Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction
Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characteriz...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Murshid, Nimer [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2017transfer abstract |
|---|
| Schlagwörter: |
|---|
| Umfang: |
6 |
|---|
| Übergeordnetes Werk: |
Enthalten in: The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial - Li, Chenglong ELSEVIER, 2019, New York, NY [u.a.] |
|---|---|
| Übergeordnetes Werk: |
volume:851 ; year:2017 ; day:15 ; month:11 ; pages:40-45 ; extent:6 |
| Links: |
|---|
| DOI / URN: |
10.1016/j.jorganchem.2017.09.003 |
|---|
| Katalog-ID: |
ELV04072381X |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | ELV04072381X | ||
| 003 | DE-627 | ||
| 005 | 20230625232657.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 180725s2017 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.jorganchem.2017.09.003 |2 doi | |
| 028 | 5 | 2 | |a GBV00000000000058A.pica |
| 035 | |a (DE-627)ELV04072381X | ||
| 035 | |a (ELSEVIER)S0022-328X(17)30514-4 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | |a 540 | |
| 082 | 0 | 4 | |a 540 |q DE-600 |
| 082 | 0 | 4 | |a 610 |q VZ |
| 084 | |a 44.85 |2 bkl | ||
| 084 | |a 44.66 |2 bkl | ||
| 100 | 1 | |a Murshid, Nimer |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction |
| 264 | 1 | |c 2017transfer abstract | |
| 300 | |a 6 | ||
| 336 | |a nicht spezifiziert |b zzz |2 rdacontent | ||
| 337 | |a nicht spezifiziert |b z |2 rdamedia | ||
| 338 | |a nicht spezifiziert |b zu |2 rdacarrier | ||
| 520 | |a Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. | ||
| 520 | |a Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. | ||
| 650 | 7 | |a Migration insertion reaction |2 Elsevier | |
| 650 | 7 | |a Iron-phosphine amphiphiles |2 Elsevier | |
| 650 | 7 | |a Metal-carbonyl complex |2 Elsevier | |
| 650 | 7 | |a Iron-carbonyl PEG amphiphile |2 Elsevier | |
| 650 | 7 | |a Fp-surfactants |2 Elsevier | |
| 650 | 7 | |a Organometallic amphiphiles |2 Elsevier | |
| 700 | 1 | |a El-Temtamy, Abdelrahman |4 oth | |
| 700 | 1 | |a Wang, Xiaosong |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |n Elsevier |a Li, Chenglong ELSEVIER |t The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |d 2019 |g New York, NY [u.a.] |w (DE-627)ELV002971518 |
| 773 | 1 | 8 | |g volume:851 |g year:2017 |g day:15 |g month:11 |g pages:40-45 |g extent:6 |
| 856 | 4 | 0 | |u https://doi.org/10.1016/j.jorganchem.2017.09.003 |3 Volltext |
| 912 | |a GBV_USEFLAG_U | ||
| 912 | |a GBV_ELV | ||
| 912 | |a SYSFLAG_U | ||
| 912 | |a SSG-OLC-PHA | ||
| 936 | b | k | |a 44.85 |j Kardiologie |j Angiologie |q VZ |
| 936 | b | k | |a 44.66 |j Anästhesiologie |q VZ |
| 951 | |a AR | ||
| 952 | |d 851 |j 2017 |b 15 |c 1115 |h 40-45 |g 6 | ||
| 953 | |2 045F |a 540 | ||
| author_variant |
n m nm |
|---|---|
| matchkey_str |
murshidnimereltemtamyabdelrahmanwangxiao:2017----:yteiadouineaiuomtlabnlmhpiew |
| hierarchy_sort_str |
2017transfer abstract |
| bklnumber |
44.85 44.66 |
| publishDate |
2017 |
| allfields |
10.1016/j.jorganchem.2017.09.003 doi GBV00000000000058A.pica (DE-627)ELV04072381X (ELSEVIER)S0022-328X(17)30514-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Murshid, Nimer verfasserin aut Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles Elsevier El-Temtamy, Abdelrahman oth Wang, Xiaosong oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:851 year:2017 day:15 month:11 pages:40-45 extent:6 https://doi.org/10.1016/j.jorganchem.2017.09.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 851 2017 15 1115 40-45 6 045F 540 |
| spelling |
10.1016/j.jorganchem.2017.09.003 doi GBV00000000000058A.pica (DE-627)ELV04072381X (ELSEVIER)S0022-328X(17)30514-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Murshid, Nimer verfasserin aut Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles Elsevier El-Temtamy, Abdelrahman oth Wang, Xiaosong oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:851 year:2017 day:15 month:11 pages:40-45 extent:6 https://doi.org/10.1016/j.jorganchem.2017.09.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 851 2017 15 1115 40-45 6 045F 540 |
| allfields_unstemmed |
10.1016/j.jorganchem.2017.09.003 doi GBV00000000000058A.pica (DE-627)ELV04072381X (ELSEVIER)S0022-328X(17)30514-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Murshid, Nimer verfasserin aut Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles Elsevier El-Temtamy, Abdelrahman oth Wang, Xiaosong oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:851 year:2017 day:15 month:11 pages:40-45 extent:6 https://doi.org/10.1016/j.jorganchem.2017.09.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 851 2017 15 1115 40-45 6 045F 540 |
| allfieldsGer |
10.1016/j.jorganchem.2017.09.003 doi GBV00000000000058A.pica (DE-627)ELV04072381X (ELSEVIER)S0022-328X(17)30514-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Murshid, Nimer verfasserin aut Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles Elsevier El-Temtamy, Abdelrahman oth Wang, Xiaosong oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:851 year:2017 day:15 month:11 pages:40-45 extent:6 https://doi.org/10.1016/j.jorganchem.2017.09.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 851 2017 15 1115 40-45 6 045F 540 |
| allfieldsSound |
10.1016/j.jorganchem.2017.09.003 doi GBV00000000000058A.pica (DE-627)ELV04072381X (ELSEVIER)S0022-328X(17)30514-4 DE-627 ger DE-627 rakwb eng 540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Murshid, Nimer verfasserin aut Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction 2017transfer abstract 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles Elsevier El-Temtamy, Abdelrahman oth Wang, Xiaosong oth Enthalten in Elsevier Li, Chenglong ELSEVIER The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial 2019 New York, NY [u.a.] (DE-627)ELV002971518 volume:851 year:2017 day:15 month:11 pages:40-45 extent:6 https://doi.org/10.1016/j.jorganchem.2017.09.003 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA 44.85 Kardiologie Angiologie VZ 44.66 Anästhesiologie VZ AR 851 2017 15 1115 40-45 6 045F 540 |
| language |
English |
| source |
Enthalten in The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial New York, NY [u.a.] volume:851 year:2017 day:15 month:11 pages:40-45 extent:6 |
| sourceStr |
Enthalten in The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial New York, NY [u.a.] volume:851 year:2017 day:15 month:11 pages:40-45 extent:6 |
| format_phy_str_mv |
Article |
| bklname |
Kardiologie Angiologie Anästhesiologie |
| institution |
findex.gbv.de |
| topic_facet |
Migration insertion reaction Iron-phosphine amphiphiles Metal-carbonyl complex Iron-carbonyl PEG amphiphile Fp-surfactants Organometallic amphiphiles |
| dewey-raw |
540 |
| isfreeaccess_bool |
false |
| container_title |
The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
| authorswithroles_txt_mv |
Murshid, Nimer @@aut@@ El-Temtamy, Abdelrahman @@oth@@ Wang, Xiaosong @@oth@@ |
| publishDateDaySort_date |
2017-01-15T00:00:00Z |
| hierarchy_top_id |
ELV002971518 |
| dewey-sort |
3540 |
| id |
ELV04072381X |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV04072381X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230625232657.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">180725s2017 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jorganchem.2017.09.003</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">GBV00000000000058A.pica</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV04072381X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0022-328X(17)30514-4</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">540</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">610</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">44.85</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">44.66</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Murshid, Nimer</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017transfer abstract</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">6</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour.</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Migration insertion reaction</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Iron-phosphine amphiphiles</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Metal-carbonyl complex</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Iron-carbonyl PEG amphiphile</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Fp-surfactants</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Organometallic amphiphiles</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">El-Temtamy, Abdelrahman</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Xiaosong</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="n">Elsevier</subfield><subfield code="a">Li, Chenglong ELSEVIER</subfield><subfield code="t">The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial</subfield><subfield code="d">2019</subfield><subfield code="g">New York, NY [u.a.]</subfield><subfield code="w">(DE-627)ELV002971518</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:851</subfield><subfield code="g">year:2017</subfield><subfield code="g">day:15</subfield><subfield code="g">month:11</subfield><subfield code="g">pages:40-45</subfield><subfield code="g">extent:6</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1016/j.jorganchem.2017.09.003</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">44.85</subfield><subfield code="j">Kardiologie</subfield><subfield code="j">Angiologie</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">44.66</subfield><subfield code="j">Anästhesiologie</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">851</subfield><subfield code="j">2017</subfield><subfield code="b">15</subfield><subfield code="c">1115</subfield><subfield code="h">40-45</subfield><subfield code="g">6</subfield></datafield><datafield tag="953" ind1=" " ind2=" "><subfield code="2">045F</subfield><subfield code="a">540</subfield></datafield></record></collection>
|
| author |
Murshid, Nimer |
| spellingShingle |
Murshid, Nimer ddc 540 ddc 610 bkl 44.85 bkl 44.66 Elsevier Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction |
| authorStr |
Murshid, Nimer |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)ELV002971518 |
| format |
electronic Article |
| dewey-ones |
540 - Chemistry & allied sciences 610 - Medicine & health |
| delete_txt_mv |
keep |
| author_role |
aut |
| collection |
elsevier |
| remote_str |
true |
| illustrated |
Not Illustrated |
| topic_title |
540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles Elsevier |
| topic |
ddc 540 ddc 610 bkl 44.85 bkl 44.66 Elsevier Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles |
| topic_unstemmed |
ddc 540 ddc 610 bkl 44.85 bkl 44.66 Elsevier Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles |
| topic_browse |
ddc 540 ddc 610 bkl 44.85 bkl 44.66 Elsevier Migration insertion reaction Elsevier Iron-phosphine amphiphiles Elsevier Metal-carbonyl complex Elsevier Iron-carbonyl PEG amphiphile Elsevier Fp-surfactants Elsevier Organometallic amphiphiles |
| format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
zu |
| author2_variant |
a e t aet x w xw |
| hierarchy_parent_title |
The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
| hierarchy_parent_id |
ELV002971518 |
| dewey-tens |
540 - Chemistry 610 - Medicine & health |
| hierarchy_top_title |
The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)ELV002971518 |
| title |
Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction |
| ctrlnum |
(DE-627)ELV04072381X (ELSEVIER)S0022-328X(17)30514-4 |
| title_full |
Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction |
| author_sort |
Murshid, Nimer |
| journal |
The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
| journalStr |
The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
500 - Science 600 - Technology |
| recordtype |
marc |
| publishDateSort |
2017 |
| contenttype_str_mv |
zzz |
| container_start_page |
40 |
| author_browse |
Murshid, Nimer |
| container_volume |
851 |
| physical |
6 |
| class |
540 540 DE-600 610 VZ 44.85 bkl 44.66 bkl |
| format_se |
Elektronische Aufsätze |
| author-letter |
Murshid, Nimer |
| doi_str_mv |
10.1016/j.jorganchem.2017.09.003 |
| dewey-full |
540 610 |
| title_sort |
synthesis and solution behaviour of metal-carbonyl amphiphiles with an fp (cpfe(co)2) junction |
| title_auth |
Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction |
| abstract |
Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. |
| abstractGer |
Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. |
| abstract_unstemmed |
Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour. |
| collection_details |
GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA |
| title_short |
Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction |
| url |
https://doi.org/10.1016/j.jorganchem.2017.09.003 |
| remote_bool |
true |
| author2 |
El-Temtamy, Abdelrahman Wang, Xiaosong |
| author2Str |
El-Temtamy, Abdelrahman Wang, Xiaosong |
| ppnlink |
ELV002971518 |
| mediatype_str_mv |
z |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| author2_role |
oth oth |
| doi_str |
10.1016/j.jorganchem.2017.09.003 |
| up_date |
2024-07-06T18:13:23.023Z |
| _version_ |
1803854390781542400 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">ELV04072381X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230625232657.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">180725s2017 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.jorganchem.2017.09.003</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">GBV00000000000058A.pica</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV04072381X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0022-328X(17)30514-4</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">540</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">610</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">44.85</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">44.66</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Murshid, Nimer</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis and solution behaviour of metal-carbonyl amphiphiles with an Fp (CpFe(CO)2) junction</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017transfer abstract</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">6</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour.</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Metallo-amphiphilic macromolecules with an iron-carbonyl junction (PEGPPh2-FpR, PEGPPh2: polyethylene glycol diphenyl phosphine, Mn, PEG = 550 or 2000 g/mol; R = octadecyl or hexyl; Fp = CpFe(CO)2) are synthesized via migration insertion reaction of FpR in the presence of PEGPPh2 and are characterized using 31P, 1H NMR and IR. The prepared amphiphiles are air stable, soluble in most organic solvents, e.g. THF, DCM, DMF, and exhibit a reversible redox activity as indicated by cyclic voltammetry (CV) experiments. Surface tension measurements indicate that the prepared molecules exhibit typical amphiphilic properties with critical micelle concentrations (CMC) in water ranging between 30 and 113 μM. The aqueous micelles aggregated from PEGPPh2-FpR agglomerate into suspensions, which is similar with the solution behaviour of Brij® surfactants, the organic analogue without the Fp junction. The redox activity of Fp junction in 1–4, which is sensitive to assembling structures, will be a possible advantage for further investigation on this agglomeration behaviour.</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Migration insertion reaction</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Iron-phosphine amphiphiles</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Metal-carbonyl complex</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Iron-carbonyl PEG amphiphile</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Fp-surfactants</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Organometallic amphiphiles</subfield><subfield code="2">Elsevier</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">El-Temtamy, Abdelrahman</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Xiaosong</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="n">Elsevier</subfield><subfield code="a">Li, Chenglong ELSEVIER</subfield><subfield code="t">The Effect of Simultaneous Renal Replacement Therapy on Extracorporeal Membrane Oxygenation Support for Postcardiotomy Patients with Cardiogenic Shock: A Pilot Randomized Controlled Trial</subfield><subfield code="d">2019</subfield><subfield code="g">New York, NY [u.a.]</subfield><subfield code="w">(DE-627)ELV002971518</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:851</subfield><subfield code="g">year:2017</subfield><subfield code="g">day:15</subfield><subfield code="g">month:11</subfield><subfield code="g">pages:40-45</subfield><subfield code="g">extent:6</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1016/j.jorganchem.2017.09.003</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">44.85</subfield><subfield code="j">Kardiologie</subfield><subfield code="j">Angiologie</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">44.66</subfield><subfield code="j">Anästhesiologie</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">851</subfield><subfield code="j">2017</subfield><subfield code="b">15</subfield><subfield code="c">1115</subfield><subfield code="h">40-45</subfield><subfield code="g">6</subfield></datafield><datafield tag="953" ind1=" " ind2=" "><subfield code="2">045F</subfield><subfield code="a">540</subfield></datafield></record></collection>
|
| score |
7.4005537 |