Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents
A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Holmes, Michael R. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015transfer abstract |
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| Umfang: |
7 |
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| Übergeordnetes Werk: |
Enthalten in: The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial - Li, Chenglong ELSEVIER, 2019, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:795 ; year:2015 ; day:15 ; month:10 ; pages:18-24 ; extent:7 |
| Links: |
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| DOI / URN: |
10.1016/j.jorganchem.2015.02.034 |
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ELV029361818 |
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| 245 | 1 | 0 | |a Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents |
| 264 | 1 | |c 2015transfer abstract | |
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| 520 | |a A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. | ||
| 520 | |a A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. | ||
| 650 | 7 | |a Gold (I) complexes |2 Elsevier | |
| 650 | 7 | |a Rotational barrier |2 Elsevier | |
| 650 | 7 | |a NHC ligands |2 Elsevier | |
| 650 | 7 | |a Percent buried volumes |2 Elsevier | |
| 650 | 7 | |a Ligand dynamics |2 Elsevier | |
| 700 | 1 | |a Manganaro, John F. |4 oth | |
| 700 | 1 | |a Barnes, Charles L. |4 oth | |
| 700 | 1 | |a Gung, Benjamin W. |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Li, Chenglong ELSEVIER |t The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |d 2019 |g New York, NY [u.a.] |w (DE-627)ELV002971518 |
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10.1016/j.jorganchem.2015.02.034 doi GBVA2015023000001.pica (DE-627)ELV029361818 (ELSEVIER)S0022-328X(15)00112-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Holmes, Michael R. verfasserin aut Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents 2015transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. Gold (I) complexes Elsevier Rotational barrier Elsevier NHC ligands Elsevier Percent buried volumes Elsevier Ligand dynamics Elsevier Manganaro, John F. oth Barnes, Charles L. oth Gung, Benjamin W. oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:795 year:2015 day:15 month:10 pages:18-24 extent:7 https://doi.org/10.1016/j.jorganchem.2015.02.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 795 2015 15 1015 18-24 7 045F 540 |
| spelling |
10.1016/j.jorganchem.2015.02.034 doi GBVA2015023000001.pica (DE-627)ELV029361818 (ELSEVIER)S0022-328X(15)00112-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Holmes, Michael R. verfasserin aut Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents 2015transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. Gold (I) complexes Elsevier Rotational barrier Elsevier NHC ligands Elsevier Percent buried volumes Elsevier Ligand dynamics Elsevier Manganaro, John F. oth Barnes, Charles L. oth Gung, Benjamin W. oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:795 year:2015 day:15 month:10 pages:18-24 extent:7 https://doi.org/10.1016/j.jorganchem.2015.02.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 795 2015 15 1015 18-24 7 045F 540 |
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10.1016/j.jorganchem.2015.02.034 doi GBVA2015023000001.pica (DE-627)ELV029361818 (ELSEVIER)S0022-328X(15)00112-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Holmes, Michael R. verfasserin aut Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents 2015transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. Gold (I) complexes Elsevier Rotational barrier Elsevier NHC ligands Elsevier Percent buried volumes Elsevier Ligand dynamics Elsevier Manganaro, John F. oth Barnes, Charles L. oth Gung, Benjamin W. oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:795 year:2015 day:15 month:10 pages:18-24 extent:7 https://doi.org/10.1016/j.jorganchem.2015.02.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 795 2015 15 1015 18-24 7 045F 540 |
| allfieldsGer |
10.1016/j.jorganchem.2015.02.034 doi GBVA2015023000001.pica (DE-627)ELV029361818 (ELSEVIER)S0022-328X(15)00112-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Holmes, Michael R. verfasserin aut Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents 2015transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. Gold (I) complexes Elsevier Rotational barrier Elsevier NHC ligands Elsevier Percent buried volumes Elsevier Ligand dynamics Elsevier Manganaro, John F. oth Barnes, Charles L. oth Gung, Benjamin W. oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:795 year:2015 day:15 month:10 pages:18-24 extent:7 https://doi.org/10.1016/j.jorganchem.2015.02.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 795 2015 15 1015 18-24 7 045F 540 |
| allfieldsSound |
10.1016/j.jorganchem.2015.02.034 doi GBVA2015023000001.pica (DE-627)ELV029361818 (ELSEVIER)S0022-328X(15)00112-6 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Holmes, Michael R. verfasserin aut Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents 2015transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. Gold (I) complexes Elsevier Rotational barrier Elsevier NHC ligands Elsevier Percent buried volumes Elsevier Ligand dynamics Elsevier Manganaro, John F. oth Barnes, Charles L. oth Gung, Benjamin W. oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:795 year:2015 day:15 month:10 pages:18-24 extent:7 https://doi.org/10.1016/j.jorganchem.2015.02.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 795 2015 15 1015 18-24 7 045F 540 |
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Enthalten in The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial New York, NY [u.a.] volume:795 year:2015 day:15 month:10 pages:18-24 extent:7 |
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Enthalten in The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial New York, NY [u.a.] volume:795 year:2015 day:15 month:10 pages:18-24 extent:7 |
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The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
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Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents |
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The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
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synthesis and characterization of novel chiral [(nhc)au(i)cl] complexes: featuring ortho-biphenyl substituents |
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Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents |
| abstract |
A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. |
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A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. |
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A series of new chiral [(NHC)Au(I)Cl] are synthesized. The chiral NHC ligands feature pairs of ortho-biphenyl groups. The distal phenyl groups of the biphenyl substituents are varied from simple phenyl, 3,5-dimethylphenyl, to 3,5-di-t-butylphenyl. X-Ray structure analysis were performed for two such [(NHC)Au(I)Cl] complexes. High percent buried volumes were calculated for two novel chiral [(NHC)Au(I)Cl]complexes whose structure were solved by an X-ray analysis. The rotational motion in the biphenyl group is slow on the NMR time scale. Rotational barriers were determined using WINDNMR for two of the chiral gold complexes. |
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Synthesis and characterization of novel chiral [(NHC)Au(I)Cl] complexes: Featuring ortho-biphenyl substituents |
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