Competitive sorption between 17α-ethinyl estradiol and bisphenol A/4-n-nonylphenol by soils
The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundl...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Li, Jianzhong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2013transfer abstract |
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| Schlagwörter: |
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| Umfang: |
10 |
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| Übergeordnetes Werk: |
Enthalten in: The development of a computational platform to design and simulate on-board hydrogen storage systems - Mazzucco, Andrea ELSEVIER, 2017transfer abstract, [Amsterdam] |
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| Übergeordnetes Werk: |
volume:25 ; year:2013 ; number:6 ; day:1 ; month:06 ; pages:1154-1163 ; extent:10 |
| Links: |
|---|
| DOI / URN: |
10.1016/S1001-0742(12)60165-X |
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| 520 | |a The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. | ||
| 520 | |a The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. | ||
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| 700 | 1 | |a Xiang, Xi |4 oth | |
| 700 | 1 | |a Xu, Shuang |4 oth | |
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| 700 | 1 | |a Liu, Xiang |4 oth | |
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10.1016/S1001-0742(12)60165-X doi GBVA2013016000028.pica (DE-627)ELV033347735 (ELSEVIER)S1001-0742(12)60165-X DE-627 ger DE-627 rakwb eng 690 690 DE-600 660 VZ 620 VZ 610 VZ 44.94 bkl Li, Jianzhong verfasserin aut Competitive sorption between 17α-ethinyl estradiol and bisphenol A/4-n-nonylphenol by soils 2013transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. endocrine-disrupting chemicals Elsevier distributed reactivity model Elsevier black carbon Elsevier 17α-ethinyl estradiol Elsevier competitive sorption Elsevier Jiang, Lu oth Xiang, Xi oth Xu, Shuang oth Wen, Rou oth Liu, Xiang oth Enthalten in Elsevier Mazzucco, Andrea ELSEVIER The development of a computational platform to design and simulate on-board hydrogen storage systems 2017transfer abstract [Amsterdam] (DE-627)ELV015065863 volume:25 year:2013 number:6 day:1 month:06 pages:1154-1163 extent:10 https://doi.org/10.1016/S1001-0742(12)60165-X Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_40 GBV_ILN_70 GBV_ILN_252 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 25 2013 6 1 0601 1154-1163 10 045F 690 |
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10.1016/S1001-0742(12)60165-X doi GBVA2013016000028.pica (DE-627)ELV033347735 (ELSEVIER)S1001-0742(12)60165-X DE-627 ger DE-627 rakwb eng 690 690 DE-600 660 VZ 620 VZ 610 VZ 44.94 bkl Li, Jianzhong verfasserin aut Competitive sorption between 17α-ethinyl estradiol and bisphenol A/4-n-nonylphenol by soils 2013transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. endocrine-disrupting chemicals Elsevier distributed reactivity model Elsevier black carbon Elsevier 17α-ethinyl estradiol Elsevier competitive sorption Elsevier Jiang, Lu oth Xiang, Xi oth Xu, Shuang oth Wen, Rou oth Liu, Xiang oth Enthalten in Elsevier Mazzucco, Andrea ELSEVIER The development of a computational platform to design and simulate on-board hydrogen storage systems 2017transfer abstract [Amsterdam] (DE-627)ELV015065863 volume:25 year:2013 number:6 day:1 month:06 pages:1154-1163 extent:10 https://doi.org/10.1016/S1001-0742(12)60165-X Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_40 GBV_ILN_70 GBV_ILN_252 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 25 2013 6 1 0601 1154-1163 10 045F 690 |
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10.1016/S1001-0742(12)60165-X doi GBVA2013016000028.pica (DE-627)ELV033347735 (ELSEVIER)S1001-0742(12)60165-X DE-627 ger DE-627 rakwb eng 690 690 DE-600 660 VZ 620 VZ 610 VZ 44.94 bkl Li, Jianzhong verfasserin aut Competitive sorption between 17α-ethinyl estradiol and bisphenol A/4-n-nonylphenol by soils 2013transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. endocrine-disrupting chemicals Elsevier distributed reactivity model Elsevier black carbon Elsevier 17α-ethinyl estradiol Elsevier competitive sorption Elsevier Jiang, Lu oth Xiang, Xi oth Xu, Shuang oth Wen, Rou oth Liu, Xiang oth Enthalten in Elsevier Mazzucco, Andrea ELSEVIER The development of a computational platform to design and simulate on-board hydrogen storage systems 2017transfer abstract [Amsterdam] (DE-627)ELV015065863 volume:25 year:2013 number:6 day:1 month:06 pages:1154-1163 extent:10 https://doi.org/10.1016/S1001-0742(12)60165-X Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_40 GBV_ILN_70 GBV_ILN_252 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 25 2013 6 1 0601 1154-1163 10 045F 690 |
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10.1016/S1001-0742(12)60165-X doi GBVA2013016000028.pica (DE-627)ELV033347735 (ELSEVIER)S1001-0742(12)60165-X DE-627 ger DE-627 rakwb eng 690 690 DE-600 660 VZ 620 VZ 610 VZ 44.94 bkl Li, Jianzhong verfasserin aut Competitive sorption between 17α-ethinyl estradiol and bisphenol A/4-n-nonylphenol by soils 2013transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. endocrine-disrupting chemicals Elsevier distributed reactivity model Elsevier black carbon Elsevier 17α-ethinyl estradiol Elsevier competitive sorption Elsevier Jiang, Lu oth Xiang, Xi oth Xu, Shuang oth Wen, Rou oth Liu, Xiang oth Enthalten in Elsevier Mazzucco, Andrea ELSEVIER The development of a computational platform to design and simulate on-board hydrogen storage systems 2017transfer abstract [Amsterdam] (DE-627)ELV015065863 volume:25 year:2013 number:6 day:1 month:06 pages:1154-1163 extent:10 https://doi.org/10.1016/S1001-0742(12)60165-X Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_40 GBV_ILN_70 GBV_ILN_252 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 25 2013 6 1 0601 1154-1163 10 045F 690 |
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10.1016/S1001-0742(12)60165-X doi GBVA2013016000028.pica (DE-627)ELV033347735 (ELSEVIER)S1001-0742(12)60165-X DE-627 ger DE-627 rakwb eng 690 690 DE-600 660 VZ 620 VZ 610 VZ 44.94 bkl Li, Jianzhong verfasserin aut Competitive sorption between 17α-ethinyl estradiol and bisphenol A/4-n-nonylphenol by soils 2013transfer abstract 10 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. endocrine-disrupting chemicals Elsevier distributed reactivity model Elsevier black carbon Elsevier 17α-ethinyl estradiol Elsevier competitive sorption Elsevier Jiang, Lu oth Xiang, Xi oth Xu, Shuang oth Wen, Rou oth Liu, Xiang oth Enthalten in Elsevier Mazzucco, Andrea ELSEVIER The development of a computational platform to design and simulate on-board hydrogen storage systems 2017transfer abstract [Amsterdam] (DE-627)ELV015065863 volume:25 year:2013 number:6 day:1 month:06 pages:1154-1163 extent:10 https://doi.org/10.1016/S1001-0742(12)60165-X Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_24 GBV_ILN_40 GBV_ILN_70 GBV_ILN_252 44.94 Hals-Nasen-Ohrenheilkunde VZ AR 25 2013 6 1 0601 1154-1163 10 045F 690 |
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competitive sorption between 17α-ethinyl estradiol and bisphenol a/4-n-nonylphenol by soils |
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Competitive sorption between 17α-ethinyl estradiol and bisphenol A/4-n-nonylphenol by soils |
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The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. |
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The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. |
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The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes. |
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Competitive sorption between 17α-ethinyl estradiol and bisphenol A/4-n-nonylphenol by soils |
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Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The sorption of 17α-ethinyl estradiol (EE2), bisphenol A (BPA), and 4-n-nonylphenol (NP) in single systems and the sorption of EE2 with different initial aqueous concentrations of BPA or NP were examined using three soils. Results showed that all sorption isotherms were nonlinear and fit the Freundlich model. The degree of nonlinearity was in the order BPA (0.537–0.686) > EE2 (0.705–0.858) > NP (0.875–0.0.951) in single systems. The isotherm linearity index of EE2 sorption calculated by the Freundlich model for Loam, Silt Loam and Silt increased from 0.758, 0.705 and 0.858, to 0.889, 0.910 and 0.969, respectively, when BPA concentration increased from 0 to 1000 μg/L, but the effect of NP was comparably minimal. Additionally, EE2 significantly suppressed the sorption of BPA, but insignificantly suppressed that of NP. These findings can be attributed to the difference of sorption affinity of EE2, NP and BPA on the hard carbon (e.g., black carbon) of soil organic matter that dominated the sorption in the low equilibrium aqueous concentration range of endocrine-disrupting chemicals (EDCs). Competitive sorption among EDCs presents new challenges for predicting the transport and fate of EDCs under the influence of co-solutes.</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">endocrine-disrupting chemicals</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">distributed reactivity model</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">black carbon</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">17α-ethinyl estradiol</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">competitive sorption</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Jiang, Lu</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xiang, Xi</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xu, Shuang</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wen, Rou</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Liu, Xiang</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="n">Elsevier</subfield><subfield code="a">Mazzucco, Andrea ELSEVIER</subfield><subfield code="t">The development of a computational platform to design and simulate on-board hydrogen storage systems</subfield><subfield code="d">2017transfer abstract</subfield><subfield code="g">[Amsterdam]</subfield><subfield code="w">(DE-627)ELV015065863</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:25</subfield><subfield code="g">year:2013</subfield><subfield code="g">number:6</subfield><subfield code="g">day:1</subfield><subfield code="g">month:06</subfield><subfield code="g">pages:1154-1163</subfield><subfield code="g">extent:10</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1016/S1001-0742(12)60165-X</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_252</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">44.94</subfield><subfield code="j">Hals-Nasen-Ohrenheilkunde</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">25</subfield><subfield code="j">2013</subfield><subfield code="e">6</subfield><subfield code="b">1</subfield><subfield code="c">0601</subfield><subfield code="h">1154-1163</subfield><subfield code="g">10</subfield></datafield><datafield tag="953" ind1=" " ind2=" "><subfield code="2">045F</subfield><subfield code="a">690</subfield></datafield></record></collection>
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