Synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities
We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidoz...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Guo, Dan [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2013transfer abstract |
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| Umfang: |
9 |
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| Übergeordnetes Werk: |
Enthalten in: A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells - Haghgoo, M. ELSEVIER, 2020, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:98 ; year:2013 ; number:3 ; pages:384-392 ; extent:9 |
| Links: |
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| DOI / URN: |
10.1016/j.dyepig.2013.03.026 |
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| 245 | 1 | 0 | |a Synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities |
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| 520 | |a We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. | ||
| 520 | |a We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. | ||
| 650 | 7 | |a Crystal growth |2 Elsevier | |
| 650 | 7 | |a Imidazolium |2 Elsevier | |
| 650 | 7 | |a Second harmonic generation |2 Elsevier | |
| 650 | 7 | |a Synthesis |2 Elsevier | |
| 650 | 7 | |a Organic |2 Elsevier | |
| 650 | 7 | |a Nonlinear optics |2 Elsevier | |
| 700 | 1 | |a Ren, Yan |4 oth | |
| 700 | 1 | |a Liu, Jie |4 oth | |
| 700 | 1 | |a Tao, Xutang |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Haghgoo, M. ELSEVIER |t A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells |d 2020 |g Amsterdam [u.a.] |w (DE-627)ELV004269640 |
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10.1016/j.dyepig.2013.03.026 doi GBVA2013003000021.pica (DE-627)ELV027024121 (ELSEVIER)S0143-7208(13)00115-0 DE-627 ger DE-627 rakwb eng 660 660 DE-600 690 VZ 50.31 bkl 56.11 bkl Guo, Dan verfasserin aut Synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities 2013transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. Crystal growth Elsevier Imidazolium Elsevier Second harmonic generation Elsevier Synthesis Elsevier Organic Elsevier Nonlinear optics Elsevier Ren, Yan oth Liu, Jie oth Tao, Xutang oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:98 year:2013 number:3 pages:384-392 extent:9 https://doi.org/10.1016/j.dyepig.2013.03.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 98 2013 3 384-392 9 045F 660 |
| spelling |
10.1016/j.dyepig.2013.03.026 doi GBVA2013003000021.pica (DE-627)ELV027024121 (ELSEVIER)S0143-7208(13)00115-0 DE-627 ger DE-627 rakwb eng 660 660 DE-600 690 VZ 50.31 bkl 56.11 bkl Guo, Dan verfasserin aut Synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities 2013transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. Crystal growth Elsevier Imidazolium Elsevier Second harmonic generation Elsevier Synthesis Elsevier Organic Elsevier Nonlinear optics Elsevier Ren, Yan oth Liu, Jie oth Tao, Xutang oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:98 year:2013 number:3 pages:384-392 extent:9 https://doi.org/10.1016/j.dyepig.2013.03.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 98 2013 3 384-392 9 045F 660 |
| allfields_unstemmed |
10.1016/j.dyepig.2013.03.026 doi GBVA2013003000021.pica (DE-627)ELV027024121 (ELSEVIER)S0143-7208(13)00115-0 DE-627 ger DE-627 rakwb eng 660 660 DE-600 690 VZ 50.31 bkl 56.11 bkl Guo, Dan verfasserin aut Synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities 2013transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. Crystal growth Elsevier Imidazolium Elsevier Second harmonic generation Elsevier Synthesis Elsevier Organic Elsevier Nonlinear optics Elsevier Ren, Yan oth Liu, Jie oth Tao, Xutang oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:98 year:2013 number:3 pages:384-392 extent:9 https://doi.org/10.1016/j.dyepig.2013.03.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 98 2013 3 384-392 9 045F 660 |
| allfieldsGer |
10.1016/j.dyepig.2013.03.026 doi GBVA2013003000021.pica (DE-627)ELV027024121 (ELSEVIER)S0143-7208(13)00115-0 DE-627 ger DE-627 rakwb eng 660 660 DE-600 690 VZ 50.31 bkl 56.11 bkl Guo, Dan verfasserin aut Synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities 2013transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. Crystal growth Elsevier Imidazolium Elsevier Second harmonic generation Elsevier Synthesis Elsevier Organic Elsevier Nonlinear optics Elsevier Ren, Yan oth Liu, Jie oth Tao, Xutang oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:98 year:2013 number:3 pages:384-392 extent:9 https://doi.org/10.1016/j.dyepig.2013.03.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 98 2013 3 384-392 9 045F 660 |
| allfieldsSound |
10.1016/j.dyepig.2013.03.026 doi GBVA2013003000021.pica (DE-627)ELV027024121 (ELSEVIER)S0143-7208(13)00115-0 DE-627 ger DE-627 rakwb eng 660 660 DE-600 690 VZ 50.31 bkl 56.11 bkl Guo, Dan verfasserin aut Synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities 2013transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. Crystal growth Elsevier Imidazolium Elsevier Second harmonic generation Elsevier Synthesis Elsevier Organic Elsevier Nonlinear optics Elsevier Ren, Yan oth Liu, Jie oth Tao, Xutang oth Enthalten in Elsevier Science Haghgoo, M. ELSEVIER A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells 2020 Amsterdam [u.a.] (DE-627)ELV004269640 volume:98 year:2013 number:3 pages:384-392 extent:9 https://doi.org/10.1016/j.dyepig.2013.03.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 50.31 Technische Mechanik VZ 56.11 Baukonstruktion VZ AR 98 2013 3 384-392 9 045F 660 |
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English |
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Enthalten in A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells Amsterdam [u.a.] volume:98 year:2013 number:3 pages:384-392 extent:9 |
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Enthalten in A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells Amsterdam [u.a.] volume:98 year:2013 number:3 pages:384-392 extent:9 |
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A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells |
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Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. 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A multiscale analysis for free vibration of fuzzy fiber-reinforced nanocomposite conical shells |
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synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities |
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Synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities |
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We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. |
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We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. |
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We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p-[(N, N-dimethylamino) styryl]-3-methylimidozalium 1-naphthalenesulfonate (II) (DINS-1(II)) and trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium mesitylenesulfonate (DITMS) exhibit acentric crystal structures. The former belongs to Pna21 space group, while the latter crystallizes in Pn phase. The macroscopic optical nonlinearity of the acentric crystals have been estimated by Kurtz and Perry powder test at various grain sizes. Compared to DINS-1(II), DITMS exhibits a relatively large second order nonlinearity benefiting from the almost parallel arrangement of the main molecular charge–transfer axis in lattice. The growth of the bulk DITMS crystal has been investigated. |
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