Efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air
Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic aci...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Xie, Ruirui [verfasserIn] |
|---|
| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018transfer abstract |
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| Umfang: |
8 |
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| Übergeordnetes Werk: |
Enthalten in: Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects - Moreno-Cabezali, Belen Maria ELSEVIER, 2020, an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids, New York, NY [u.a.] |
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| Übergeordnetes Werk: |
volume:249 ; year:2018 ; pages:486-493 ; extent:8 |
| Links: |
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| DOI / URN: |
10.1016/j.molliq.2017.11.066 |
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| 520 | |a Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. | ||
| 520 | |a Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. | ||
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| 700 | 1 | |a Ding, Hongying |4 oth | |
| 700 | 1 | |a Yan, Bing |4 oth | |
| 700 | 1 | |a Cheng, Bowen |4 oth | |
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10.1016/j.molliq.2017.11.066 doi GBV00000000000294A.pica (DE-627)ELV041480333 (ELSEVIER)S0167-7322(17)34068-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 004 VZ 85.35 bkl 54.80 bkl Xie, Ruirui verfasserin aut Efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air 2018transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Zang, Hongjun oth Ding, Hongying oth Yan, Bing oth Cheng, Bowen oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:249 year:2018 pages:486-493 extent:8 https://doi.org/10.1016/j.molliq.2017.11.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 249 2018 486-493 8 045F 540 |
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10.1016/j.molliq.2017.11.066 doi GBV00000000000294A.pica (DE-627)ELV041480333 (ELSEVIER)S0167-7322(17)34068-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 004 VZ 85.35 bkl 54.80 bkl Xie, Ruirui verfasserin aut Efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air 2018transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Zang, Hongjun oth Ding, Hongying oth Yan, Bing oth Cheng, Bowen oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:249 year:2018 pages:486-493 extent:8 https://doi.org/10.1016/j.molliq.2017.11.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 249 2018 486-493 8 045F 540 |
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10.1016/j.molliq.2017.11.066 doi GBV00000000000294A.pica (DE-627)ELV041480333 (ELSEVIER)S0167-7322(17)34068-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 004 VZ 85.35 bkl 54.80 bkl Xie, Ruirui verfasserin aut Efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air 2018transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Zang, Hongjun oth Ding, Hongying oth Yan, Bing oth Cheng, Bowen oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:249 year:2018 pages:486-493 extent:8 https://doi.org/10.1016/j.molliq.2017.11.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 249 2018 486-493 8 045F 540 |
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10.1016/j.molliq.2017.11.066 doi GBV00000000000294A.pica (DE-627)ELV041480333 (ELSEVIER)S0167-7322(17)34068-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 004 VZ 85.35 bkl 54.80 bkl Xie, Ruirui verfasserin aut Efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air 2018transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Zang, Hongjun oth Ding, Hongying oth Yan, Bing oth Cheng, Bowen oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:249 year:2018 pages:486-493 extent:8 https://doi.org/10.1016/j.molliq.2017.11.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 249 2018 486-493 8 045F 540 |
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10.1016/j.molliq.2017.11.066 doi GBV00000000000294A.pica (DE-627)ELV041480333 (ELSEVIER)S0167-7322(17)34068-0 DE-627 ger DE-627 rakwb eng 540 540 DE-600 004 VZ 85.35 bkl 54.80 bkl Xie, Ruirui verfasserin aut Efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air 2018transfer abstract 8 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. Zang, Hongjun oth Ding, Hongying oth Yan, Bing oth Cheng, Bowen oth Enthalten in Elsevier Moreno-Cabezali, Belen Maria ELSEVIER Application of a fuzzy-logic based model for risk assessment in additive manufacturing R&D projects 2020 an international journal devoted to fundamental aspects of structure, interactions and dynamic processes in simple, molecular and complex liquids New York, NY [u.a.] (DE-627)ELV004280490 volume:249 year:2018 pages:486-493 extent:8 https://doi.org/10.1016/j.molliq.2017.11.066 Volltext GBV_USEFLAG_U GBV_ELV SYSFLAG_U 85.35 Fertigung VZ 54.80 Angewandte Informatik VZ AR 249 2018 486-493 8 045F 540 |
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The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. 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Efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air |
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efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air |
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Efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air |
| abstract |
Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. |
| abstractGer |
Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. |
| abstract_unstemmed |
Efficient molybdenum- and tungsten-based catalysts have been reported for the oxidation of furoin and 5,5′-dihydroxymethyl furoin (DHMF) to furil and 5,5′-bihydroxymethyl furil (BHMF), respectively. The catalytic oxidation reactions were performed using oxygen in air as the accelerator in acetic acid solvent. Under the optimized reaction conditions and by using tetra-hexadecyltrimethyl ammonium octamolybdate ([CTAB]4Mo8O26) as a catalyst, excellent conversions to furil (~100%) and BHMF (~94%) were observed in a shorter reaction time compared to the other catalysts. This oxidation reaction has been performed by using acetic acid as a solvent under air for the first time, and the catalysts can be readily recycled with no noticeable loss in their catalytic activity over five consecutive catalytic cycles. In this manner, the catalytic system developed in this work is a greener and more environmentally benign process for the oxidation of furoin and DHMF. |
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Efficient oxidation of furoin and 5,5′-dihydroxymethyl furoin to α-diketone furanil over molybdenum and tungsten compounds with air |
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