Preparation and characterization of stimuli-responsive hydrophilic polysulfone membrane modified with poly (N-vinylcaprolactam-co-acrylic acid)
Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane cast...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Sinha, M.K. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014transfer abstract |
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| Umfang: |
10 |
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| Übergeordnetes Werk: |
Enthalten in: Differential effects of total sleep deprivation on contextual and spatial memory: Modulatory effects of modafinil - 2011transfer abstract, the international journal on the science and technology of desalting and water purification, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:348 ; year:2014 ; day:1 ; month:09 ; pages:16-25 ; extent:10 |
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| DOI / URN: |
10.1016/j.desal.2014.06.007 |
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| 520 | |a Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. | ||
| 520 | |a Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. | ||
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10.1016/j.desal.2014.06.007 doi GBVA2014020000018.pica (DE-627)ELV028432282 (ELSEVIER)S0011-9164(14)00328-2 DE-627 ger DE-627 rakwb eng 570 690 570 DE-600 690 DE-600 540 VZ 610 VZ 44.85 bkl Sinha, M.K. verfasserin aut Preparation and characterization of stimuli-responsive hydrophilic polysulfone membrane modified with poly (N-vinylcaprolactam-co-acrylic acid) 2014transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Purkait, M.K. oth Enthalten in Elsevier Science Differential effects of total sleep deprivation on contextual and spatial memory: Modulatory effects of modafinil 2011transfer abstract the international journal on the science and technology of desalting and water purification Amsterdam [u.a.] (DE-627)ELV010644288 volume:348 year:2014 day:1 month:09 pages:16-25 extent:10 https://doi.org/10.1016/j.desal.2014.06.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ AR 348 2014 1 0901 16-25 10 045F 570 |
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10.1016/j.desal.2014.06.007 doi GBVA2014020000018.pica (DE-627)ELV028432282 (ELSEVIER)S0011-9164(14)00328-2 DE-627 ger DE-627 rakwb eng 570 690 570 DE-600 690 DE-600 540 VZ 610 VZ 44.85 bkl Sinha, M.K. verfasserin aut Preparation and characterization of stimuli-responsive hydrophilic polysulfone membrane modified with poly (N-vinylcaprolactam-co-acrylic acid) 2014transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Purkait, M.K. oth Enthalten in Elsevier Science Differential effects of total sleep deprivation on contextual and spatial memory: Modulatory effects of modafinil 2011transfer abstract the international journal on the science and technology of desalting and water purification Amsterdam [u.a.] (DE-627)ELV010644288 volume:348 year:2014 day:1 month:09 pages:16-25 extent:10 https://doi.org/10.1016/j.desal.2014.06.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ AR 348 2014 1 0901 16-25 10 045F 570 |
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10.1016/j.desal.2014.06.007 doi GBVA2014020000018.pica (DE-627)ELV028432282 (ELSEVIER)S0011-9164(14)00328-2 DE-627 ger DE-627 rakwb eng 570 690 570 DE-600 690 DE-600 540 VZ 610 VZ 44.85 bkl Sinha, M.K. verfasserin aut Preparation and characterization of stimuli-responsive hydrophilic polysulfone membrane modified with poly (N-vinylcaprolactam-co-acrylic acid) 2014transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Purkait, M.K. oth Enthalten in Elsevier Science Differential effects of total sleep deprivation on contextual and spatial memory: Modulatory effects of modafinil 2011transfer abstract the international journal on the science and technology of desalting and water purification Amsterdam [u.a.] (DE-627)ELV010644288 volume:348 year:2014 day:1 month:09 pages:16-25 extent:10 https://doi.org/10.1016/j.desal.2014.06.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ AR 348 2014 1 0901 16-25 10 045F 570 |
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10.1016/j.desal.2014.06.007 doi GBVA2014020000018.pica (DE-627)ELV028432282 (ELSEVIER)S0011-9164(14)00328-2 DE-627 ger DE-627 rakwb eng 570 690 570 DE-600 690 DE-600 540 VZ 610 VZ 44.85 bkl Sinha, M.K. verfasserin aut Preparation and characterization of stimuli-responsive hydrophilic polysulfone membrane modified with poly (N-vinylcaprolactam-co-acrylic acid) 2014transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Purkait, M.K. oth Enthalten in Elsevier Science Differential effects of total sleep deprivation on contextual and spatial memory: Modulatory effects of modafinil 2011transfer abstract the international journal on the science and technology of desalting and water purification Amsterdam [u.a.] (DE-627)ELV010644288 volume:348 year:2014 day:1 month:09 pages:16-25 extent:10 https://doi.org/10.1016/j.desal.2014.06.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ AR 348 2014 1 0901 16-25 10 045F 570 |
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10.1016/j.desal.2014.06.007 doi GBVA2014020000018.pica (DE-627)ELV028432282 (ELSEVIER)S0011-9164(14)00328-2 DE-627 ger DE-627 rakwb eng 570 690 570 DE-600 690 DE-600 540 VZ 610 VZ 44.85 bkl Sinha, M.K. verfasserin aut Preparation and characterization of stimuli-responsive hydrophilic polysulfone membrane modified with poly (N-vinylcaprolactam-co-acrylic acid) 2014transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. Purkait, M.K. oth Enthalten in Elsevier Science Differential effects of total sleep deprivation on contextual and spatial memory: Modulatory effects of modafinil 2011transfer abstract the international journal on the science and technology of desalting and water purification Amsterdam [u.a.] (DE-627)ELV010644288 volume:348 year:2014 day:1 month:09 pages:16-25 extent:10 https://doi.org/10.1016/j.desal.2014.06.007 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ AR 348 2014 1 0901 16-25 10 045F 570 |
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preparation and characterization of stimuli-responsive hydrophilic polysulfone membrane modified with poly (n-vinylcaprolactam-co-acrylic acid) |
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Preparation and characterization of stimuli-responsive hydrophilic polysulfone membrane modified with poly (N-vinylcaprolactam-co-acrylic acid) |
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Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. |
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Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. |
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Novel polysulfone (PSF) ultrafiltration membranes with pH and thermo sensitivity were prepared using the copolymer poly (N-vinylcaprolactam-co-acrylic acid) (poly (VCL-co-AA)) as an additive. The copolymer was synthesized by free radical solution polymerization, and directly blended in membrane casting solution to prepare the asymmetric membranes by phase inversion method. The presence of copolymer in blended membranes was confirmed by comparing IR spectra of plain PSF membrane and blended PSF membrane. The morphology and structure of the resulting membranes were observed by scanning electron microscope (SEM) and field emission scanning electron microscope (FESEM). The membranes were characterized in terms of pure water flux (PWF), hydraulic permeability and hydrophilicity. PWF increased from 1 to 18.8L/m2h, when wt.% of copolymer increases from 0 to 2.5. Similarly, water contact angle decreased from 76° to 58°. The blended membranes showed evident of pH and thermo sensitivity. The stimuli responsive behaviour of membranes was also investigated in terms of pH and temperature. In addition, solution of bovine serum albumin (BSA) was used to study the permeation and antifouling performance of prepared membranes. A significant increase in BSA flux (from 0.061L/m2h for plain membrane to 3.37L/m2h for membrane with 6 wt.% of copolymer) and decrease in membrane fouling was observed. |
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