Osmotic power generation by inner selective hollow fiber membranes: An investigation of thermodynamics, mass transfer, and module scale modelling
A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Xiong, Jun Ying [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017transfer abstract |
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| Schlagwörter: |
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| Umfang: |
12 |
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| Übergeordnetes Werk: |
Enthalten in: Steering charge kinetics in W - Yue, Xin-Zheng ELSEVIER, 2019, the official journal of the North American Membrane Society, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:526 ; year:2017 ; day:15 ; month:03 ; pages:417-428 ; extent:12 |
| Links: |
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| DOI / URN: |
10.1016/j.memsci.2016.12.056 |
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| 520 | |a A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. | ||
| 520 | |a A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. | ||
| 650 | 7 | |a Pressure retarded osmosis (PRO) |2 Elsevier | |
| 650 | 7 | |a Hollow fiber membrane |2 Elsevier | |
| 650 | 7 | |a Module scale simulation |2 Elsevier | |
| 650 | 7 | |a Mass transfer |2 Elsevier | |
| 650 | 7 | |a Gibbs free energy of mixing |2 Elsevier | |
| 700 | 1 | |a Cai, Dong Jun |4 oth | |
| 700 | 1 | |a Chong, Qing Yu |4 oth | |
| 700 | 1 | |a Lee, Swin Hui |4 oth | |
| 700 | 1 | |a Chung, Tai-Shung |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Yue, Xin-Zheng ELSEVIER |t Steering charge kinetics in W |d 2019 |d the official journal of the North American Membrane Society |g New York, NY [u.a.] |w (DE-627)ELV002478420 |
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10.1016/j.memsci.2016.12.056 doi GBV00000000000059A.pica (DE-627)ELV025323369 (ELSEVIER)S0376-7388(16)32344-4 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Xiong, Jun Ying verfasserin aut Osmotic power generation by inner selective hollow fiber membranes: An investigation of thermodynamics, mass transfer, and module scale modelling 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. Pressure retarded osmosis (PRO) Elsevier Hollow fiber membrane Elsevier Module scale simulation Elsevier Mass transfer Elsevier Gibbs free energy of mixing Elsevier Cai, Dong Jun oth Chong, Qing Yu oth Lee, Swin Hui oth Chung, Tai-Shung oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:526 year:2017 day:15 month:03 pages:417-428 extent:12 https://doi.org/10.1016/j.memsci.2016.12.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 526 2017 15 0315 417-428 12 045F 570 |
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10.1016/j.memsci.2016.12.056 doi GBV00000000000059A.pica (DE-627)ELV025323369 (ELSEVIER)S0376-7388(16)32344-4 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Xiong, Jun Ying verfasserin aut Osmotic power generation by inner selective hollow fiber membranes: An investigation of thermodynamics, mass transfer, and module scale modelling 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. Pressure retarded osmosis (PRO) Elsevier Hollow fiber membrane Elsevier Module scale simulation Elsevier Mass transfer Elsevier Gibbs free energy of mixing Elsevier Cai, Dong Jun oth Chong, Qing Yu oth Lee, Swin Hui oth Chung, Tai-Shung oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:526 year:2017 day:15 month:03 pages:417-428 extent:12 https://doi.org/10.1016/j.memsci.2016.12.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 526 2017 15 0315 417-428 12 045F 570 |
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10.1016/j.memsci.2016.12.056 doi GBV00000000000059A.pica (DE-627)ELV025323369 (ELSEVIER)S0376-7388(16)32344-4 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Xiong, Jun Ying verfasserin aut Osmotic power generation by inner selective hollow fiber membranes: An investigation of thermodynamics, mass transfer, and module scale modelling 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. Pressure retarded osmosis (PRO) Elsevier Hollow fiber membrane Elsevier Module scale simulation Elsevier Mass transfer Elsevier Gibbs free energy of mixing Elsevier Cai, Dong Jun oth Chong, Qing Yu oth Lee, Swin Hui oth Chung, Tai-Shung oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:526 year:2017 day:15 month:03 pages:417-428 extent:12 https://doi.org/10.1016/j.memsci.2016.12.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 526 2017 15 0315 417-428 12 045F 570 |
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10.1016/j.memsci.2016.12.056 doi GBV00000000000059A.pica (DE-627)ELV025323369 (ELSEVIER)S0376-7388(16)32344-4 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Xiong, Jun Ying verfasserin aut Osmotic power generation by inner selective hollow fiber membranes: An investigation of thermodynamics, mass transfer, and module scale modelling 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. Pressure retarded osmosis (PRO) Elsevier Hollow fiber membrane Elsevier Module scale simulation Elsevier Mass transfer Elsevier Gibbs free energy of mixing Elsevier Cai, Dong Jun oth Chong, Qing Yu oth Lee, Swin Hui oth Chung, Tai-Shung oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:526 year:2017 day:15 month:03 pages:417-428 extent:12 https://doi.org/10.1016/j.memsci.2016.12.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 526 2017 15 0315 417-428 12 045F 570 |
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10.1016/j.memsci.2016.12.056 doi GBV00000000000059A.pica (DE-627)ELV025323369 (ELSEVIER)S0376-7388(16)32344-4 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Xiong, Jun Ying verfasserin aut Osmotic power generation by inner selective hollow fiber membranes: An investigation of thermodynamics, mass transfer, and module scale modelling 2017transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. Pressure retarded osmosis (PRO) Elsevier Hollow fiber membrane Elsevier Module scale simulation Elsevier Mass transfer Elsevier Gibbs free energy of mixing Elsevier Cai, Dong Jun oth Chong, Qing Yu oth Lee, Swin Hui oth Chung, Tai-Shung oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:526 year:2017 day:15 month:03 pages:417-428 extent:12 https://doi.org/10.1016/j.memsci.2016.12.056 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 526 2017 15 0315 417-428 12 045F 570 |
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Osmotic power generation by inner selective hollow fiber membranes: An investigation of thermodynamics, mass transfer, and module scale modelling |
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A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. |
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A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. |
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A comprehensive analysis of fluid motion, mass transport, thermodynamics and power generation during pressure retarded osmotic (PRO) processes was conducted. This work aims to (1) elucidate the fundamental relationship among various membrane properties and operation parameters and (2) analyse their individual and combined impacts on PRO module performance. A state-of-the-art inner-selective thin-film composite (TFC) hollow fiber membrane was employed in the modelling. The analyses of mass transfer and Gibbs free energy of mixing indicate that the asymmetric nature of hollow fibers results in more significant external concentration polarization (ECP) in the lumen side of the inner-selective hollow fiber membranes. In addition, a trade-off relationship exists between the power density (PD) and the specific energy (SE). The PD vs. SE trade-off upper bound may provide a useful guidance whether the flowrates of the feed and draw solutions should be further optimized in order to (1) minimize the boundary thickness and (2) maximize the osmotic power generation. Two new terms, mass transfer efficiency and power harvesting efficiency for osmotic power generation, have been proposed. This work may provide useful insights to design and operate PRO modules with enhanced performance so that the PRO process becomes more promising in real applications in the near future. |
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Osmotic power generation by inner selective hollow fiber membranes: An investigation of thermodynamics, mass transfer, and module scale modelling |
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