Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity
The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an...
Ausführliche Beschreibung
Autor*in: |
Plaza, A. [verfasserIn] |
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Englisch |
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2013transfer abstract |
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12 |
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Enthalten in: Steering charge kinetics in W - Yue, Xin-Zheng ELSEVIER, 2019, the official journal of the North American Membrane Society, New York, NY [u.a.] |
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Übergeordnetes Werk: |
volume:444 ; year:2013 ; day:1 ; month:10 ; pages:201-212 ; extent:12 |
Links: |
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DOI / URN: |
10.1016/j.memsci.2013.04.034 |
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Katalog-ID: |
ELV033112770 |
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245 | 1 | 0 | |a Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity |
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520 | |a The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. | ||
520 | |a The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. | ||
650 | 7 | |a Supported liquid membranes |2 Elsevier | |
650 | 7 | |a Butanol |2 Elsevier | |
650 | 7 | |a Gelled ionic liquid |2 Elsevier | |
650 | 7 | |a Mass transfer |2 Elsevier | |
650 | 7 | |a Pervaporation |2 Elsevier | |
700 | 1 | |a Merlet, G. |4 oth | |
700 | 1 | |a Hasanoglu, A. |4 oth | |
700 | 1 | |a Isaacs, M. |4 oth | |
700 | 1 | |a Sanchez, J. |4 oth | |
700 | 1 | |a Romero, J. |4 oth | |
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10.1016/j.memsci.2013.04.034 doi GBVA2013012000001.pica (DE-627)ELV033112770 (ELSEVIER)S0376-7388(13)00314-1 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Plaza, A. verfasserin aut Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity 2013transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. Supported liquid membranes Elsevier Butanol Elsevier Gelled ionic liquid Elsevier Mass transfer Elsevier Pervaporation Elsevier Merlet, G. oth Hasanoglu, A. oth Isaacs, M. oth Sanchez, J. oth Romero, J. oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:444 year:2013 day:1 month:10 pages:201-212 extent:12 https://doi.org/10.1016/j.memsci.2013.04.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 444 2013 1 1001 201-212 12 045F 570 |
spelling |
10.1016/j.memsci.2013.04.034 doi GBVA2013012000001.pica (DE-627)ELV033112770 (ELSEVIER)S0376-7388(13)00314-1 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Plaza, A. verfasserin aut Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity 2013transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. Supported liquid membranes Elsevier Butanol Elsevier Gelled ionic liquid Elsevier Mass transfer Elsevier Pervaporation Elsevier Merlet, G. oth Hasanoglu, A. oth Isaacs, M. oth Sanchez, J. oth Romero, J. oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:444 year:2013 day:1 month:10 pages:201-212 extent:12 https://doi.org/10.1016/j.memsci.2013.04.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 444 2013 1 1001 201-212 12 045F 570 |
allfields_unstemmed |
10.1016/j.memsci.2013.04.034 doi GBVA2013012000001.pica (DE-627)ELV033112770 (ELSEVIER)S0376-7388(13)00314-1 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Plaza, A. verfasserin aut Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity 2013transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. Supported liquid membranes Elsevier Butanol Elsevier Gelled ionic liquid Elsevier Mass transfer Elsevier Pervaporation Elsevier Merlet, G. oth Hasanoglu, A. oth Isaacs, M. oth Sanchez, J. oth Romero, J. oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:444 year:2013 day:1 month:10 pages:201-212 extent:12 https://doi.org/10.1016/j.memsci.2013.04.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 444 2013 1 1001 201-212 12 045F 570 |
allfieldsGer |
10.1016/j.memsci.2013.04.034 doi GBVA2013012000001.pica (DE-627)ELV033112770 (ELSEVIER)S0376-7388(13)00314-1 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Plaza, A. verfasserin aut Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity 2013transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. Supported liquid membranes Elsevier Butanol Elsevier Gelled ionic liquid Elsevier Mass transfer Elsevier Pervaporation Elsevier Merlet, G. oth Hasanoglu, A. oth Isaacs, M. oth Sanchez, J. oth Romero, J. oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:444 year:2013 day:1 month:10 pages:201-212 extent:12 https://doi.org/10.1016/j.memsci.2013.04.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 444 2013 1 1001 201-212 12 045F 570 |
allfieldsSound |
10.1016/j.memsci.2013.04.034 doi GBVA2013012000001.pica (DE-627)ELV033112770 (ELSEVIER)S0376-7388(13)00314-1 DE-627 ger DE-627 rakwb eng 570 570 DE-600 540 VZ 35.17 bkl 58.50 bkl 43.12 bkl Plaza, A. verfasserin aut Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity 2013transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. Supported liquid membranes Elsevier Butanol Elsevier Gelled ionic liquid Elsevier Mass transfer Elsevier Pervaporation Elsevier Merlet, G. oth Hasanoglu, A. oth Isaacs, M. oth Sanchez, J. oth Romero, J. oth Enthalten in Elsevier Yue, Xin-Zheng ELSEVIER Steering charge kinetics in W 2019 the official journal of the North American Membrane Society New York, NY [u.a.] (DE-627)ELV002478420 volume:444 year:2013 day:1 month:10 pages:201-212 extent:12 https://doi.org/10.1016/j.memsci.2013.04.034 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 35.17 Katalyse VZ 58.50 Umwelttechnik: Allgemeines VZ 43.12 Umweltchemie VZ AR 444 2013 1 1001 201-212 12 045F 570 |
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Enthalten in Steering charge kinetics in W New York, NY [u.a.] volume:444 year:2013 day:1 month:10 pages:201-212 extent:12 |
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Enthalten in Steering charge kinetics in W New York, NY [u.a.] volume:444 year:2013 day:1 month:10 pages:201-212 extent:12 |
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Supported liquid membranes Butanol Gelled ionic liquid Mass transfer Pervaporation |
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Steering charge kinetics in W |
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separation of butanol from abe mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: analysis of transport phenomena and selectivity |
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Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity |
abstract |
The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. |
abstractGer |
The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. |
abstract_unstemmed |
The separation of acetone–butanol–ethanol mixtures (ABE) from aqueous solutions, which are produced in ABE fermentation processes, is carried out by sweep gas pervaporation using gelled supported ionic liquid membranes and by membrane evaporation. The membranes were synthesized by the gelation of an ionic liquid ([bmim][PF6]) into the porosity of polytetrafluoroethylene (PTFE) hollow fibers. The performance of the membranes used in sweep gas pervaporation is compared with the membrane evaporation process using the same hollow fiber support without IL in order to verify the selectivity contributed by the gelled ionic liquid gap formed in the membrane pores. Improved butanol/ethanol selectivity was verified for gelled IL membranes in pervaporation experiments compared to the evaporation process. A resistance-in-series model was developed to simulate the pervaporation process. The model predictions were in good agreement with the experimental results. IL membranes are found to have potential for separation of butanol from the ABE mixtures by pervaporation. |
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Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity |
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