Transformation and removal of arsenic in groundwater by sequential anodic oxidation and electrocoagulation
Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequ...
Ausführliche Beschreibung
Autor*in: |
Zhang, Peng [verfasserIn] |
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Sprache: |
Englisch |
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2014transfer abstract |
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9 |
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Übergeordnetes Werk: |
Enthalten in: Coffee’s country of origin determined by NMR: The Colombian case - Arana, V.A. ELSEVIER, 2015, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:164 ; year:2014 ; pages:299-307 ; extent:9 |
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DOI / URN: |
10.1016/j.jconhyd.2014.06.009 |
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520 | |a Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. | ||
520 | |a Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. | ||
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700 | 1 | |a Yuan, Songhu |4 oth | |
700 | 1 | |a Liao, Peng |4 oth | |
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10.1016/j.jconhyd.2014.06.009 doi GBVA2014006000016.pica (DE-627)ELV033765308 (ELSEVIER)S0169-7722(14)00092-8 DE-627 ger DE-627 rakwb eng 550 550 DE-600 540 VZ 660 VZ 540 VZ 35.00 bkl Zhang, Peng verfasserin aut Transformation and removal of arsenic in groundwater by sequential anodic oxidation and electrocoagulation 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Tong, Man oth Yuan, Songhu oth Liao, Peng oth Enthalten in Elsevier Science Arana, V.A. ELSEVIER Coffee’s country of origin determined by NMR: The Colombian case 2015 Amsterdam [u.a.] (DE-627)ELV01298082X volume:164 year:2014 pages:299-307 extent:9 https://doi.org/10.1016/j.jconhyd.2014.06.009 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_179 35.00 Chemie: Allgemeines VZ AR 164 2014 299-307 9 045F 550 |
spelling |
10.1016/j.jconhyd.2014.06.009 doi GBVA2014006000016.pica (DE-627)ELV033765308 (ELSEVIER)S0169-7722(14)00092-8 DE-627 ger DE-627 rakwb eng 550 550 DE-600 540 VZ 660 VZ 540 VZ 35.00 bkl Zhang, Peng verfasserin aut Transformation and removal of arsenic in groundwater by sequential anodic oxidation and electrocoagulation 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Tong, Man oth Yuan, Songhu oth Liao, Peng oth Enthalten in Elsevier Science Arana, V.A. ELSEVIER Coffee’s country of origin determined by NMR: The Colombian case 2015 Amsterdam [u.a.] (DE-627)ELV01298082X volume:164 year:2014 pages:299-307 extent:9 https://doi.org/10.1016/j.jconhyd.2014.06.009 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_179 35.00 Chemie: Allgemeines VZ AR 164 2014 299-307 9 045F 550 |
allfields_unstemmed |
10.1016/j.jconhyd.2014.06.009 doi GBVA2014006000016.pica (DE-627)ELV033765308 (ELSEVIER)S0169-7722(14)00092-8 DE-627 ger DE-627 rakwb eng 550 550 DE-600 540 VZ 660 VZ 540 VZ 35.00 bkl Zhang, Peng verfasserin aut Transformation and removal of arsenic in groundwater by sequential anodic oxidation and electrocoagulation 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Tong, Man oth Yuan, Songhu oth Liao, Peng oth Enthalten in Elsevier Science Arana, V.A. ELSEVIER Coffee’s country of origin determined by NMR: The Colombian case 2015 Amsterdam [u.a.] (DE-627)ELV01298082X volume:164 year:2014 pages:299-307 extent:9 https://doi.org/10.1016/j.jconhyd.2014.06.009 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_179 35.00 Chemie: Allgemeines VZ AR 164 2014 299-307 9 045F 550 |
allfieldsGer |
10.1016/j.jconhyd.2014.06.009 doi GBVA2014006000016.pica (DE-627)ELV033765308 (ELSEVIER)S0169-7722(14)00092-8 DE-627 ger DE-627 rakwb eng 550 550 DE-600 540 VZ 660 VZ 540 VZ 35.00 bkl Zhang, Peng verfasserin aut Transformation and removal of arsenic in groundwater by sequential anodic oxidation and electrocoagulation 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Tong, Man oth Yuan, Songhu oth Liao, Peng oth Enthalten in Elsevier Science Arana, V.A. ELSEVIER Coffee’s country of origin determined by NMR: The Colombian case 2015 Amsterdam [u.a.] (DE-627)ELV01298082X volume:164 year:2014 pages:299-307 extent:9 https://doi.org/10.1016/j.jconhyd.2014.06.009 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_179 35.00 Chemie: Allgemeines VZ AR 164 2014 299-307 9 045F 550 |
allfieldsSound |
10.1016/j.jconhyd.2014.06.009 doi GBVA2014006000016.pica (DE-627)ELV033765308 (ELSEVIER)S0169-7722(14)00092-8 DE-627 ger DE-627 rakwb eng 550 550 DE-600 540 VZ 660 VZ 540 VZ 35.00 bkl Zhang, Peng verfasserin aut Transformation and removal of arsenic in groundwater by sequential anodic oxidation and electrocoagulation 2014transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. Tong, Man oth Yuan, Songhu oth Liao, Peng oth Enthalten in Elsevier Science Arana, V.A. ELSEVIER Coffee’s country of origin determined by NMR: The Colombian case 2015 Amsterdam [u.a.] (DE-627)ELV01298082X volume:164 year:2014 pages:299-307 extent:9 https://doi.org/10.1016/j.jconhyd.2014.06.009 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 GBV_ILN_179 35.00 Chemie: Allgemeines VZ AR 164 2014 299-307 9 045F 550 |
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The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. 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transformation and removal of arsenic in groundwater by sequential anodic oxidation and electrocoagulation |
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Transformation and removal of arsenic in groundwater by sequential anodic oxidation and electrocoagulation |
abstract |
Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. |
abstractGer |
Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. |
abstract_unstemmed |
Oxidation of As(III) to As(V) is generally essential for the efficient remediation of As(III)-contaminated groundwater. The performance and mechanisms of As(III) oxidation by an as-synthesized active anode, SnO2 loaded onto Ti-based TiO2 nanotubes (Ti/TiO2NTs/Sb–SnO2), were investigated. The subsequent removal of total arsenic by electrocoagulation (EC) was further tested. The Ti/TiO2NTs/Sb-SnO2 anode showed a high and lasting electrochemical activity for As(III) oxidation. 6.67μM As(III) in synthetic groundwater was completely oxidized to As(V) within 60min at 50mA. Direct electron transfer was mainly responsible at the current below 30mA, while hydroxyl radicals contributed increasingly with the increase in the current above 30mA. As(III) oxidation was moderately inhibited by the presence of bicarbonate (20mM), while was dramatically increased with increasing the concentration of chloride (0–10mM). After the complete oxidation of As(III) to As(V), total arsenic was efficiently removed by EC in the same reactor by reversing electrode polarity. The removal efficiency increased with increasing the current but decreased by the presence of phosphate and silica. Anodic oxidation represents an effective pretreatment approach to increasing EC removal of As(III) in groundwater under O2-limited conditions. |
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Transformation and removal of arsenic in groundwater by sequential anodic oxidation and electrocoagulation |
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https://doi.org/10.1016/j.jconhyd.2014.06.009 |
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