The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2–
This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(C...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ciabatti, Iacopo [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017transfer abstract |
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| Schlagwörter: |
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| Umfang: |
7 |
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| Übergeordnetes Werk: |
Enthalten in: The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial - Li, Chenglong ELSEVIER, 2019, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:849 ; year:2017 ; day:1 ; month:11 ; pages:299-305 ; extent:7 |
| Links: |
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| DOI / URN: |
10.1016/j.jorganchem.2017.01.029 |
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ELV036207624 |
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| 100 | 1 | |a Ciabatti, Iacopo |e verfasserin |4 aut | |
| 245 | 1 | 4 | |a The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– |
| 264 | 1 | |c 2017transfer abstract | |
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| 520 | |a This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. | ||
| 520 | |a This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. | ||
| 650 | 7 | |a Carbide |2 Elsevier | |
| 650 | 7 | |a Carbonyl ligand |2 Elsevier | |
| 650 | 7 | |a Cluster compound |2 Elsevier | |
| 650 | 7 | |a Electrochemistry |2 Elsevier | |
| 650 | 7 | |a Nickel |2 Elsevier | |
| 700 | 1 | |a Femoni, Cristina |4 oth | |
| 700 | 1 | |a Funaioli, Tiziana |4 oth | |
| 700 | 1 | |a Iapalucci, Maria Carmela |4 oth | |
| 700 | 1 | |a Merighi, Stefano |4 oth | |
| 700 | 1 | |a Zacchini, Stefano |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Li, Chenglong ELSEVIER |t The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |d 2019 |g New York, NY [u.a.] |w (DE-627)ELV002971518 |
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10.1016/j.jorganchem.2017.01.029 doi GBV00000000000251A.pica (DE-627)ELV036207624 (ELSEVIER)S0022-328X(17)30058-X DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Ciabatti, Iacopo verfasserin aut The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. Carbide Elsevier Carbonyl ligand Elsevier Cluster compound Elsevier Electrochemistry Elsevier Nickel Elsevier Femoni, Cristina oth Funaioli, Tiziana oth Iapalucci, Maria Carmela oth Merighi, Stefano oth Zacchini, Stefano oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:849 year:2017 day:1 month:11 pages:299-305 extent:7 https://doi.org/10.1016/j.jorganchem.2017.01.029 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 849 2017 1 1101 299-305 7 045F 540 |
| spelling |
10.1016/j.jorganchem.2017.01.029 doi GBV00000000000251A.pica (DE-627)ELV036207624 (ELSEVIER)S0022-328X(17)30058-X DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Ciabatti, Iacopo verfasserin aut The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. Carbide Elsevier Carbonyl ligand Elsevier Cluster compound Elsevier Electrochemistry Elsevier Nickel Elsevier Femoni, Cristina oth Funaioli, Tiziana oth Iapalucci, Maria Carmela oth Merighi, Stefano oth Zacchini, Stefano oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:849 year:2017 day:1 month:11 pages:299-305 extent:7 https://doi.org/10.1016/j.jorganchem.2017.01.029 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 849 2017 1 1101 299-305 7 045F 540 |
| allfields_unstemmed |
10.1016/j.jorganchem.2017.01.029 doi GBV00000000000251A.pica (DE-627)ELV036207624 (ELSEVIER)S0022-328X(17)30058-X DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Ciabatti, Iacopo verfasserin aut The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. Carbide Elsevier Carbonyl ligand Elsevier Cluster compound Elsevier Electrochemistry Elsevier Nickel Elsevier Femoni, Cristina oth Funaioli, Tiziana oth Iapalucci, Maria Carmela oth Merighi, Stefano oth Zacchini, Stefano oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:849 year:2017 day:1 month:11 pages:299-305 extent:7 https://doi.org/10.1016/j.jorganchem.2017.01.029 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 849 2017 1 1101 299-305 7 045F 540 |
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10.1016/j.jorganchem.2017.01.029 doi GBV00000000000251A.pica (DE-627)ELV036207624 (ELSEVIER)S0022-328X(17)30058-X DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Ciabatti, Iacopo verfasserin aut The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. Carbide Elsevier Carbonyl ligand Elsevier Cluster compound Elsevier Electrochemistry Elsevier Nickel Elsevier Femoni, Cristina oth Funaioli, Tiziana oth Iapalucci, Maria Carmela oth Merighi, Stefano oth Zacchini, Stefano oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:849 year:2017 day:1 month:11 pages:299-305 extent:7 https://doi.org/10.1016/j.jorganchem.2017.01.029 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 849 2017 1 1101 299-305 7 045F 540 |
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10.1016/j.jorganchem.2017.01.029 doi GBV00000000000251A.pica (DE-627)ELV036207624 (ELSEVIER)S0022-328X(17)30058-X DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Ciabatti, Iacopo verfasserin aut The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– 2017transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. Carbide Elsevier Carbonyl ligand Elsevier Cluster compound Elsevier Electrochemistry Elsevier Nickel Elsevier Femoni, Cristina oth Funaioli, Tiziana oth Iapalucci, Maria Carmela oth Merighi, Stefano oth Zacchini, Stefano oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:849 year:2017 day:1 month:11 pages:299-305 extent:7 https://doi.org/10.1016/j.jorganchem.2017.01.029 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 849 2017 1 1101 299-305 7 045F 540 |
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Enthalten in The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial New York, NY [u.a.] volume:849 year:2017 day:1 month:11 pages:299-305 extent:7 |
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The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
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Ciabatti, Iacopo @@aut@@ Femoni, Cristina @@oth@@ Funaioli, Tiziana @@oth@@ Iapalucci, Maria Carmela @@oth@@ Merighi, Stefano @@oth@@ Zacchini, Stefano @@oth@@ |
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| author |
Ciabatti, Iacopo |
| spellingShingle |
Ciabatti, Iacopo ddc 540 ddc 610 bkl 44.85 bkl 44.66 Elsevier Carbide Elsevier Carbonyl ligand Elsevier Cluster compound Elsevier Electrochemistry Elsevier Nickel The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– |
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Ciabatti, Iacopo |
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540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– Carbide Elsevier Carbonyl ligand Elsevier Cluster compound Elsevier Electrochemistry Elsevier Nickel Elsevier |
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ddc 540 ddc 610 bkl 44.85 bkl 44.66 Elsevier Carbide Elsevier Carbonyl ligand Elsevier Cluster compound Elsevier Electrochemistry Elsevier Nickel |
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Elektronische Aufsätze Aufsätze Elektronische Ressource |
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The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
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540 - Chemistry 610 - Medicine & health |
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The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
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The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– |
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(DE-627)ELV036207624 (ELSEVIER)S0022-328X(17)30058-X |
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The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– |
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Ciabatti, Iacopo |
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The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
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The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
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Ciabatti, Iacopo |
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Elektronische Aufsätze |
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Ciabatti, Iacopo |
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10.1016/j.jorganchem.2017.01.029 |
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540 610 |
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redox chemistry of [ni9c(co)17]2– and [ni10(c2)(co)16]2–: synthesis, electrochemistry and structure of [ni12c(co)18]4– and [ni22(c2)4(co)28(et2s)]2– |
| title_auth |
The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– |
| abstract |
This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. |
| abstractGer |
This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. |
| abstract_unstemmed |
This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction of [Ni9C(CO)17]2– with Na/naphtalene affords the new [Ni12C(CO)18]4– mono-carbide cluster. Under the same experimental conditions, [Ni10(C2)(CO)16]2– reacts with Na/naphtalene yielding a mixture of the previously reported [Ni11(C2)(CO)15]4– and [Ni12(C2)(CO)16]4– mono-acetylide tetra-anions. The oxidation reactions of both [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–, carried out with miscellaneous reagents, e.g., [C7H7][BF4], [Cp2Fe][PF6], AgNO3, are more complicated and less selective, leading to mixtures of products, among which the previously reported [Ni8C(CO)16]2–, [Ni16(C2)2(CO)23]4–, [Ni38C6(CO)42]6– and [Ni32C6(CO)36]6– species have been identified. Interestingly, oxidation of [Ni10(C2)(CO)16]2– with Pd(Et2S)2Cl2 affords the new tetra-acetylide [Ni22(C2)4(CO)28(Et2S)]2–, even if in low yields. The new species [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– have been structurally characterized by means of single crystal X-ray diffraction. Electrochemical and spectroelectrochemical studies have been performed on [Ni12C(CO)18]4–. This compound can be electrochemically oxidized and reduced reversibly affording [Ni12C(CO)18]3– and [Ni12C(CO)18]5–, respectively. The same species can be obtained by chemical methods but, due to their limited stability during work-up, it has not been possible to isolate them. |
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The redox chemistry of [Ni9C(CO)17]2– and [Ni10(C2)(CO)16]2–: Synthesis, electrochemistry and structure of [Ni12C(CO)18]4– and [Ni22(C2)4(CO)28(Et2S)]2– |
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https://doi.org/10.1016/j.jorganchem.2017.01.029 |
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Femoni, Cristina Funaioli, Tiziana Iapalucci, Maria Carmela Merighi, Stefano Zacchini, Stefano |
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Femoni, Cristina Funaioli, Tiziana Iapalucci, Maria Carmela Merighi, Stefano Zacchini, Stefano |
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