Fast magic-angle sample spinning solid-state NMR at 60–100kHz for natural abundance samples
In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resoluti...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Nishiyama, Yusuke [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016transfer abstract |
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| Schlagwörter: |
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| Umfang: |
13 |
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| Übergeordnetes Werk: |
Enthalten in: A high-speed, flexible-scanning chemical imaging system using a light-addressable potentiometric sensor integrated with an analog micromirror - Das, Anirban ELSEVIER, 2014, an international journal, Orlando, Fla |
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| Übergeordnetes Werk: |
volume:78 ; year:2016 ; pages:24-36 ; extent:13 |
| Links: |
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| DOI / URN: |
10.1016/j.ssnmr.2016.06.002 |
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| 520 | |a In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. | ||
| 520 | |a In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. | ||
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| 650 | 7 | |a Large anisotropy |2 Elsevier | |
| 650 | 7 | |a Ultrafast MAS |2 Elsevier | |
| 650 | 7 | |a 1H NMR |2 Elsevier | |
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10.1016/j.ssnmr.2016.06.002 doi GBVA2016015000018.pica (DE-627)ELV035410736 (ELSEVIER)S0926-2040(16)30047-9 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 610 VZ 44.91 bkl Nishiyama, Yusuke verfasserin aut Fast magic-angle sample spinning solid-state NMR at 60–100kHz for natural abundance samples 2016transfer abstract 13 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. Solid-state NMR Elsevier Natural abundance Elsevier 1H inverse detection Elsevier Fast MAS Elsevier Large anisotropy Elsevier Ultrafast MAS Elsevier 1H NMR Elsevier Enthalten in Academic Press Das, Anirban ELSEVIER A high-speed, flexible-scanning chemical imaging system using a light-addressable potentiometric sensor integrated with an analog micromirror 2014 an international journal Orlando, Fla (DE-627)ELV012450979 volume:78 year:2016 pages:24-36 extent:13 https://doi.org/10.1016/j.ssnmr.2016.06.002 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 44.91 Psychiatrie Psychopathologie VZ AR 78 2016 24-36 13 045F 540 |
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10.1016/j.ssnmr.2016.06.002 doi GBVA2016015000018.pica (DE-627)ELV035410736 (ELSEVIER)S0926-2040(16)30047-9 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 610 VZ 44.91 bkl Nishiyama, Yusuke verfasserin aut Fast magic-angle sample spinning solid-state NMR at 60–100kHz for natural abundance samples 2016transfer abstract 13 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. Solid-state NMR Elsevier Natural abundance Elsevier 1H inverse detection Elsevier Fast MAS Elsevier Large anisotropy Elsevier Ultrafast MAS Elsevier 1H NMR Elsevier Enthalten in Academic Press Das, Anirban ELSEVIER A high-speed, flexible-scanning chemical imaging system using a light-addressable potentiometric sensor integrated with an analog micromirror 2014 an international journal Orlando, Fla (DE-627)ELV012450979 volume:78 year:2016 pages:24-36 extent:13 https://doi.org/10.1016/j.ssnmr.2016.06.002 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 44.91 Psychiatrie Psychopathologie VZ AR 78 2016 24-36 13 045F 540 |
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10.1016/j.ssnmr.2016.06.002 doi GBVA2016015000018.pica (DE-627)ELV035410736 (ELSEVIER)S0926-2040(16)30047-9 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 610 VZ 44.91 bkl Nishiyama, Yusuke verfasserin aut Fast magic-angle sample spinning solid-state NMR at 60–100kHz for natural abundance samples 2016transfer abstract 13 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. Solid-state NMR Elsevier Natural abundance Elsevier 1H inverse detection Elsevier Fast MAS Elsevier Large anisotropy Elsevier Ultrafast MAS Elsevier 1H NMR Elsevier Enthalten in Academic Press Das, Anirban ELSEVIER A high-speed, flexible-scanning chemical imaging system using a light-addressable potentiometric sensor integrated with an analog micromirror 2014 an international journal Orlando, Fla (DE-627)ELV012450979 volume:78 year:2016 pages:24-36 extent:13 https://doi.org/10.1016/j.ssnmr.2016.06.002 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 44.91 Psychiatrie Psychopathologie VZ AR 78 2016 24-36 13 045F 540 |
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10.1016/j.ssnmr.2016.06.002 doi GBVA2016015000018.pica (DE-627)ELV035410736 (ELSEVIER)S0926-2040(16)30047-9 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 610 VZ 44.91 bkl Nishiyama, Yusuke verfasserin aut Fast magic-angle sample spinning solid-state NMR at 60–100kHz for natural abundance samples 2016transfer abstract 13 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. Solid-state NMR Elsevier Natural abundance Elsevier 1H inverse detection Elsevier Fast MAS Elsevier Large anisotropy Elsevier Ultrafast MAS Elsevier 1H NMR Elsevier Enthalten in Academic Press Das, Anirban ELSEVIER A high-speed, flexible-scanning chemical imaging system using a light-addressable potentiometric sensor integrated with an analog micromirror 2014 an international journal Orlando, Fla (DE-627)ELV012450979 volume:78 year:2016 pages:24-36 extent:13 https://doi.org/10.1016/j.ssnmr.2016.06.002 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 44.91 Psychiatrie Psychopathologie VZ AR 78 2016 24-36 13 045F 540 |
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10.1016/j.ssnmr.2016.06.002 doi GBVA2016015000018.pica (DE-627)ELV035410736 (ELSEVIER)S0926-2040(16)30047-9 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 610 VZ 44.91 bkl Nishiyama, Yusuke verfasserin aut Fast magic-angle sample spinning solid-state NMR at 60–100kHz for natural abundance samples 2016transfer abstract 13 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. Solid-state NMR Elsevier Natural abundance Elsevier 1H inverse detection Elsevier Fast MAS Elsevier Large anisotropy Elsevier Ultrafast MAS Elsevier 1H NMR Elsevier Enthalten in Academic Press Das, Anirban ELSEVIER A high-speed, flexible-scanning chemical imaging system using a light-addressable potentiometric sensor integrated with an analog micromirror 2014 an international journal Orlando, Fla (DE-627)ELV012450979 volume:78 year:2016 pages:24-36 extent:13 https://doi.org/10.1016/j.ssnmr.2016.06.002 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_40 44.91 Psychiatrie Psychopathologie VZ AR 78 2016 24-36 13 045F 540 |
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Enthalten in A high-speed, flexible-scanning chemical imaging system using a light-addressable potentiometric sensor integrated with an analog micromirror Orlando, Fla volume:78 year:2016 pages:24-36 extent:13 |
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The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. 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Fast magic-angle sample spinning solid-state NMR at 60–100kHz for natural abundance samples |
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In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. |
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In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. |
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In spite of tremendous progress made in pulse sequence designs and sophisticated hardware developments, methods to improve sensitivity and resolution in solid-state NMR (ssNMR) are still emerging. The rate at which sample is spun at magic angle determines the extent to which sensitivity and resolution of NMR spectra are improved. To this end, the prime objective of this article is to give a comprehensive theoretical and experimental framework of fast magic angle spinning (MAS) technique. The engineering design of fast MAS rotors based on spinning rate, sample volume, and sensitivity is presented in detail. Besides, the benefits of fast MAS citing the recent progress in methodology, especially for natural abundance samples are also highlighted. The effect of the MAS rate on 1H resolution, which is a key to the success of the 1H inverse detection methods, is described by a simple mathematical factor named as the homogeneity factor k. A comparison between various 1H inverse detection methods is also presented. Moreover, methods to reduce the number of spinning sidebands (SSBs) for the systems with huge anisotropies in combination with 1H inverse detection at fast MAS are discussed. |
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