A comment on water’s structure using monomer fraction data and theories
Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer f...
Ausführliche Beschreibung
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| Autor*in: |
Liang, Xiaodong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016transfer abstract |
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| Schlagwörter: |
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| Umfang: |
5 |
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| Übergeordnetes Werk: |
Enthalten in: Fabrication and compressive behaviour of an aluminium foam composite - Li, Yong-gang ELSEVIER, 2015, an international journal, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:407 ; year:2016 ; day:15 ; month:01 ; pages:2-6 ; extent:5 |
| Links: |
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| DOI / URN: |
10.1016/j.fluid.2015.06.017 |
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ELV029783720 |
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| 520 | |a Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. | ||
| 520 | |a Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. | ||
| 650 | 7 | |a Water |2 Elsevier | |
| 650 | 7 | |a Monomer fractions |2 Elsevier | |
| 650 | 7 | |a Dielectric constant |2 Elsevier | |
| 650 | 7 | |a CPA |2 Elsevier | |
| 650 | 7 | |a SAFT |2 Elsevier | |
| 700 | 1 | |a Maribo-Mogensen, Bjørn |4 oth | |
| 700 | 1 | |a Tsivintzelis, Ioannis |4 oth | |
| 700 | 1 | |a Kontogeorgis, Georgios M. |4 oth | |
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10.1016/j.fluid.2015.06.017 doi GBVA2016013000005.pica (DE-627)ELV029783720 (ELSEVIER)S0378-3812(15)00336-2 DE-627 ger DE-627 rakwb eng 660 540 660 DE-600 540 DE-600 670 VZ 540 VZ 630 VZ Liang, Xiaodong verfasserin aut A comment on water’s structure using monomer fraction data and theories 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Water Elsevier Monomer fractions Elsevier Dielectric constant Elsevier CPA Elsevier SAFT Elsevier Maribo-Mogensen, Bjørn oth Tsivintzelis, Ioannis oth Kontogeorgis, Georgios M. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:407 year:2016 day:15 month:01 pages:2-6 extent:5 https://doi.org/10.1016/j.fluid.2015.06.017 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 407 2016 15 0115 2-6 5 045F 660 |
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10.1016/j.fluid.2015.06.017 doi GBVA2016013000005.pica (DE-627)ELV029783720 (ELSEVIER)S0378-3812(15)00336-2 DE-627 ger DE-627 rakwb eng 660 540 660 DE-600 540 DE-600 670 VZ 540 VZ 630 VZ Liang, Xiaodong verfasserin aut A comment on water’s structure using monomer fraction data and theories 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Water Elsevier Monomer fractions Elsevier Dielectric constant Elsevier CPA Elsevier SAFT Elsevier Maribo-Mogensen, Bjørn oth Tsivintzelis, Ioannis oth Kontogeorgis, Georgios M. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:407 year:2016 day:15 month:01 pages:2-6 extent:5 https://doi.org/10.1016/j.fluid.2015.06.017 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 407 2016 15 0115 2-6 5 045F 660 |
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10.1016/j.fluid.2015.06.017 doi GBVA2016013000005.pica (DE-627)ELV029783720 (ELSEVIER)S0378-3812(15)00336-2 DE-627 ger DE-627 rakwb eng 660 540 660 DE-600 540 DE-600 670 VZ 540 VZ 630 VZ Liang, Xiaodong verfasserin aut A comment on water’s structure using monomer fraction data and theories 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Water Elsevier Monomer fractions Elsevier Dielectric constant Elsevier CPA Elsevier SAFT Elsevier Maribo-Mogensen, Bjørn oth Tsivintzelis, Ioannis oth Kontogeorgis, Georgios M. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:407 year:2016 day:15 month:01 pages:2-6 extent:5 https://doi.org/10.1016/j.fluid.2015.06.017 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 407 2016 15 0115 2-6 5 045F 660 |
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10.1016/j.fluid.2015.06.017 doi GBVA2016013000005.pica (DE-627)ELV029783720 (ELSEVIER)S0378-3812(15)00336-2 DE-627 ger DE-627 rakwb eng 660 540 660 DE-600 540 DE-600 670 VZ 540 VZ 630 VZ Liang, Xiaodong verfasserin aut A comment on water’s structure using monomer fraction data and theories 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Water Elsevier Monomer fractions Elsevier Dielectric constant Elsevier CPA Elsevier SAFT Elsevier Maribo-Mogensen, Bjørn oth Tsivintzelis, Ioannis oth Kontogeorgis, Georgios M. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:407 year:2016 day:15 month:01 pages:2-6 extent:5 https://doi.org/10.1016/j.fluid.2015.06.017 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 407 2016 15 0115 2-6 5 045F 660 |
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10.1016/j.fluid.2015.06.017 doi GBVA2016013000005.pica (DE-627)ELV029783720 (ELSEVIER)S0378-3812(15)00336-2 DE-627 ger DE-627 rakwb eng 660 540 660 DE-600 540 DE-600 670 VZ 540 VZ 630 VZ Liang, Xiaodong verfasserin aut A comment on water’s structure using monomer fraction data and theories 2016transfer abstract 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. Water Elsevier Monomer fractions Elsevier Dielectric constant Elsevier CPA Elsevier SAFT Elsevier Maribo-Mogensen, Bjørn oth Tsivintzelis, Ioannis oth Kontogeorgis, Georgios M. oth Enthalten in Science Direct Li, Yong-gang ELSEVIER Fabrication and compressive behaviour of an aluminium foam composite 2015 an international journal New York, NY [u.a.] (DE-627)ELV013241125 volume:407 year:2016 day:15 month:01 pages:2-6 extent:5 https://doi.org/10.1016/j.fluid.2015.06.017 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_31 GBV_ILN_40 GBV_ILN_100 GBV_ILN_136 AR 407 2016 15 0115 2-6 5 045F 660 |
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Enthalten in Fabrication and compressive behaviour of an aluminium foam composite New York, NY [u.a.] volume:407 year:2016 day:15 month:01 pages:2-6 extent:5 |
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Enthalten in Fabrication and compressive behaviour of an aluminium foam composite New York, NY [u.a.] volume:407 year:2016 day:15 month:01 pages:2-6 extent:5 |
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Fabrication and compressive behaviour of an aluminium foam composite |
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Liang, Xiaodong @@aut@@ Maribo-Mogensen, Bjørn @@oth@@ Tsivintzelis, Ioannis @@oth@@ Kontogeorgis, Georgios M. @@oth@@ |
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a comment on water’s structure using monomer fraction data and theories |
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A comment on water’s structure using monomer fraction data and theories |
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Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. |
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Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. |
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Monomer fraction data for water (and other compounds) can provide useful information about their structure and can be used in “advanced” equations of state, which account explicitly for association phenomena. Recent findings about the performance of association theories in representing the monomer fraction of water are reviewed. Three such theories are considered and all of them perform qualitatively similar. They can all represent phase equilibria for water solutions qualitatively well but with parameters which are not in good agreement with Luck’s famous monomer fraction data. While this could set the theoretical basis of these theories in doubt, we also show in this work that the findings with these association models are in agreement with a recently presented theory which links monomer fraction to dielectric constants. This new theory, like the three thermodynamic models, predicts more hydrogen bonding in water than Luck’s data (Angew. Chem. Int. Ed. Engl. 1980, vol. 19, pp. 28). Moreover, it appears that both the new theory and the three models provide evidence for the four-site association scheme for water and thus support that the tetrahedral structure of the water molecule is correct or at least that the tetrahedral structure is in agreement with several pure water physical properties, monomer fraction information and phase equilibria data in mixtures with alkanes. |
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