar cells Elsevier Perovskite Elsevier Stability Elsevier Luminescence downshifting Elsevier Stoichkov, Vasil oth Fernandes, Ricardo Vignoto oth Duarte, José Leonil oth Laureto, Edson oth Kettle, Jeff oth Visoly-Fisher, Iris oth Katz, Eugene A. oth Enthalten in Elsevier Science saleh, Dalia I ELSEVIER Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands 2022 physics, materials and applications Amsterdam [u.a.] (DE-627)ELV007843747 volume:49 year:2017 pages:129-134 extent:6 https://doi.org/10.1016/j.orgel.2017.06.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.00 Chemie: Allgemeines VZ AR 49 2017 129-134 6 |
| allfieldsGer |
10.1016/j.orgel.2017.06.056 doi GBV00000000000385.pica (DE-627)ELV025130803 (ELSEVIER)S1566-1199(17)30313-0 DE-627 ger DE-627 rakwb eng 540 VZ 35.00 bkl Anizelli, Helder Scapin verfasserin aut Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. Degradation Elsevier Solar cells Elsevier Perovskite Elsevier Stability Elsevier Luminescence downshifting Elsevier Stoichkov, Vasil oth Fernandes, Ricardo Vignoto oth Duarte, José Leonil oth Laureto, Edson oth Kettle, Jeff oth Visoly-Fisher, Iris oth Katz, Eugene A. oth Enthalten in Elsevier Science saleh, Dalia I ELSEVIER Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands 2022 physics, materials and applications Amsterdam [u.a.] (DE-627)ELV007843747 volume:49 year:2017 pages:129-134 extent:6 https://doi.org/10.1016/j.orgel.2017.06.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.00 Chemie: Allgemeines VZ AR 49 2017 129-134 6 |
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10.1016/j.orgel.2017.06.056 doi GBV00000000000385.pica (DE-627)ELV025130803 (ELSEVIER)S1566-1199(17)30313-0 DE-627 ger DE-627 rakwb eng 540 VZ 35.00 bkl Anizelli, Helder Scapin verfasserin aut Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. Degradation Elsevier Solar cells Elsevier Perovskite Elsevier Stability Elsevier Luminescence downshifting Elsevier Stoichkov, Vasil oth Fernandes, Ricardo Vignoto oth Duarte, José Leonil oth Laureto, Edson oth Kettle, Jeff oth Visoly-Fisher, Iris oth Katz, Eugene A. oth Enthalten in Elsevier Science saleh, Dalia I ELSEVIER Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands 2022 physics, materials and applications Amsterdam [u.a.] (DE-627)ELV007843747 volume:49 year:2017 pages:129-134 extent:6 https://doi.org/10.1016/j.orgel.2017.06.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.00 Chemie: Allgemeines VZ AR 49 2017 129-134 6 |
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Enthalten in Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands Amsterdam [u.a.] volume:49 year:2017 pages:129-134 extent:6 |
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Enthalten in Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands Amsterdam [u.a.] volume:49 year:2017 pages:129-134 extent:6 |
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Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands |
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Anizelli, Helder Scapin @@aut@@ Stoichkov, Vasil @@oth@@ Fernandes, Ricardo Vignoto @@oth@@ Duarte, José Leonil @@oth@@ Laureto, Edson @@oth@@ Kettle, Jeff @@oth@@ Visoly-Fisher, Iris @@oth@@ Katz, Eugene A. @@oth@@ |
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Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices |
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Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices |
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Ultrasound-assisted synthesis and biological activity of nanosized supramolecular coordination polymers of silver(I) with chloride, thiocyanate, and 4,4′-bipyridine ligands |
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application of luminescence downshifting materials for enhanced stability of ch<ce:inf loc="post">3</ce:inf>nh<ce:inf loc="post">3</ce:inf>pbi<ce:inf loc="post">3(1-x)</ce:inf>cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices |
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Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices |
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The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. |
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The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. |
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The application of luminescent down shifting (LDS) layers as alternative UV filters for CH3NH3PbI3(1-x)Cl3x perovskite solar cell (PSC) devices is reported. A combination of photo-absorption measurements and of device decay measurements during light soaking are used to verify the stability. The application of a UV filter or LDS layer was able to significantly retard photo-induced degradation with ∼18% drop in device power conversion efficiency (PCE) observed over 30 h for non-encapsulated devices, which is compared to ∼97% for an un-filtered device, also without encapsulation. Whilst the PCE of the PSC device decreases with the application of the LDS layer, the drop is not as significant as when a commercial UV filter is used. Considering that UV filters will be essential for the commercialization of PSCs, the work provides evidence that the LDS layer can act as an alternative UV filter in PSCs and can limit the drop in PCE that can be expected from the inclusion of a UV filter, thus providing an added benefit over commercial UV filters. |
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Application of luminescence downshifting materials for enhanced stability of CH<ce:inf loc="post">3</ce:inf>NH<ce:inf loc="post">3</ce:inf>PbI<ce:inf loc="post">3(1-x)</ce:inf>Cl<ce:inf loc="post">3x</ce:inf> perovskite photovoltaic devices |
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