Perspectives on DNP-enhanced NMR spectroscopy in solutions
More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and per...
Ausführliche Beschreibung
Autor*in: |
van Bentum, Jan [verfasserIn] |
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Englisch |
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2016transfer abstract |
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9 |
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Übergeordnetes Werk: |
Enthalten in: Response letter - Hiranaka, Takaaki ELSEVIER, 2021, JMR, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:264 ; year:2016 ; pages:59-67 ; extent:9 |
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DOI / URN: |
10.1016/j.jmr.2016.01.010 |
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520 | |a More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. | ||
520 | |a More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. | ||
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10.1016/j.jmr.2016.01.010 doi GBVA2016019000007.pica (DE-627)ELV035504234 (ELSEVIER)S1090-7807(16)00051-3 DE-627 ger DE-627 rakwb eng 550 530 550 DE-600 530 DE-600 610 VZ 44.83 bkl van Bentum, Jan verfasserin aut Perspectives on DNP-enhanced NMR spectroscopy in solutions 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. Supercritical solvent Elsevier Liquid state DNP Elsevier Rapid melt DNP Elsevier Overhauser Elsevier van Meerten, Bas oth Sharma, Manvendra oth Kentgens, Arno oth Enthalten in Elsevier Hiranaka, Takaaki ELSEVIER Response letter 2021 JMR Amsterdam [u.a.] (DE-627)ELV005993725 volume:264 year:2016 pages:59-67 extent:9 https://doi.org/10.1016/j.jmr.2016.01.010 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.83 Rheumatologie Orthopädie VZ AR 264 2016 59-67 9 045F 550 |
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10.1016/j.jmr.2016.01.010 doi GBVA2016019000007.pica (DE-627)ELV035504234 (ELSEVIER)S1090-7807(16)00051-3 DE-627 ger DE-627 rakwb eng 550 530 550 DE-600 530 DE-600 610 VZ 44.83 bkl van Bentum, Jan verfasserin aut Perspectives on DNP-enhanced NMR spectroscopy in solutions 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. Supercritical solvent Elsevier Liquid state DNP Elsevier Rapid melt DNP Elsevier Overhauser Elsevier van Meerten, Bas oth Sharma, Manvendra oth Kentgens, Arno oth Enthalten in Elsevier Hiranaka, Takaaki ELSEVIER Response letter 2021 JMR Amsterdam [u.a.] (DE-627)ELV005993725 volume:264 year:2016 pages:59-67 extent:9 https://doi.org/10.1016/j.jmr.2016.01.010 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.83 Rheumatologie Orthopädie VZ AR 264 2016 59-67 9 045F 550 |
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10.1016/j.jmr.2016.01.010 doi GBVA2016019000007.pica (DE-627)ELV035504234 (ELSEVIER)S1090-7807(16)00051-3 DE-627 ger DE-627 rakwb eng 550 530 550 DE-600 530 DE-600 610 VZ 44.83 bkl van Bentum, Jan verfasserin aut Perspectives on DNP-enhanced NMR spectroscopy in solutions 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. Supercritical solvent Elsevier Liquid state DNP Elsevier Rapid melt DNP Elsevier Overhauser Elsevier van Meerten, Bas oth Sharma, Manvendra oth Kentgens, Arno oth Enthalten in Elsevier Hiranaka, Takaaki ELSEVIER Response letter 2021 JMR Amsterdam [u.a.] (DE-627)ELV005993725 volume:264 year:2016 pages:59-67 extent:9 https://doi.org/10.1016/j.jmr.2016.01.010 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.83 Rheumatologie Orthopädie VZ AR 264 2016 59-67 9 045F 550 |
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10.1016/j.jmr.2016.01.010 doi GBVA2016019000007.pica (DE-627)ELV035504234 (ELSEVIER)S1090-7807(16)00051-3 DE-627 ger DE-627 rakwb eng 550 530 550 DE-600 530 DE-600 610 VZ 44.83 bkl van Bentum, Jan verfasserin aut Perspectives on DNP-enhanced NMR spectroscopy in solutions 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. Supercritical solvent Elsevier Liquid state DNP Elsevier Rapid melt DNP Elsevier Overhauser Elsevier van Meerten, Bas oth Sharma, Manvendra oth Kentgens, Arno oth Enthalten in Elsevier Hiranaka, Takaaki ELSEVIER Response letter 2021 JMR Amsterdam [u.a.] (DE-627)ELV005993725 volume:264 year:2016 pages:59-67 extent:9 https://doi.org/10.1016/j.jmr.2016.01.010 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.83 Rheumatologie Orthopädie VZ AR 264 2016 59-67 9 045F 550 |
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10.1016/j.jmr.2016.01.010 doi GBVA2016019000007.pica (DE-627)ELV035504234 (ELSEVIER)S1090-7807(16)00051-3 DE-627 ger DE-627 rakwb eng 550 530 550 DE-600 530 DE-600 610 VZ 44.83 bkl van Bentum, Jan verfasserin aut Perspectives on DNP-enhanced NMR spectroscopy in solutions 2016transfer abstract 9 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. Supercritical solvent Elsevier Liquid state DNP Elsevier Rapid melt DNP Elsevier Overhauser Elsevier van Meerten, Bas oth Sharma, Manvendra oth Kentgens, Arno oth Enthalten in Elsevier Hiranaka, Takaaki ELSEVIER Response letter 2021 JMR Amsterdam [u.a.] (DE-627)ELV005993725 volume:264 year:2016 pages:59-67 extent:9 https://doi.org/10.1016/j.jmr.2016.01.010 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.83 Rheumatologie Orthopädie VZ AR 264 2016 59-67 9 045F 550 |
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Perspectives on DNP-enhanced NMR spectroscopy in solutions |
abstract |
More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. |
abstractGer |
More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. |
abstract_unstemmed |
More than 60years after the seminal work of Albert Overhauser on dynamic nuclear polarization by dynamic cross relaxation of coupled electron–nuclear spin systems, the quest for sensitivity enhancement in NMR spectroscopy is as pressing as ever. In this contribution we will review the status and perspectives for dynamic nuclear polarization in the liquid state. An appealing approach seems to be the use of supercritical solvents that may allow an extension of the Overhauser mechanism towards common high magnetic fields. A complementary approach is the use of solid state DNP on frozen solutions, followed by a rapid dissolution or in-situ melting step and NMR detection with substantially enhanced polarization levels in the liquid state. We will review recent developments in the field and discuss perspectives for the near future. |
collection_details |
GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA |
title_short |
Perspectives on DNP-enhanced NMR spectroscopy in solutions |
url |
https://doi.org/10.1016/j.jmr.2016.01.010 |
remote_bool |
true |
author2 |
van Meerten, Bas Sharma, Manvendra Kentgens, Arno |
author2Str |
van Meerten, Bas Sharma, Manvendra Kentgens, Arno |
ppnlink |
ELV005993725 |
mediatype_str_mv |
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isOA_txt |
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hochschulschrift_bool |
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author2_role |
oth oth oth |
doi_str |
10.1016/j.jmr.2016.01.010 |
up_date |
2024-07-06T17:43:50.468Z |
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1803852532121862144 |
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score |
7.399788 |