The interaction between copper species and pyrite surfaces in copper cyanide solutions
The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold...
Ausführliche Beschreibung
Autor*in: |
Guo, Bao [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2017transfer abstract |
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Umfang: |
8 |
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Übergeordnetes Werk: |
Enthalten in: Designing a reverse logistics network to manage construction and demolition wastes: A robust bi-level approach - Jahangiri, Adel ELSEVIER, 2022, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:158 ; year:2017 ; day:10 ; month:01 ; pages:85-92 ; extent:8 |
Links: |
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DOI / URN: |
10.1016/j.minpro.2016.11.021 |
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245 | 1 | 4 | |a The interaction between copper species and pyrite surfaces in copper cyanide solutions |
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520 | |a The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. | ||
520 | |a The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. | ||
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10.1016/j.minpro.2016.11.021 doi GBVA2017009000011.pica (DE-627)ELV035832010 (ELSEVIER)S0301-7516(16)30254-X DE-627 ger DE-627 rakwb eng 550 550 DE-600 690 330 VZ 43.35 bkl 85.35 bkl Guo, Bao verfasserin aut The interaction between copper species and pyrite surfaces in copper cyanide solutions 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. Peng, Yongjun oth Enthalten in Elsevier Science Jahangiri, Adel ELSEVIER Designing a reverse logistics network to manage construction and demolition wastes: A robust bi-level approach 2022 Amsterdam [u.a.] (DE-627)ELV008849315 volume:158 year:2017 day:10 month:01 pages:85-92 extent:8 https://doi.org/10.1016/j.minpro.2016.11.021 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO 43.35 Umweltrichtlinien Umweltnormen VZ 85.35 Fertigung VZ AR 158 2017 10 0110 85-92 8 045F 550 |
spelling |
10.1016/j.minpro.2016.11.021 doi GBVA2017009000011.pica (DE-627)ELV035832010 (ELSEVIER)S0301-7516(16)30254-X DE-627 ger DE-627 rakwb eng 550 550 DE-600 690 330 VZ 43.35 bkl 85.35 bkl Guo, Bao verfasserin aut The interaction between copper species and pyrite surfaces in copper cyanide solutions 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. Peng, Yongjun oth Enthalten in Elsevier Science Jahangiri, Adel ELSEVIER Designing a reverse logistics network to manage construction and demolition wastes: A robust bi-level approach 2022 Amsterdam [u.a.] (DE-627)ELV008849315 volume:158 year:2017 day:10 month:01 pages:85-92 extent:8 https://doi.org/10.1016/j.minpro.2016.11.021 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO 43.35 Umweltrichtlinien Umweltnormen VZ 85.35 Fertigung VZ AR 158 2017 10 0110 85-92 8 045F 550 |
allfields_unstemmed |
10.1016/j.minpro.2016.11.021 doi GBVA2017009000011.pica (DE-627)ELV035832010 (ELSEVIER)S0301-7516(16)30254-X DE-627 ger DE-627 rakwb eng 550 550 DE-600 690 330 VZ 43.35 bkl 85.35 bkl Guo, Bao verfasserin aut The interaction between copper species and pyrite surfaces in copper cyanide solutions 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. Peng, Yongjun oth Enthalten in Elsevier Science Jahangiri, Adel ELSEVIER Designing a reverse logistics network to manage construction and demolition wastes: A robust bi-level approach 2022 Amsterdam [u.a.] (DE-627)ELV008849315 volume:158 year:2017 day:10 month:01 pages:85-92 extent:8 https://doi.org/10.1016/j.minpro.2016.11.021 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO 43.35 Umweltrichtlinien Umweltnormen VZ 85.35 Fertigung VZ AR 158 2017 10 0110 85-92 8 045F 550 |
allfieldsGer |
10.1016/j.minpro.2016.11.021 doi GBVA2017009000011.pica (DE-627)ELV035832010 (ELSEVIER)S0301-7516(16)30254-X DE-627 ger DE-627 rakwb eng 550 550 DE-600 690 330 VZ 43.35 bkl 85.35 bkl Guo, Bao verfasserin aut The interaction between copper species and pyrite surfaces in copper cyanide solutions 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. Peng, Yongjun oth Enthalten in Elsevier Science Jahangiri, Adel ELSEVIER Designing a reverse logistics network to manage construction and demolition wastes: A robust bi-level approach 2022 Amsterdam [u.a.] (DE-627)ELV008849315 volume:158 year:2017 day:10 month:01 pages:85-92 extent:8 https://doi.org/10.1016/j.minpro.2016.11.021 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO 43.35 Umweltrichtlinien Umweltnormen VZ 85.35 Fertigung VZ AR 158 2017 10 0110 85-92 8 045F 550 |
allfieldsSound |
10.1016/j.minpro.2016.11.021 doi GBVA2017009000011.pica (DE-627)ELV035832010 (ELSEVIER)S0301-7516(16)30254-X DE-627 ger DE-627 rakwb eng 550 550 DE-600 690 330 VZ 43.35 bkl 85.35 bkl Guo, Bao verfasserin aut The interaction between copper species and pyrite surfaces in copper cyanide solutions 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. Peng, Yongjun oth Enthalten in Elsevier Science Jahangiri, Adel ELSEVIER Designing a reverse logistics network to manage construction and demolition wastes: A robust bi-level approach 2022 Amsterdam [u.a.] (DE-627)ELV008849315 volume:158 year:2017 day:10 month:01 pages:85-92 extent:8 https://doi.org/10.1016/j.minpro.2016.11.021 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO 43.35 Umweltrichtlinien Umweltnormen VZ 85.35 Fertigung VZ AR 158 2017 10 0110 85-92 8 045F 550 |
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interaction between copper species and pyrite surfaces in copper cyanide solutions |
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The interaction between copper species and pyrite surfaces in copper cyanide solutions |
abstract |
The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. |
abstractGer |
The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. |
abstract_unstemmed |
The adsorption of copper ions and the formation of a copper sulfide phase on pyrite surfaces are of vital importance to alter the surface property of pyrite and determine its fate either to be rejected in the flotation of polymetallic sulfide ores or to be recovered in the flotation of pyritic gold ores. Cyanide and copper may co-exist in the process water with complicated speciation. The objective of this study is to understand the interaction between copper cyanide species and pyrite and clarify the possible adsorption of copper on pyrite surfaces from cyanide-bearing solutions. Surface-enhanced Raman spectroscopy and electrochemical measurements were used to determine the reaction products formed on pyrite surfaces. It was found that Cu(I)-bearing species were incorporated into pyrite, forming a CuS-like sulfide from copper cyanide solutions at a more oxidizing potential, while a Cu2S-like sulfide formed at a more reducing potential. The amount of copper deposited on pyrite was significantly improved at a more reducing potential at which the pyrite surface tended to be FeS-like. In addition, these Cu(I)-sulfides on pyrite surfaces were dissolved by cyanide-bearing species at a high CN/Cu ratio, compromising the total amount of copper uptake. |
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The interaction between copper species and pyrite surfaces in copper cyanide solutions |
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