Electrospun CuFe2O4 nanotubes as anodes for high-performance lithium-ion batteries
Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fib...
Ausführliche Beschreibung
Autor*in: |
Peng, Shengjie [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2014transfer abstract |
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Umfang: |
7 |
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Übergeordnetes Werk: |
Enthalten in: Cu2O-sensitized TiO2 nanorods with nanocavities for highly efficient photocatalytic hydrogen production under solar irradiation - Praveen Kumar, D. ELSEVIER, 2015transfer abstract, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:23 ; year:2014 ; number:3 ; pages:301-307 ; extent:7 |
Links: |
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DOI / URN: |
10.1016/S2095-4956(14)60151-0 |
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Katalog-ID: |
ELV03935721X |
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520 | |a Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. | ||
520 | |a Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. | ||
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10.1016/S2095-4956(14)60151-0 doi GBVA2014011000018.pica (DE-627)ELV03935721X (ELSEVIER)S2095-4956(14)60151-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 690 VZ 56.03 bkl Peng, Shengjie verfasserin aut Electrospun CuFe2O4 nanotubes as anodes for high-performance lithium-ion batteries 2014transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. electrospinning Elsevier one-dimensional structures Elsevier nanotubes, lithium ion batteries Elsevier ferrite salts Elsevier Li, Linlin oth Srinivasan, Madhavi oth Enthalten in Elsevier Praveen Kumar, D. ELSEVIER Cu2O-sensitized TiO2 nanorods with nanocavities for highly efficient photocatalytic hydrogen production under solar irradiation 2015transfer abstract Amsterdam [u.a.] (DE-627)ELV01862751X volume:23 year:2014 number:3 pages:301-307 extent:7 https://doi.org/10.1016/S2095-4956(14)60151-0 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_21 GBV_ILN_40 56.03 Methoden im Bauingenieurwesen VZ AR 23 2014 3 301-307 7 045F 540 |
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10.1016/S2095-4956(14)60151-0 doi GBVA2014011000018.pica (DE-627)ELV03935721X (ELSEVIER)S2095-4956(14)60151-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 690 VZ 56.03 bkl Peng, Shengjie verfasserin aut Electrospun CuFe2O4 nanotubes as anodes for high-performance lithium-ion batteries 2014transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. electrospinning Elsevier one-dimensional structures Elsevier nanotubes, lithium ion batteries Elsevier ferrite salts Elsevier Li, Linlin oth Srinivasan, Madhavi oth Enthalten in Elsevier Praveen Kumar, D. ELSEVIER Cu2O-sensitized TiO2 nanorods with nanocavities for highly efficient photocatalytic hydrogen production under solar irradiation 2015transfer abstract Amsterdam [u.a.] (DE-627)ELV01862751X volume:23 year:2014 number:3 pages:301-307 extent:7 https://doi.org/10.1016/S2095-4956(14)60151-0 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_21 GBV_ILN_40 56.03 Methoden im Bauingenieurwesen VZ AR 23 2014 3 301-307 7 045F 540 |
allfields_unstemmed |
10.1016/S2095-4956(14)60151-0 doi GBVA2014011000018.pica (DE-627)ELV03935721X (ELSEVIER)S2095-4956(14)60151-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 690 VZ 56.03 bkl Peng, Shengjie verfasserin aut Electrospun CuFe2O4 nanotubes as anodes for high-performance lithium-ion batteries 2014transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. electrospinning Elsevier one-dimensional structures Elsevier nanotubes, lithium ion batteries Elsevier ferrite salts Elsevier Li, Linlin oth Srinivasan, Madhavi oth Enthalten in Elsevier Praveen Kumar, D. ELSEVIER Cu2O-sensitized TiO2 nanorods with nanocavities for highly efficient photocatalytic hydrogen production under solar irradiation 2015transfer abstract Amsterdam [u.a.] (DE-627)ELV01862751X volume:23 year:2014 number:3 pages:301-307 extent:7 https://doi.org/10.1016/S2095-4956(14)60151-0 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_21 GBV_ILN_40 56.03 Methoden im Bauingenieurwesen VZ AR 23 2014 3 301-307 7 045F 540 |
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10.1016/S2095-4956(14)60151-0 doi GBVA2014011000018.pica (DE-627)ELV03935721X (ELSEVIER)S2095-4956(14)60151-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 690 VZ 56.03 bkl Peng, Shengjie verfasserin aut Electrospun CuFe2O4 nanotubes as anodes for high-performance lithium-ion batteries 2014transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. electrospinning Elsevier one-dimensional structures Elsevier nanotubes, lithium ion batteries Elsevier ferrite salts Elsevier Li, Linlin oth Srinivasan, Madhavi oth Enthalten in Elsevier Praveen Kumar, D. ELSEVIER Cu2O-sensitized TiO2 nanorods with nanocavities for highly efficient photocatalytic hydrogen production under solar irradiation 2015transfer abstract Amsterdam [u.a.] (DE-627)ELV01862751X volume:23 year:2014 number:3 pages:301-307 extent:7 https://doi.org/10.1016/S2095-4956(14)60151-0 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_21 GBV_ILN_40 56.03 Methoden im Bauingenieurwesen VZ AR 23 2014 3 301-307 7 045F 540 |
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10.1016/S2095-4956(14)60151-0 doi GBVA2014011000018.pica (DE-627)ELV03935721X (ELSEVIER)S2095-4956(14)60151-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 530 VZ 620 VZ 690 VZ 56.03 bkl Peng, Shengjie verfasserin aut Electrospun CuFe2O4 nanotubes as anodes for high-performance lithium-ion batteries 2014transfer abstract 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. electrospinning Elsevier one-dimensional structures Elsevier nanotubes, lithium ion batteries Elsevier ferrite salts Elsevier Li, Linlin oth Srinivasan, Madhavi oth Enthalten in Elsevier Praveen Kumar, D. ELSEVIER Cu2O-sensitized TiO2 nanorods with nanocavities for highly efficient photocatalytic hydrogen production under solar irradiation 2015transfer abstract Amsterdam [u.a.] (DE-627)ELV01862751X volume:23 year:2014 number:3 pages:301-307 extent:7 https://doi.org/10.1016/S2095-4956(14)60151-0 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_21 GBV_ILN_40 56.03 Methoden im Bauingenieurwesen VZ AR 23 2014 3 301-307 7 045F 540 |
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Enthalten in Cu2O-sensitized TiO2 nanorods with nanocavities for highly efficient photocatalytic hydrogen production under solar irradiation Amsterdam [u.a.] volume:23 year:2014 number:3 pages:301-307 extent:7 |
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Enthalten in Cu2O-sensitized TiO2 nanorods with nanocavities for highly efficient photocatalytic hydrogen production under solar irradiation Amsterdam [u.a.] volume:23 year:2014 number:3 pages:301-307 extent:7 |
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Cu2O-sensitized TiO2 nanorods with nanocavities for highly efficient photocatalytic hydrogen production under solar irradiation |
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abstract |
Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. |
abstractGer |
Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. |
abstract_unstemmed |
Herein, we report on the synthesis and lithium storage properties of electrospun one-dimensional (1D) CuFe2O4 nanomaterials. 1D CuFe2O4 nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers. The as-prepared CuFe2O4 nanotubes with wall thickness of ~50 nm presented diameters of ·~150 nm and lengths up to several millimeters. It was found that phase separation between the electrospun composite materials occured during the electrospinning process, while the as-spun precursor nanofibers composed of polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) and metal salts might possess a core-shell structure (PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination. Moreover, as a demonstration of the functional properties of the 1D nanostructure, CuFe2O4 nanotubes and nanorods were investigated as anodes for lithium ion batteries (LIBs). It was demonstrated that CuFe2O4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g−1 at a current density of 200 mA·g−1 over 50 cycles, but also showed superior rate capability with respect to counterpart nanorods. Probably, the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. |
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