High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)

Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Qi, Zhi [verfasserIn] Zhang, Wenchao He, Xiangdong Yang, Rongjie

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2016transfer abstract

Schlagwörter:	Nano composites Functional composites Polymer-matrix composites

Umfang:	12

Übergeordnetes Werk:	Enthalten in: No title available - an international journal, Amsterdam [u.a.]
Übergeordnetes Werk:	volume:127 ; year:2016 ; day:28 ; month:04 ; pages:8-19 ; extent:12

Links:	Volltext

DOI / URN:	10.1016/j.compscitech.2016.02.026

Katalog-ID:	ELV035220937

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520			\|a Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs.
520			\|a Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs.
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700	1		\|a He, Xiangdong \|4 oth
700	1		\|a Yang, Rongjie \|4 oth
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allfields	10.1016/j.compscitech.2016.02.026 doi GBVA2016008000023.pica (DE-627)ELV035220937 (ELSEVIER)S0266-3538(16)30068-9 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 Qi, Zhi verfasserin aut High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) 2016transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Nano composites Elsevier Functional composites Elsevier Polymer-matrix composites Elsevier Zhang, Wenchao oth He, Xiangdong oth Yang, Rongjie oth Enthalten in Elsevier No title available an international journal Amsterdam [u.a.] (DE-627)ELV013958402 nnns volume:127 year:2016 day:28 month:04 pages:8-19 extent:12 https://doi.org/10.1016/j.compscitech.2016.02.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_40 AR 127 2016 28 0428 8-19 12 045F 660
spelling	10.1016/j.compscitech.2016.02.026 doi GBVA2016008000023.pica (DE-627)ELV035220937 (ELSEVIER)S0266-3538(16)30068-9 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 Qi, Zhi verfasserin aut High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) 2016transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Nano composites Elsevier Functional composites Elsevier Polymer-matrix composites Elsevier Zhang, Wenchao oth He, Xiangdong oth Yang, Rongjie oth Enthalten in Elsevier No title available an international journal Amsterdam [u.a.] (DE-627)ELV013958402 nnns volume:127 year:2016 day:28 month:04 pages:8-19 extent:12 https://doi.org/10.1016/j.compscitech.2016.02.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_40 AR 127 2016 28 0428 8-19 12 045F 660
allfields_unstemmed	10.1016/j.compscitech.2016.02.026 doi GBVA2016008000023.pica (DE-627)ELV035220937 (ELSEVIER)S0266-3538(16)30068-9 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 Qi, Zhi verfasserin aut High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) 2016transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Nano composites Elsevier Functional composites Elsevier Polymer-matrix composites Elsevier Zhang, Wenchao oth He, Xiangdong oth Yang, Rongjie oth Enthalten in Elsevier No title available an international journal Amsterdam [u.a.] (DE-627)ELV013958402 nnns volume:127 year:2016 day:28 month:04 pages:8-19 extent:12 https://doi.org/10.1016/j.compscitech.2016.02.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_40 AR 127 2016 28 0428 8-19 12 045F 660
allfieldsGer	10.1016/j.compscitech.2016.02.026 doi GBVA2016008000023.pica (DE-627)ELV035220937 (ELSEVIER)S0266-3538(16)30068-9 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 Qi, Zhi verfasserin aut High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) 2016transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Nano composites Elsevier Functional composites Elsevier Polymer-matrix composites Elsevier Zhang, Wenchao oth He, Xiangdong oth Yang, Rongjie oth Enthalten in Elsevier No title available an international journal Amsterdam [u.a.] (DE-627)ELV013958402 nnns volume:127 year:2016 day:28 month:04 pages:8-19 extent:12 https://doi.org/10.1016/j.compscitech.2016.02.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_40 AR 127 2016 28 0428 8-19 12 045F 660
allfieldsSound	10.1016/j.compscitech.2016.02.026 doi GBVA2016008000023.pica (DE-627)ELV035220937 (ELSEVIER)S0266-3538(16)30068-9 DE-627 ger DE-627 rakwb eng 660 670 660 DE-600 670 DE-600 Qi, Zhi verfasserin aut High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) 2016transfer abstract 12 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs. Nano composites Elsevier Functional composites Elsevier Polymer-matrix composites Elsevier Zhang, Wenchao oth He, Xiangdong oth Yang, Rongjie oth Enthalten in Elsevier No title available an international journal Amsterdam [u.a.] (DE-627)ELV013958402 nnns volume:127 year:2016 day:28 month:04 pages:8-19 extent:12 https://doi.org/10.1016/j.compscitech.2016.02.026 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_40 AR 127 2016 28 0428 8-19 12 045F 660
language	English
source	Enthalten in No title available Amsterdam [u.a.] volume:127 year:2016 day:28 month:04 pages:8-19 extent:12
sourceStr	Enthalten in No title available Amsterdam [u.a.] volume:127 year:2016 day:28 month:04 pages:8-19 extent:12
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Nano composites Functional composites Polymer-matrix composites
dewey-raw	660
isfreeaccess_bool	false
container_title	No title available
authorswithroles_txt_mv	Qi, Zhi @@aut@@ Zhang, Wenchao @@oth@@ He, Xiangdong @@oth@@ Yang, Rongjie @@oth@@
publishDateDaySort_date	2016-01-28T00:00:00Z
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Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. 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author	Qi, Zhi
spellingShingle	Qi, Zhi ddc 660 ddc 670 Elsevier Nano composites Elsevier Functional composites Elsevier Polymer-matrix composites High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)
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topic_title	660 670 660 DE-600 670 DE-600 High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) Nano composites Elsevier Functional composites Elsevier Polymer-matrix composites Elsevier
topic	ddc 660 ddc 670 Elsevier Nano composites Elsevier Functional composites Elsevier Polymer-matrix composites
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title	High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)
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title_full	High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)
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title_sort	high-efficiency flame retardency of epoxy resin composites with perfect t8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (p-posss)
title_auth	High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)
abstract	Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs.
abstractGer	Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs.
abstract_unstemmed	Phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) of perfect T8 caged structures was designed as a new class of flame retardant. Phosphorus containing POSS combine several advantages from phosphorus based flame retardant and nanostructure inorganic-organic hybrid materials. Three phosphorus containing POSSs were synthesized by the addition reaction of octa vinyl POSS with diphenylphosphine (DPP), diphenylphosphine oxide (DPOP), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), respectively. The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardant performance and mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed in detail based on TGA-FTIR, XPS, and FTIR. The main flame retardant activity of DPP-POSS, DPOP-POSS, and DOPO-POSS are in the especially strong condensed phase activity through charring and intumescence due to the synergistic between phosphorus and silicon in these POSSs.
collection_details	GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_40
title_short	High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)
url	https://doi.org/10.1016/j.compscitech.2016.02.026
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author2	Zhang, Wenchao He, Xiangdong Yang, Rongjie
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up_date	2024-07-06T17:00:09.286Z
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