Synthesis, photophysical and electrochemical properties of symmetric silicon-linked diphenyl 1,3,4-oxadizole derivatives
A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggr...
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| Autor*in: |
Li, Dongfeng [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015transfer abstract |
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| Umfang: |
6 |
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| Übergeordnetes Werk: |
Enthalten in: Therapeutic Advances in Pediatric Multiple Sclerosis - 2013, the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry, Amsterdam [u.a.] |
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| Übergeordnetes Werk: |
volume:71 ; year:2015 ; number:18 ; day:6 ; month:05 ; pages:2680-2685 ; extent:6 |
| Links: |
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| DOI / URN: |
10.1016/j.tet.2015.03.039 |
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| 520 | |a A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. | ||
| 520 | |a A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. | ||
| 650 | 7 | |a Electron-transporting materials |2 Elsevier | |
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| 700 | 1 | |a Shang, Xiaohong |4 oth | |
| 700 | 1 | |a Xia, Yan |4 oth | |
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| 700 | 1 | |a Li, Min |4 oth | |
| 700 | 1 | |a Li, Bao |4 oth | |
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10.1016/j.tet.2015.03.039 doi GBVA2015001000005.pica (DE-627)ELV028561341 (ELSEVIER)S0040-4020(15)00337-3 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Li, Dongfeng verfasserin aut Synthesis, photophysical and electrochemical properties of symmetric silicon-linked diphenyl 1,3,4-oxadizole derivatives 2015transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. Electron-transporting materials Elsevier 1,3,4-Oxadizoles Elsevier Theoretical calculation Elsevier Huang, Zhuo oth Shang, Xiaohong oth Xia, Yan oth Zhang, Yuandong oth Li, Min oth Li, Bao oth Hou, Ruibin oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:71 year:2015 number:18 day:6 month:05 pages:2680-2685 extent:6 https://doi.org/10.1016/j.tet.2015.03.039 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 71 2015 18 6 0506 2680-2685 6 045F 540 |
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10.1016/j.tet.2015.03.039 doi GBVA2015001000005.pica (DE-627)ELV028561341 (ELSEVIER)S0040-4020(15)00337-3 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Li, Dongfeng verfasserin aut Synthesis, photophysical and electrochemical properties of symmetric silicon-linked diphenyl 1,3,4-oxadizole derivatives 2015transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. Electron-transporting materials Elsevier 1,3,4-Oxadizoles Elsevier Theoretical calculation Elsevier Huang, Zhuo oth Shang, Xiaohong oth Xia, Yan oth Zhang, Yuandong oth Li, Min oth Li, Bao oth Hou, Ruibin oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:71 year:2015 number:18 day:6 month:05 pages:2680-2685 extent:6 https://doi.org/10.1016/j.tet.2015.03.039 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 71 2015 18 6 0506 2680-2685 6 045F 540 |
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10.1016/j.tet.2015.03.039 doi GBVA2015001000005.pica (DE-627)ELV028561341 (ELSEVIER)S0040-4020(15)00337-3 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Li, Dongfeng verfasserin aut Synthesis, photophysical and electrochemical properties of symmetric silicon-linked diphenyl 1,3,4-oxadizole derivatives 2015transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. Electron-transporting materials Elsevier 1,3,4-Oxadizoles Elsevier Theoretical calculation Elsevier Huang, Zhuo oth Shang, Xiaohong oth Xia, Yan oth Zhang, Yuandong oth Li, Min oth Li, Bao oth Hou, Ruibin oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:71 year:2015 number:18 day:6 month:05 pages:2680-2685 extent:6 https://doi.org/10.1016/j.tet.2015.03.039 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 71 2015 18 6 0506 2680-2685 6 045F 540 |
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10.1016/j.tet.2015.03.039 doi GBVA2015001000005.pica (DE-627)ELV028561341 (ELSEVIER)S0040-4020(15)00337-3 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Li, Dongfeng verfasserin aut Synthesis, photophysical and electrochemical properties of symmetric silicon-linked diphenyl 1,3,4-oxadizole derivatives 2015transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. Electron-transporting materials Elsevier 1,3,4-Oxadizoles Elsevier Theoretical calculation Elsevier Huang, Zhuo oth Shang, Xiaohong oth Xia, Yan oth Zhang, Yuandong oth Li, Min oth Li, Bao oth Hou, Ruibin oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:71 year:2015 number:18 day:6 month:05 pages:2680-2685 extent:6 https://doi.org/10.1016/j.tet.2015.03.039 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 71 2015 18 6 0506 2680-2685 6 045F 540 |
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10.1016/j.tet.2015.03.039 doi GBVA2015001000005.pica (DE-627)ELV028561341 (ELSEVIER)S0040-4020(15)00337-3 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 150 VZ LING DE-30 fid 77.00 bkl Li, Dongfeng verfasserin aut Synthesis, photophysical and electrochemical properties of symmetric silicon-linked diphenyl 1,3,4-oxadizole derivatives 2015transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. Electron-transporting materials Elsevier 1,3,4-Oxadizoles Elsevier Theoretical calculation Elsevier Huang, Zhuo oth Shang, Xiaohong oth Xia, Yan oth Zhang, Yuandong oth Li, Min oth Li, Bao oth Hou, Ruibin oth Enthalten in Elsevier Science Therapeutic Advances in Pediatric Multiple Sclerosis 2013 the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry Amsterdam [u.a.] (DE-627)ELV011938943 volume:71 year:2015 number:18 day:6 month:05 pages:2680-2685 extent:6 https://doi.org/10.1016/j.tet.2015.03.039 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U FID-LING 77.00 Psychologie: Allgemeines VZ AR 71 2015 18 6 0506 2680-2685 6 045F 540 |
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Synthesis, photophysical and electrochemical properties of symmetric silicon-linked diphenyl 1,3,4-oxadizole derivatives |
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A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. |
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A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. |
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A series of novel, symmetric, silicon-linked, V-shaped, organic fluorescent compounds 1a–c with an electron-deficient 1,3,4-oxadizoles unit and a diphenyl moiety were successfully synthesized. We show that the Si atom possesses a special V-shaped structure that weakens π–π stacking resulting in aggregation-induced emission. This new type of compound may show tunable light emission in solution and in a solid-state thin film. Theoretical calculations were used to analyze the frontier molecular orbitals of the two compounds. The HOMO and LUMO energy levels of the studied compounds range from −1.55 to −1.78 eV and from −5.70 to −6.15 eV, indicating that they will function well as electron transport materials. |
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