A novel method for the evaluation of the Rare Earth (RE) coordination number in RE-doped ceria through Raman spectroscopy
A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination numb...
Ausführliche Beschreibung
Autor*in: |
Artini, Cristina [verfasserIn] |
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Englisch |
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2017transfer abstract |
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8 |
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Enthalten in: P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION - Garg, A. ELSEVIER, 2014, diffusion and reactions, Amsterdam [u.a.] |
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Übergeordnetes Werk: |
volume:311 ; year:2017 ; day:15 ; month:11 ; pages:90-97 ; extent:8 |
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DOI / URN: |
10.1016/j.ssi.2017.09.016 |
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ELV040804690 |
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520 | |a A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. | ||
520 | |a A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. | ||
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10.1016/j.ssi.2017.09.016 doi GBV00000000000255A.pica (DE-627)ELV040804690 (ELSEVIER)S0167-2738(17)30374-0 DE-627 ger DE-627 rakwb eng 530 530 DE-600 610 VZ 610 VZ 44.44 bkl Artini, Cristina verfasserin aut A novel method for the evaluation of the Rare Earth (RE) coordination number in RE-doped ceria through Raman spectroscopy 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. Carnasciali, Maria Maddalena oth Plaisier, Jasper Rikkert oth Costa, Giorgio Andrea oth Pani, Marcella oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:311 year:2017 day:15 month:11 pages:90-97 extent:8 https://doi.org/10.1016/j.ssi.2017.09.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 311 2017 15 1115 90-97 8 045F 530 |
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10.1016/j.ssi.2017.09.016 doi GBV00000000000255A.pica (DE-627)ELV040804690 (ELSEVIER)S0167-2738(17)30374-0 DE-627 ger DE-627 rakwb eng 530 530 DE-600 610 VZ 610 VZ 44.44 bkl Artini, Cristina verfasserin aut A novel method for the evaluation of the Rare Earth (RE) coordination number in RE-doped ceria through Raman spectroscopy 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. Carnasciali, Maria Maddalena oth Plaisier, Jasper Rikkert oth Costa, Giorgio Andrea oth Pani, Marcella oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:311 year:2017 day:15 month:11 pages:90-97 extent:8 https://doi.org/10.1016/j.ssi.2017.09.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 311 2017 15 1115 90-97 8 045F 530 |
allfields_unstemmed |
10.1016/j.ssi.2017.09.016 doi GBV00000000000255A.pica (DE-627)ELV040804690 (ELSEVIER)S0167-2738(17)30374-0 DE-627 ger DE-627 rakwb eng 530 530 DE-600 610 VZ 610 VZ 44.44 bkl Artini, Cristina verfasserin aut A novel method for the evaluation of the Rare Earth (RE) coordination number in RE-doped ceria through Raman spectroscopy 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. Carnasciali, Maria Maddalena oth Plaisier, Jasper Rikkert oth Costa, Giorgio Andrea oth Pani, Marcella oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:311 year:2017 day:15 month:11 pages:90-97 extent:8 https://doi.org/10.1016/j.ssi.2017.09.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 311 2017 15 1115 90-97 8 045F 530 |
allfieldsGer |
10.1016/j.ssi.2017.09.016 doi GBV00000000000255A.pica (DE-627)ELV040804690 (ELSEVIER)S0167-2738(17)30374-0 DE-627 ger DE-627 rakwb eng 530 530 DE-600 610 VZ 610 VZ 44.44 bkl Artini, Cristina verfasserin aut A novel method for the evaluation of the Rare Earth (RE) coordination number in RE-doped ceria through Raman spectroscopy 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. Carnasciali, Maria Maddalena oth Plaisier, Jasper Rikkert oth Costa, Giorgio Andrea oth Pani, Marcella oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:311 year:2017 day:15 month:11 pages:90-97 extent:8 https://doi.org/10.1016/j.ssi.2017.09.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 311 2017 15 1115 90-97 8 045F 530 |
allfieldsSound |
10.1016/j.ssi.2017.09.016 doi GBV00000000000255A.pica (DE-627)ELV040804690 (ELSEVIER)S0167-2738(17)30374-0 DE-627 ger DE-627 rakwb eng 530 530 DE-600 610 VZ 610 VZ 44.44 bkl Artini, Cristina verfasserin aut A novel method for the evaluation of the Rare Earth (RE) coordination number in RE-doped ceria through Raman spectroscopy 2017transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. Carnasciali, Maria Maddalena oth Plaisier, Jasper Rikkert oth Costa, Giorgio Andrea oth Pani, Marcella oth Enthalten in Elsevier Science Garg, A. ELSEVIER P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION 2014 diffusion and reactions Amsterdam [u.a.] (DE-627)ELV012106844 volume:311 year:2017 day:15 month:11 pages:90-97 extent:8 https://doi.org/10.1016/j.ssi.2017.09.016 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_21 GBV_ILN_78 44.44 Parasitologie Medizin VZ AR 311 2017 15 1115 90-97 8 045F 530 |
language |
English |
source |
Enthalten in P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION Amsterdam [u.a.] volume:311 year:2017 day:15 month:11 pages:90-97 extent:8 |
sourceStr |
Enthalten in P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION Amsterdam [u.a.] volume:311 year:2017 day:15 month:11 pages:90-97 extent:8 |
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P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION |
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The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. 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P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION |
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A novel method for the evaluation of the Rare Earth (RE) coordination number in RE-doped ceria through Raman spectroscopy |
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P616 TGFβ1 STIMULATION OF HUMAN BONE MARROW MESENCHYMAL STEM CELLS (MSC) ENHANCES THEIR HEPATIC ENGRAFTMENT AND THERAPEUTIC EFFECT IN INJURED LIVER VIA UPREGULATION OF CXCR3 FUNCTION |
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a novel method for the evaluation of the rare earth (re) coordination number in re-doped ceria through raman spectroscopy |
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A novel method for the evaluation of the Rare Earth (RE) coordination number in RE-doped ceria through Raman spectroscopy |
abstract |
A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. |
abstractGer |
A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. |
abstract_unstemmed |
A set of nine samples with nominal composition Ce0.5RE0.5O1.75 (RE≡Dy-Lu, Sm, Gd and Y) has been used to develop a novel method based on Raman spectroscopy, useful to evaluate the RE coordination number within the fluorite-type structure (F) of the CeO2-based solid solution. The RE coordination number is a crucial indicator of defects aggregation in doped ceria, and thus of the drop in ionic conductivity observed even well below the compositional limit of the F structure. The method has been tested on several Ce1− x RE x O2− x/2 compositions (RE≡Sm, Gd and Lu, 0.1≤ x ≤0.4); the obtained results are compared to literature data deriving from EXAFS spectroscopy, and advantages and criticisms of the method are thoroughly discussed. Samples were prepared by a coprecipitation method, their cationic composition was checked by SEM-EDS and their structural features were analyzed by room temperature synchrotron powder x-ray diffraction. |
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title_short |
A novel method for the evaluation of the Rare Earth (RE) coordination number in RE-doped ceria through Raman spectroscopy |
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https://doi.org/10.1016/j.ssi.2017.09.016 |
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Carnasciali, Maria Maddalena Plaisier, Jasper Rikkert Costa, Giorgio Andrea Pani, Marcella |
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