Fractionation of pure solvent components from degraded PUREX solvent using room temperature ionic liquids
With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liqu...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Panja, S. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014transfer abstract |
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| Schlagwörter: |
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| Umfang: |
6 |
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| Übergeordnetes Werk: |
Enthalten in: Effects of biofilm and co-culture with - Zeng, Xiangyong ELSEVIER, 2023, a merger of Separations technology and Gas separation & purification, Amsterdam [u.a.] |
|---|---|
| Übergeordnetes Werk: |
volume:122 ; year:2014 ; day:10 ; month:02 ; pages:67-72 ; extent:6 |
| Links: |
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| DOI / URN: |
10.1016/j.seppur.2013.10.046 |
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ELV027801055 |
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| 245 | 1 | 0 | |a Fractionation of pure solvent components from degraded PUREX solvent using room temperature ionic liquids |
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| 520 | |a With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. | ||
| 520 | |a With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. | ||
| 650 | 7 | |a RTIL |2 Elsevier | |
| 650 | 7 | |a TBP |2 Elsevier | |
| 650 | 7 | |a Reusability |2 Elsevier | |
| 650 | 7 | |a HDBP |2 Elsevier | |
| 650 | 7 | |a PUREX |2 Elsevier | |
| 700 | 1 | |a Misra, S.K. |4 oth | |
| 700 | 1 | |a Tripathi, S.C. |4 oth | |
| 700 | 1 | |a Bindu, M. |4 oth | |
| 700 | 1 | |a Gandhi, P.M. |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier Science |a Zeng, Xiangyong ELSEVIER |t Effects of biofilm and co-culture with |d 2023 |d a merger of Separations technology and Gas separation & purification |g Amsterdam [u.a.] |w (DE-627)ELV009500197 |
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10.1016/j.seppur.2013.10.046 doi GBVA2014002000029.pica (DE-627)ELV027801055 (ELSEVIER)S1383-5866(13)00639-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 570 630 640 VZ BIODIV DE-30 fid 42.30 bkl 44.21 bkl 58.34 bkl Panja, S. verfasserin aut Fractionation of pure solvent components from degraded PUREX solvent using room temperature ionic liquids 2014transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. RTIL Elsevier TBP Elsevier Reusability Elsevier HDBP Elsevier PUREX Elsevier Misra, S.K. oth Tripathi, S.C. oth Bindu, M. oth Gandhi, P.M. oth Enthalten in Elsevier Science Zeng, Xiangyong ELSEVIER Effects of biofilm and co-culture with 2023 a merger of Separations technology and Gas separation & purification Amsterdam [u.a.] (DE-627)ELV009500197 volume:122 year:2014 day:10 month:02 pages:67-72 extent:6 https://doi.org/10.1016/j.seppur.2013.10.046 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 42.30 Mikrobiologie VZ 44.21 Ernährung Medizin VZ 58.34 Lebensmitteltechnologie VZ AR 122 2014 10 0210 67-72 6 045F 540 |
| spelling |
10.1016/j.seppur.2013.10.046 doi GBVA2014002000029.pica (DE-627)ELV027801055 (ELSEVIER)S1383-5866(13)00639-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 570 630 640 VZ BIODIV DE-30 fid 42.30 bkl 44.21 bkl 58.34 bkl Panja, S. verfasserin aut Fractionation of pure solvent components from degraded PUREX solvent using room temperature ionic liquids 2014transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. RTIL Elsevier TBP Elsevier Reusability Elsevier HDBP Elsevier PUREX Elsevier Misra, S.K. oth Tripathi, S.C. oth Bindu, M. oth Gandhi, P.M. oth Enthalten in Elsevier Science Zeng, Xiangyong ELSEVIER Effects of biofilm and co-culture with 2023 a merger of Separations technology and Gas separation & purification Amsterdam [u.a.] (DE-627)ELV009500197 volume:122 year:2014 day:10 month:02 pages:67-72 extent:6 https://doi.org/10.1016/j.seppur.2013.10.046 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 42.30 Mikrobiologie VZ 44.21 Ernährung Medizin VZ 58.34 Lebensmitteltechnologie VZ AR 122 2014 10 0210 67-72 6 045F 540 |
| allfields_unstemmed |
10.1016/j.seppur.2013.10.046 doi GBVA2014002000029.pica (DE-627)ELV027801055 (ELSEVIER)S1383-5866(13)00639-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 570 630 640 VZ BIODIV DE-30 fid 42.30 bkl 44.21 bkl 58.34 bkl Panja, S. verfasserin aut Fractionation of pure solvent components from degraded PUREX solvent using room temperature ionic liquids 2014transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. RTIL Elsevier TBP Elsevier Reusability Elsevier HDBP Elsevier PUREX Elsevier Misra, S.K. oth Tripathi, S.C. oth Bindu, M. oth Gandhi, P.M. oth Enthalten in Elsevier Science Zeng, Xiangyong ELSEVIER Effects of biofilm and co-culture with 2023 a merger of Separations technology and Gas separation & purification Amsterdam [u.a.] (DE-627)ELV009500197 volume:122 year:2014 day:10 month:02 pages:67-72 extent:6 https://doi.org/10.1016/j.seppur.2013.10.046 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 42.30 Mikrobiologie VZ 44.21 Ernährung Medizin VZ 58.34 Lebensmitteltechnologie VZ AR 122 2014 10 0210 67-72 6 045F 540 |
| allfieldsGer |
10.1016/j.seppur.2013.10.046 doi GBVA2014002000029.pica (DE-627)ELV027801055 (ELSEVIER)S1383-5866(13)00639-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 570 630 640 VZ BIODIV DE-30 fid 42.30 bkl 44.21 bkl 58.34 bkl Panja, S. verfasserin aut Fractionation of pure solvent components from degraded PUREX solvent using room temperature ionic liquids 2014transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. RTIL Elsevier TBP Elsevier Reusability Elsevier HDBP Elsevier PUREX Elsevier Misra, S.K. oth Tripathi, S.C. oth Bindu, M. oth Gandhi, P.M. oth Enthalten in Elsevier Science Zeng, Xiangyong ELSEVIER Effects of biofilm and co-culture with 2023 a merger of Separations technology and Gas separation & purification Amsterdam [u.a.] (DE-627)ELV009500197 volume:122 year:2014 day:10 month:02 pages:67-72 extent:6 https://doi.org/10.1016/j.seppur.2013.10.046 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 42.30 Mikrobiologie VZ 44.21 Ernährung Medizin VZ 58.34 Lebensmitteltechnologie VZ AR 122 2014 10 0210 67-72 6 045F 540 |
| allfieldsSound |
10.1016/j.seppur.2013.10.046 doi GBVA2014002000029.pica (DE-627)ELV027801055 (ELSEVIER)S1383-5866(13)00639-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 570 630 640 VZ BIODIV DE-30 fid 42.30 bkl 44.21 bkl 58.34 bkl Panja, S. verfasserin aut Fractionation of pure solvent components from degraded PUREX solvent using room temperature ionic liquids 2014transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. RTIL Elsevier TBP Elsevier Reusability Elsevier HDBP Elsevier PUREX Elsevier Misra, S.K. oth Tripathi, S.C. oth Bindu, M. oth Gandhi, P.M. oth Enthalten in Elsevier Science Zeng, Xiangyong ELSEVIER Effects of biofilm and co-culture with 2023 a merger of Separations technology and Gas separation & purification Amsterdam [u.a.] (DE-627)ELV009500197 volume:122 year:2014 day:10 month:02 pages:67-72 extent:6 https://doi.org/10.1016/j.seppur.2013.10.046 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-BIODIV SSG-OLC-PHA 42.30 Mikrobiologie VZ 44.21 Ernährung Medizin VZ 58.34 Lebensmitteltechnologie VZ AR 122 2014 10 0210 67-72 6 045F 540 |
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fractionation of pure solvent components from degraded purex solvent using room temperature ionic liquids |
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Fractionation of pure solvent components from degraded PUREX solvent using room temperature ionic liquids |
| abstract |
With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. |
| abstractGer |
With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. |
| abstract_unstemmed |
With the view point of recovery of pure solvent components from degraded PUREX (Plutonium URanium Extraction) solvent, comprising of mixture of 30% TBP–HDBP-n-dodecane, three homologues of room temperature ionic liquids (C n mimCl, n =4, 6, 8) have been investigated in batch equilibration mode (liquid–liquid extraction). While lower homologues of RTIL (C4 and C6) could effectively separate out HDBP from pure TBP–HDBP-n-dodecane mixture, the higher homologue C8mimCl could quantitatively remove TBP and HDBP together leaving behind pure n-dodecane as organic phase. Efficacy of RTIL solutions have also been studied as a function of RTIL concentration, composition of various components in organic mixture, kinetics of extraction, etc. These ionic liquids were found to retain their efficacy even after five cycles of operation after their regeneration. Studies from actual degraded solvent showed that C8mimCl could remove HDBP quantitatively and TBP (∼45% of the initial concentration) whereas C6mimCl and C4mimCl showed very little extraction even for HDBP. The mechanism of extraction was found to be formation of micelles and ion-pair formation. |
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Fractionation of pure solvent components from degraded PUREX solvent using room temperature ionic liquids |
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